The instantaneous thermal expansion behavior of-two-phase heterogeneous materials subjected to a uniform temperature change is explored in the present study. The matrix phase is assumed to be a work-hardening ductile ...The instantaneous thermal expansion behavior of-two-phase heterogeneous materials subjected to a uniform temperature change is explored in the present study. The matrix phase is assumed to be a work-hardening ductile metal and the dispersive phase is assumed to consist of either aligned or randomly-oriented, elastic,, spheroidal inhomogeneities. The plastic flow and decreasing stiffness of the matrix during Eshelby's transformation strain of the equivalent inclusions are accounted for by using the deformation theory of plasticity. The explicit results of the instantaneous overall thermal expansion coefficients and the critical inelastic temperature changes are presented for aligned disc- and fiber-inclusions. For the spherical and randomly-oriented spheroidal inclusion, the present study demonstrates that when the yielding of the composites is governed by the average matrix stress, the overall response is always elastic in spite of the temperature change.展开更多
The correlation between structure, chemical bond and thermoelectric properties of boron carbides is discussed based on structural calculations with self-consistent-field discrete variation (SCF-DV-X-a) method, one of ...The correlation between structure, chemical bond and thermoelectric properties of boron carbides is discussed based on structural calculations with self-consistent-field discrete variation (SCF-DV-X-a) method, one of calculation methods of molecular orbital in quantum chemistry. Nine different structural models far calculation are proposed. The calculated results show that the chain is negatively charged and the icosahedron is positively charged, i. e. [C-B-B(C)](delta-) - [B11B(C)](delta+). The total strength of the five covalent bonds between an atom and its five co-ordinating atoms in the icosahedra is slightly larger than the three times of strength of a single bond. The bond between icosahedron and chain or between icosahedra is single bond, but the bond between boron in the middle of chain and carbon or other boron has the characteristic of a double bond. Models 3 and 4 (C-B-B-B11C) are the most stable and easily formed, and the charges of icosahedra of these two models are the lowest, so the disproportionation reaction occurs and the bipolaron forms easily, and the concentration of the carriers and conductivity are the largest, which is consistent with the experimental result that the conductivity has the largest value when the cat-ban content is 13.3%.展开更多
基金This work was supported by the National Science Foundation under the Grant 19302017 and 59472031
文摘The instantaneous thermal expansion behavior of-two-phase heterogeneous materials subjected to a uniform temperature change is explored in the present study. The matrix phase is assumed to be a work-hardening ductile metal and the dispersive phase is assumed to consist of either aligned or randomly-oriented, elastic,, spheroidal inhomogeneities. The plastic flow and decreasing stiffness of the matrix during Eshelby's transformation strain of the equivalent inclusions are accounted for by using the deformation theory of plasticity. The explicit results of the instantaneous overall thermal expansion coefficients and the critical inelastic temperature changes are presented for aligned disc- and fiber-inclusions. For the spherical and randomly-oriented spheroidal inclusion, the present study demonstrates that when the yielding of the composites is governed by the average matrix stress, the overall response is always elastic in spite of the temperature change.
基金National Science Foundation of China Through Outsanding Younth Scientist Foundation (No. 59825102) Science Foundation of Hubei ProvinceCNo. 98J028).
文摘The correlation between structure, chemical bond and thermoelectric properties of boron carbides is discussed based on structural calculations with self-consistent-field discrete variation (SCF-DV-X-a) method, one of calculation methods of molecular orbital in quantum chemistry. Nine different structural models far calculation are proposed. The calculated results show that the chain is negatively charged and the icosahedron is positively charged, i. e. [C-B-B(C)](delta-) - [B11B(C)](delta+). The total strength of the five covalent bonds between an atom and its five co-ordinating atoms in the icosahedra is slightly larger than the three times of strength of a single bond. The bond between icosahedron and chain or between icosahedra is single bond, but the bond between boron in the middle of chain and carbon or other boron has the characteristic of a double bond. Models 3 and 4 (C-B-B-B11C) are the most stable and easily formed, and the charges of icosahedra of these two models are the lowest, so the disproportionation reaction occurs and the bipolaron forms easily, and the concentration of the carriers and conductivity are the largest, which is consistent with the experimental result that the conductivity has the largest value when the cat-ban content is 13.3%.
