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AlSc15中间合金中Al_(3)Sc金属间化合物的电化学行为及对局部腐蚀的影响
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作者 蒋伟 高坤元 +6 位作者 胡秀华 文胜平 黄晖 吴晓蓝 魏午 聂祚仁 启世亮 《轻合金加工技术》 CAS 2024年第2期54-58,共5页
将过共晶AlSc15合金加热至液态,以10℃/h速率冷却得到毫米级尺寸的Al_(3)Sc金属间化合物。利用微区电化学和扫描开尔文探针力显微镜(SKPFM)研究了Al_(3)Sc金属间化合物在不同pH值的0.1 mol/L NaCl溶液中的电化学特征及对局部腐蚀敏感性... 将过共晶AlSc15合金加热至液态,以10℃/h速率冷却得到毫米级尺寸的Al_(3)Sc金属间化合物。利用微区电化学和扫描开尔文探针力显微镜(SKPFM)研究了Al_(3)Sc金属间化合物在不同pH值的0.1 mol/L NaCl溶液中的电化学特征及对局部腐蚀敏感性的影响。结果表明,Al_(3)Sc金属间化合物存在自钝化现象,且在碱性环境中有明显的维钝区域;随着pH值的增加,Al_(3)Sc腐蚀电位逐渐降低,在中性和碱性条件下的腐蚀速率明显低于酸性条件下的;Al_(3)Sc金属间化合物与周围铝基体之间的伏打电位差约为40 mV,在铝合金中可能作为较弱的局部阴极,对电偶腐蚀的影响不大。 展开更多
关键词 Al_(3)Sc金属间化合物 微电化学技术 扫描开尔文 局部腐蚀
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Er元素添加对Al-7.7Li合金时效强化及显微组织的影响 被引量:1
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作者 刘琦兵 高坤元 +1 位作者 聂祚仁 丁宇升 《热加工工艺》 北大核心 2020年第14期111-113,118,共4页
通过显微硬度测试及三维原子探针(3DAP)分析对Al-0.03Er、Al-7.7Li、Al-0.03Er-7.7Li (at%)合金的时效强化与显微组织进行了研究。结果表明,Al-0.03Er合金在350℃等温时效10 min达到峰时效硬度38HV,相比固溶态硬度提升了12 HV。Al-7.7L... 通过显微硬度测试及三维原子探针(3DAP)分析对Al-0.03Er、Al-7.7Li、Al-0.03Er-7.7Li (at%)合金的时效强化与显微组织进行了研究。结果表明,Al-0.03Er合金在350℃等温时效10 min达到峰时效硬度38HV,相比固溶态硬度提升了12 HV。Al-7.7Li合金在190℃等温时效24 h达到峰时效硬度98 HV,相比固溶态提升了56 HV。Al-0.03Er-7.7Li合金经350℃/1 h+190℃/8h双级时效后,硬度达108 HV,相比固溶态提升了66 HV,其强化效果为Al-0.03Er、Al-7.7Li合金强化效果的叠加。对此状态的Al-Er-Li合金显微组织进行分析,结果表明,合金中有3种析出相:Al3Er、Al3Li及以Al3Er为核、Al3Li为壳的Al3(Er,Li)相,说明先析出的Al3Er能作为Al3Li异质形核的核心,从而促进了Al3Li的析出,使Al-Er-Li合金强度高于Al-Li合金的强度。 展开更多
关键词 AL-LI合金 Er元素 时效强化
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THERMODYNAMIC ANALYSIS OF Mo-La_2O_3 THERMIONIC CATHODE WIRE 被引量:9
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作者 Zhou Meiling Wang Jinshu +3 位作者 Zhang Jiuxing nie zuoren Li Er Zuo Tieyong(Department of Materials Science and Engineering,Beijing Polytechnic University,Beijing 100022) 《中国有色金属学会会刊:英文版》 CSCD 1996年第4期57-60,共4页
THERMODYNAMICANALYSISOFMo-La_2O_3THERMIONICCATHODEWIRE¥ZhouMeiling;WangJinshu;ZhangJiuxing;NieZuoren;LiEr;Zuo... THERMODYNAMICANALYSISOFMo-La_2O_3THERMIONICCATHODEWIRE¥ZhouMeiling;WangJinshu;ZhangJiuxing;NieZuoren;LiEr;ZuoTieyong(Departmen... 展开更多
关键词 MOLYBDENUM La2O3 CATHODE THERMODYNAMICS
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Function of Oxygen in Mo-La2O3 Cathode
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作者 Hao Shiming nie zuoren 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第4期446-446,共1页
Different atomic ratio La/O film cathodes were prepared by pulsed laser deposition under various vacuum conditions. The emission properties were measured and their surface composition was investigated with in situ AES... Different atomic ratio La/O film cathodes were prepared by pulsed laser deposition under various vacuum conditions. The emission properties were measured and their surface composition was investigated with in situ AES analyses. The function of oxygen in thermoionic emission of Mo-La2O3 cathode was investigated. Excess oxygen is negative to electron emission because lanthanum is easy to become stable La2O3, but proper proportion oxygen can weaken the evaporation of lanthanum and conduce to cathodes' stable work. The formation of oxygen vacancies enhances semiconductor property of La-O compound and improves greatly the performance of cathodes. 展开更多
关键词 thermionic emission CATHODE oxygen vacancies rare earths
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Sc对Al/Fe层状复合材料界面化合物生长行为的影响
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作者 王振 高坤元 +3 位作者 张小军 聂祚仁 黄晖 吴晓蓝 《金属热处理》 CAS CSCD 北大核心 2024年第1期84-90,共7页
采用SEM、EDS等手段研究了铝侧添加Sc元素对Al/Fe复合界面金属间化合物的生长、种类及组织形貌的影响。结果表明,冷轧复合的Al/Fe复合板在475~640℃退火1 h后均产生了连续的界面化合物,在560℃及以下时,金属间化合物厚度变化趋势基本一... 采用SEM、EDS等手段研究了铝侧添加Sc元素对Al/Fe复合界面金属间化合物的生长、种类及组织形貌的影响。结果表明,冷轧复合的Al/Fe复合板在475~640℃退火1 h后均产生了连续的界面化合物,在560℃及以下时,金属间化合物厚度变化趋势基本一致,在560℃以上时,含Sc的复合板界面金属间化合物增长趋势明显变缓,厚度大幅降低,这表明Al侧添加Sc元素不能完全抑制界面金属间化合物的产生。同时,Sc元素的添加并未改变界面化合物的种类及分布,界面化合物从Al侧到Fe侧依次为FeAl_(3)、Fe_(2)Al_(5)、FeAl。在475℃时,Fe侧Fe_(2)Al_(5)相呈细小的锯齿状形貌,但整体十分平整,在580℃时,Fe侧Fe_(2)Al_(5)相呈粗大“指状”形貌,起伏较大。 展开更多
关键词 铝/铁复合 微合金化 金属间化合物
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热旋锻AZ61镁合金的显微组织与力学性能 被引量:3
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作者 荣莉 聂祚仁 梁霄鹏 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2020年第10期3479-3483,共5页
通过多道次热旋锻,成功制备了AZ61镁合金棒丝材,经细晶强化及纳米级颗粒强化显著提高了AZ61镁合金强度,并讨论了动态沉淀析出机理。结果表明:旋锻AZ61镁合金平均晶粒直径约为8μm,YS为302 MPa,UTS达376MPa,具有中等延伸率(7%)。纳米级... 通过多道次热旋锻,成功制备了AZ61镁合金棒丝材,经细晶强化及纳米级颗粒强化显著提高了AZ61镁合金强度,并讨论了动态沉淀析出机理。结果表明:旋锻AZ61镁合金平均晶粒直径约为8μm,YS为302 MPa,UTS达376MPa,具有中等延伸率(7%)。纳米级沉淀相在旋锻变形过程中动态析出,这些沉淀相包括:晶内析出直径50~140 nm的球形β-Mg17Al12相(体积分数约6.5%)、平均直径10nm的球形Al6Mn相。大量细小纳米级第二相动态析出的机理为:旋锻是塑性变形-静态时效-塑性变形-静态时效交替进行的高频(锻打频率通常在1500~6000次/min)脉冲式热力加工过程。塑性变形产生的位错、空位等缺陷,为第二相析出提供了大量优先形核位置。并且每一脉冲周期中静态时效的时间很短(约为0.05 s数量级),所以析出的第二相不会长得过大。 展开更多
关键词 镁合金 热变形 旋锻 析出强化 力学性能
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生命周期方法与材料生命周期工程实践 被引量:1
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作者 聂祚仁 《科技导报》 CAS CSCD 北大核心 2021年第9期1-1,共1页
面对日益严峻的资源匮乏与环境污染问题,追求材料产业与资源环境协调,实现可持续发展已经成为全球共识。《Science》于2018年6月底刊登了一篇题为《Toward a sustainable materi-als system》的论文,阐述了材料生命周期工程理论在材料... 面对日益严峻的资源匮乏与环境污染问题,追求材料产业与资源环境协调,实现可持续发展已经成为全球共识。《Science》于2018年6月底刊登了一篇题为《Toward a sustainable materi-als system》的论文,阐述了材料生命周期工程理论在材料设计、研发与应用中的核心指导作用,指出了面对全球未来人口膨胀、资源短缺、环境恶化等挑战,应对材料产业基于全生命周期思想进行重新审视,深入研究与大力推广材料全生命周期可持续发展评价及应用。 展开更多
关键词 资源短缺 资源匮乏 全生命周期 环境恶化 全球共识 生命周期方法 人口膨胀 生命周期工程
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Characterization and normalization factors of abiotic resource depletion for life cycle impact assessment in China 被引量:18
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作者 GAO Feng nie zuoren +2 位作者 WANG ZhiHong GONG XianZheng ZUO TieYong 《Science China(Technological Sciences)》 SCIE EI CAS 2009年第1期215-222,共8页
The availability of resources for economic activities differs between regions, and the importance of the resources is consequently observed to be different within regions compared to a global scale. With the current s... The availability of resources for economic activities differs between regions, and the importance of the resources is consequently observed to be different within regions compared to a global scale. With the current situation in Chinese mining industry and its statistic characteristics, the characterization procedures of abiotic resource in life cycle impact assessment (LCIA) have demonstrated certain limita-tions in the Chinese materials industry. The aim of this paper is to propose new characterization and normalization factors for abiotic resource depletion categories such as metals and non-renewable en- ergy resources in a Chinese context. The actual production of abiotic resources calculated by a modi- fied model is compared to the reserve base in line with the new national standard to determine char- acterization factors in equivalence units, with antimony as the reference mineral. The normalization factors are based on the total base reserves of the most important minerals in China. A case study on primary magnesium production using the Pidgeon process is used to compare LCIA results for abiotic resource categories that are between current LCIA factors and the new Chinese factors. These factors not only reflect the importance of abiotic resource with respect to region-specific resource depletion, but also can compare with the global factors. 展开更多
关键词 RESOURCE depletion ABIOTIC RESOURCE CATEGORIES life CYCLE impact assessment (LCIA) MAGNESIUM production the Pidgeon process China
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Greenhouse gas emissions and reduction potential of primary aluminum production in China 被引量:8
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作者 GAO Feng nie zuoren +3 位作者 WANG ZhiHong LI HongMei GONG XianZheng ZUO TieYong 《Science China(Technological Sciences)》 SCIE EI CAS 2009年第8期2161-2166,共6页
A cradle-to-gate life cycle assessment was conducted in this paper to calculate the greenhouse gas (GHG) emissions, such as CO2, CH4, CF4 and C2F6 emissions, based on statistic data of Chinese aluminum industry of the... A cradle-to-gate life cycle assessment was conducted in this paper to calculate the greenhouse gas (GHG) emissions, such as CO2, CH4, CF4 and C2F6 emissions, based on statistic data of Chinese aluminum industry of the year 2003. The results showed that the GHG emissions for 1 t primary aluminum production was 21.6 t CO2 equivalent which is 70% higher than that of worldwide average level of the year 2000. The main contributors of emission were the alumina refining and aluminum smelting process accounting for 72% and 22% in accumulative emission, respectively. According to the development and application of new process technologies for primary aluminum production and the ‘target of energy-saving and emissions-reducing’ of Chinese government, the reduction potential of the GHG emissions for alumina and aluminum production were estimated. The results indicated that China aluminum industry would achieve the target of reducing about 25% GHG emissions by the end of 2010. 展开更多
关键词 aluminum METALLURGY GREENHOUSE gas ENERGY-SAVING and emissions-reducing life cycle assessment
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