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铁酸锶镧对CH_(4)化学循环转化中Mn_(3)O_(4)氧化还原性能的作用机制
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作者 陈彦广 倪永明 +4 位作者 邓冀童 徐瑞晗 韩洪晶 王海英 关宇婷 《当代化工》 CAS 2023年第4期781-786,805,共7页
通过水热合成法制备了MnO_(2),以其作为锰源通过热分解得到Mn_(3)O_(4),采用溶胶凝胶法制备了Mn_(3)O_(4)/La0.8Sr0.2FeO3,将Mn_(3)O_(4)和Mn_(3)O_(4)/La_(0.8)Sr_(0.2)FeO_(3)在900℃下与体积分数3%的CH_(4)和空气交替接触,模拟化学... 通过水热合成法制备了MnO_(2),以其作为锰源通过热分解得到Mn_(3)O_(4),采用溶胶凝胶法制备了Mn_(3)O_(4)/La0.8Sr0.2FeO3,将Mn_(3)O_(4)和Mn_(3)O_(4)/La_(0.8)Sr_(0.2)FeO_(3)在900℃下与体积分数3%的CH_(4)和空气交替接触,模拟化学循环燃烧中的氧化还原过程,研究了Mn_(3)O_(4)和Mn_(3)O_(4)/La_(0.8)Sr_(0.2)FeO_(3)的氧化还原性能和长期稳定性。结果表明:温度的升高会提高Mn_(3)O_(4)/La_(0.8)Sr_(0.2)FeO_(3)的还原失重率;纯Mn_(3)O_(4)在10次氧化还原循环后反应性能降低,不适合作为化学循环燃烧的氧载体,而多次氧化还原循环前后Mn_(3)O_(4)/La_(0.8)Sr_(0.2)FeO_(3)的还原反应活性、稳定性、晶相、元素赋存状态和形貌基本不变。 展开更多
关键词 化学循环转化 铁酸锶镧 Mn_(3)O_(4) 氧化还原
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Strong Quantum Fluctuation of Vortices in Bulk Samples of the New Superconductor MgB_(2) 被引量:1
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作者 WEN Hai-Hu LI Shi-Liang +6 位作者 ZHAO Zhi-Wen ni yong-ming REN Zhi-An CHE Guang-Can YANG Hai-Peng LIU Zhi-Yong ZHAO Zhong-Xian 《Chinese Physics Letters》 SCIE CAS CSCD 2001年第6期816-819,共4页
By using transport and magnetic measurement,the upper critical field H_(c2)(T)and the irreversibility line Hirr(T)has been determined.A big separation between H_(c2)(0)and Hirr(0)has been found showing the existence o... By using transport and magnetic measurement,the upper critical field H_(c2)(T)and the irreversibility line Hirr(T)has been determined.A big separation between H_(c2)(0)and Hirr(0)has been found showing the existence of a quantum vortex liquid state induced by quantum fluctuation of vortices in the new superconductor MgB_(2).Further investigation on the magnetic relaxation shows that both the quantum tunneling and the thermally activated flux creep depends weakly on temperature.However,when the melting field Hirr is approached,a drastic rise of the relaxation rate is observed.This may indicate that the melting of the vortex matter at a finite temperature is also induced by the quantum fluctuation of vortices. 展开更多
关键词 temperature. QUANTUM RELAXATION
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Superconducting Properties of MgB_(2) Prepared by High Pressure and Ambient Pressure
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作者 REN Zhi-An CHE Guang-Can +5 位作者 ZHAO Zhong-Xian CHEN Hong DONG Cheng ni yong-ming JIA Shun-Lian WEN Hai-Hu 《Chinese Physics Letters》 SCIE CAS CSCD 2001年第4期589-591,共3页
The new superconductor MgB_(2) has been prepared by two ways: high pressure and ambient pressure synthesis. Their superconducting properties were measured and compared. It is found that the sample prepared by high pre... The new superconductor MgB_(2) has been prepared by two ways: high pressure and ambient pressure synthesis. Their superconducting properties were measured and compared. It is found that the sample prepared by high pressure is much denser than that prepared under ambient pressure. Accordingly the high pressure sample has a very narrow transition width and a much higher bulk critical current density. 展开更多
关键词 synthesis. AMBIENT SUPERCONDUCTOR
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Upper Critical Field and Irreversibility Line Determined by Transport Measurement of the New Superconductor MgB_(2)
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作者 JIN Hao WEN Hai-Hu +8 位作者 LI Shi-Liang ZHAO Zhi-Wen ni yong-ming REN Zhi-An CHE Guang-Can YANG Hai-Peng LIU Zhi-Yong ZHENG Dong-ning ZHAO Zhong-Xian 《Chinese Physics Letters》 SCIE CAS CSCD 2001年第6期823-825,共3页
Resistive transitions of the new superconductor MgB_(2) are carried out under magnetic fields from 0 to 8 T.It is found that the irreversibility field Hirr(T)and the upper critical field Hc2(T)obtained are very close ... Resistive transitions of the new superconductor MgB_(2) are carried out under magnetic fields from 0 to 8 T.It is found that the irreversibility field Hirr(T)and the upper critical field Hc2(T)obtained are very close to those determined in the magnetic measurement.By using the Arrhenius activation lawρ=ρ0exp(-U/kBT),the activation barrier U has been determined by the low dissipation part of R(T)curves.It is found that U■kBT manifests a very weak thermal activation and thermal fluctuation effect.This may further indicate that the flux dynamics near Hirr(T)is induced by strong quantum fluctuation and tunneling of vortices. 展开更多
关键词 ACTIVATION UPPER THERMAL
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Superconductivity of(R_(0.4)Pr_(0.6))_(0.5)Ca_(0.5)Ba_(2)Cu_(3)O_(7-δ)(R=La,Pr,Nd,Sm,Eu,Gd and Y)Prepared Under High Pressure
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作者 XIONG Han CHE Guang-Can +5 位作者 YAO Yu-Shu ni yong-ming LIU Zhen-Xing JIA Shun-Lian DONG Cheng ZHAO Zhong-Xian 《Chinese Physics Letters》 SCIE CAS CSCD 2001年第5期684-686,共3页
The nearly single phase(R_(0.4)Pr_(0.6))_(0.5)Ca_(0.5)Ba_(2)Cu_(3)O_(7-δ)compounds(R=La,Pr,Nd,Sm,Eu,Gd and Y)with Tc about 100 K were prepared under high pressure and high temperature using the cubic anvil apparatus.... The nearly single phase(R_(0.4)Pr_(0.6))_(0.5)Ca_(0.5)Ba_(2)Cu_(3)O_(7-δ)compounds(R=La,Pr,Nd,Sm,Eu,Gd and Y)with Tc about 100 K were prepared under high pressure and high temperature using the cubic anvil apparatus.The Tc is much higher than that of the traditional R-123 superconductors without doping Ca on the rare-earth site.For various rare earths with different ionic radius,the(R_(0.4)Pr_(0.6))_(0.5)Ca_(0.5)Ba_(2)Cu_(3)O_(7-δ)compounds have almost the same critical temperature.This is different from the result of the ion-size effect of rare-earth ions in R1-xPrxBa2Cu3O7-δcompounds.Our results show that Pr has the same properties as other rare earths in the 123-phase compounds due to the doping of Ca. 展开更多
关键词 temperature. RARE (0)
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Microstructure and Magnetization Investigations of Cu-Doping Effect on La_(2)CuO_(4+δ) Crystal
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作者 DONG Xiao-li ZHAO Bai-ru +10 位作者 ZHAO zhong-xian LIU Wei ZHOU Lei XU Bo CHEN Hong CHE Guang-can ni yong-ming YIN Bo LI Jing-wei ZHAO Li-hua XU Zhong-yu 《Chinese Physics Letters》 SCIE CAS CSCD 1997年第3期225-228,共4页
Measurement and characterization were carried out on Cu-doped and undoped La_(2)CuO_(4+δ) samples prepared under the same conditions.The magnetization measurement on the Cu-doped La_(2)CuO_(4+δ) sample shows coexist... Measurement and characterization were carried out on Cu-doped and undoped La_(2)CuO_(4+δ) samples prepared under the same conditions.The magnetization measurement on the Cu-doped La_(2)CuO_(4+δ) sample shows coexistence of long-range antiferromagnetic order and superconductivity.A stripe-like structure was observed at room temperature on the ab-plane of Cu-doped La_(2)CuO_(4+δ) sample by transmission electron microscope.While for the undoped La_(2)CuO_(4+δ) sample no such behavior or structure feature was found.In this letter,these phenomena were discussed in terms of phase separation. 展开更多
关键词 conditions. separation. LETTER
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Characterization of CoCrFeO_(4) Nanocrystals Prepared by a Sol-Gel Method
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作者 XIONG Gang MAI Zhen-Hong +5 位作者 WANG Chao-Ying ni yong-ming ZHAO Zhong-Xian XU Ming LIU Cui-Xiu LUO Guang-Ming 《Chinese Physics Letters》 SCIE CAS CSCD 2001年第5期692-694,共3页
CoCrFeO_(4) nanocrystals have been synthesized using a sol-gel method.The specimen has an average grain size of 8.1 nm.The zero-field-cooled and field-cooled curves show a superparamagnetic transition occurring at a b... CoCrFeO_(4) nanocrystals have been synthesized using a sol-gel method.The specimen has an average grain size of 8.1 nm.The zero-field-cooled and field-cooled curves show a superparamagnetic transition occurring at a blocking temperature of TB≈249 K.The increase in coercivity of CoCrFeO_(4) nanocrystals with the decreasing temperature has been detected below the blocking temperature and could be explained by the Stoner-Wohlfarth theory.The temperature dependence of saturation magnetization shows that Bloch's law holds but with the Bloch exponent lower than the bulk value. 展开更多
关键词 holds MAGNETIZATION
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