Different atomic ratio La/O film cathodes were prepared by pulsed laser deposition under various vacuum conditions. The emission properties were measured and their surface composition was investigated with in situ AES...Different atomic ratio La/O film cathodes were prepared by pulsed laser deposition under various vacuum conditions. The emission properties were measured and their surface composition was investigated with in situ AES analyses. The function of oxygen in thermoionic emission of Mo-La2O3 cathode was investigated. Excess oxygen is negative to electron emission because lanthanum is easy to become stable La2O3, but proper proportion oxygen can weaken the evaporation of lanthanum and conduce to cathodes' stable work. The formation of oxygen vacancies enhances semiconductor property of La-O compound and improves greatly the performance of cathodes.展开更多
面对日益严峻的资源匮乏与环境污染问题,追求材料产业与资源环境协调,实现可持续发展已经成为全球共识。《Science》于2018年6月底刊登了一篇题为《Toward a sustainable materi-als system》的论文,阐述了材料生命周期工程理论在材料...面对日益严峻的资源匮乏与环境污染问题,追求材料产业与资源环境协调,实现可持续发展已经成为全球共识。《Science》于2018年6月底刊登了一篇题为《Toward a sustainable materi-als system》的论文,阐述了材料生命周期工程理论在材料设计、研发与应用中的核心指导作用,指出了面对全球未来人口膨胀、资源短缺、环境恶化等挑战,应对材料产业基于全生命周期思想进行重新审视,深入研究与大力推广材料全生命周期可持续发展评价及应用。展开更多
The availability of resources for economic activities differs between regions, and the importance of the resources is consequently observed to be different within regions compared to a global scale. With the current s...The availability of resources for economic activities differs between regions, and the importance of the resources is consequently observed to be different within regions compared to a global scale. With the current situation in Chinese mining industry and its statistic characteristics, the characterization procedures of abiotic resource in life cycle impact assessment (LCIA) have demonstrated certain limita-tions in the Chinese materials industry. The aim of this paper is to propose new characterization and normalization factors for abiotic resource depletion categories such as metals and non-renewable en- ergy resources in a Chinese context. The actual production of abiotic resources calculated by a modi- fied model is compared to the reserve base in line with the new national standard to determine char- acterization factors in equivalence units, with antimony as the reference mineral. The normalization factors are based on the total base reserves of the most important minerals in China. A case study on primary magnesium production using the Pidgeon process is used to compare LCIA results for abiotic resource categories that are between current LCIA factors and the new Chinese factors. These factors not only reflect the importance of abiotic resource with respect to region-specific resource depletion, but also can compare with the global factors.展开更多
A cradle-to-gate life cycle assessment was conducted in this paper to calculate the greenhouse gas (GHG) emissions, such as CO2, CH4, CF4 and C2F6 emissions, based on statistic data of Chinese aluminum industry of the...A cradle-to-gate life cycle assessment was conducted in this paper to calculate the greenhouse gas (GHG) emissions, such as CO2, CH4, CF4 and C2F6 emissions, based on statistic data of Chinese aluminum industry of the year 2003. The results showed that the GHG emissions for 1 t primary aluminum production was 21.6 t CO2 equivalent which is 70% higher than that of worldwide average level of the year 2000. The main contributors of emission were the alumina refining and aluminum smelting process accounting for 72% and 22% in accumulative emission, respectively. According to the development and application of new process technologies for primary aluminum production and the ‘target of energy-saving and emissions-reducing’ of Chinese government, the reduction potential of the GHG emissions for alumina and aluminum production were estimated. The results indicated that China aluminum industry would achieve the target of reducing about 25% GHG emissions by the end of 2010.展开更多
文摘Different atomic ratio La/O film cathodes were prepared by pulsed laser deposition under various vacuum conditions. The emission properties were measured and their surface composition was investigated with in situ AES analyses. The function of oxygen in thermoionic emission of Mo-La2O3 cathode was investigated. Excess oxygen is negative to electron emission because lanthanum is easy to become stable La2O3, but proper proportion oxygen can weaken the evaporation of lanthanum and conduce to cathodes' stable work. The formation of oxygen vacancies enhances semiconductor property of La-O compound and improves greatly the performance of cathodes.
文摘面对日益严峻的资源匮乏与环境污染问题,追求材料产业与资源环境协调,实现可持续发展已经成为全球共识。《Science》于2018年6月底刊登了一篇题为《Toward a sustainable materi-als system》的论文,阐述了材料生命周期工程理论在材料设计、研发与应用中的核心指导作用,指出了面对全球未来人口膨胀、资源短缺、环境恶化等挑战,应对材料产业基于全生命周期思想进行重新审视,深入研究与大力推广材料全生命周期可持续发展评价及应用。
基金Supported by the National Natural Science Foundation of China (Grant No. 50525413)the National Key Technology R&D Program (Grant No. 2006BAE04B09-6)+1 种基金the Na-tional Basic Research Program of China ("973" Project) (Grant No. 2007CB613706)Beijing Natural Science Foundation (Grant No. 2081001)
文摘The availability of resources for economic activities differs between regions, and the importance of the resources is consequently observed to be different within regions compared to a global scale. With the current situation in Chinese mining industry and its statistic characteristics, the characterization procedures of abiotic resource in life cycle impact assessment (LCIA) have demonstrated certain limita-tions in the Chinese materials industry. The aim of this paper is to propose new characterization and normalization factors for abiotic resource depletion categories such as metals and non-renewable en- ergy resources in a Chinese context. The actual production of abiotic resources calculated by a modi- fied model is compared to the reserve base in line with the new national standard to determine char- acterization factors in equivalence units, with antimony as the reference mineral. The normalization factors are based on the total base reserves of the most important minerals in China. A case study on primary magnesium production using the Pidgeon process is used to compare LCIA results for abiotic resource categories that are between current LCIA factors and the new Chinese factors. These factors not only reflect the importance of abiotic resource with respect to region-specific resource depletion, but also can compare with the global factors.
基金Supported by the National Natural Science Foundation of China (Grant No. 50525413)National Basic Research Program of China (973 Program) (Grant No. 2007CB613706)Beijing Natural Science Foundation (Grant No. 2081001)
文摘A cradle-to-gate life cycle assessment was conducted in this paper to calculate the greenhouse gas (GHG) emissions, such as CO2, CH4, CF4 and C2F6 emissions, based on statistic data of Chinese aluminum industry of the year 2003. The results showed that the GHG emissions for 1 t primary aluminum production was 21.6 t CO2 equivalent which is 70% higher than that of worldwide average level of the year 2000. The main contributors of emission were the alumina refining and aluminum smelting process accounting for 72% and 22% in accumulative emission, respectively. According to the development and application of new process technologies for primary aluminum production and the ‘target of energy-saving and emissions-reducing’ of Chinese government, the reduction potential of the GHG emissions for alumina and aluminum production were estimated. The results indicated that China aluminum industry would achieve the target of reducing about 25% GHG emissions by the end of 2010.