Superconductivity beyond electron-phonon mechanism is always twisted with magnetism. Based on a new field-effect transistor with solid ion conductor as the gate dielectric(SIC-FET), we successfully achieve an electric...Superconductivity beyond electron-phonon mechanism is always twisted with magnetism. Based on a new field-effect transistor with solid ion conductor as the gate dielectric(SIC-FET), we successfully achieve an electric-field-controlled phase transition between superconductor and ferromagnetic insulator in(Li,Fe)OHFeSe. A dome-shaped superconducting phase with optimal T_c of 43K is continuously tuned into a ferromagnetic insulating phase, which exhibits an electric-field-controlled quantum critical behavior. The origin of the ferromagnetism is ascribed to the order of the interstitial Fe ions expelled from the(Li,Fe)OH layers by gating-controlled Li injection. These surprising findings offer a unique platform to study the relationship between superconductivity and ferromagnetism in Fe-based superconductors. This work also demonstrates the superior performance of the SIC-FET in regulating physical properties of layered unconventional superconductors.展开更多
Thermoelectric materials can be used to convert heat to electric power through the Seebeck effect. We study magneto-thermoelectric figure of merit (ZT) in three-dimensional Dirac semimetal Cd3A 5 2 crystal. It is fo...Thermoelectric materials can be used to convert heat to electric power through the Seebeck effect. We study magneto-thermoelectric figure of merit (ZT) in three-dimensional Dirac semimetal Cd3A 5 2 crystal. It is found that enhancement of power factor and reduction of thermal conductivity can be realized at the same time through magnetic field although magnetoresistivity is greatly increased. ZT can be highly enhanced from 0.17 to 1.1 by more than six times around 350 K under a perpendicular magnetic field of 7 T. The huge enhancement of ZT by magnetic field arises from the linear Dirac band with large Fermi velocity and the large electric thermal conductivity in CdsA 5 2. Our work paves a new way to greatly enhance the thermoelectric performance in the quantum topological materials.展开更多
Different instabilities have been confirmed to exist in the three-dimensional(3D) electron gas when it is confined to the lowest Landau level in the extreme quantum limit. The recently discovered 3D topological semime...Different instabilities have been confirmed to exist in the three-dimensional(3D) electron gas when it is confined to the lowest Landau level in the extreme quantum limit. The recently discovered 3D topological semimetals offer a good platform to explore these phenomena due to the small sizes of their Fermi pockets, which means the quantum limit can be achieved at relatively low magnetic fields. In this work, we report the high-magnetic-field transport properties of the Dirac semimetal state in pressurized black phosphorus. Under applied hydrostatic pressure, the band structure of black phosphorus goes through an insulator-semimetal transition. In the high pressure topological semimetal phase, anomalous behaviors are observed on both magnetoresistance and Hall resistivity beyond the relatively low quantum limit field, which is demonstrated to indicate the emergence of an exotic electronic state hosting a density wave ordering. Our findings bring the first insight into the electronic interactions in black phosphorus under intense field.展开更多
The origin of the ~40 and ~30 K superconducting phases in the metal-intercalated FeSe superconductors is still unclear. We report the synthesis of K_(0.3)(NH_3)_y(FeSe_(1-x)Te_x)_2 and K_(0.6)(NH_3)_y(FeSe_(1-x)Te_x...The origin of the ~40 and ~30 K superconducting phases in the metal-intercalated FeSe superconductors is still unclear. We report the synthesis of K_(0.3)(NH_3)_y(FeSe_(1-x)Te_x)_2 and K_(0.6)(NH_3)_y(FeSe_(1-x)Te_x)_2 with x=0-0.6 by using the liquid ammonia method at room temperature. The superconducting transition temperature Tcof the former remains about 43 K for all the nominal Te content less than 0.3, while that of the latter is about 30 K and obviously decreases with Te doping. Superconductivity disappears for x ≥0.4 in both systems. Except for the different chemical pressure induced by substitution of Te for Se in both systems, we also observed distinct external pressure effect on superconductivity for both systems, with much more efficiency of suppressing Tcby external pressure in the former system. These dramatic differences of both chemical and external pressure effects on Tc between the ~30 and ~40 K superconducting phases revealed that the existence of the two superconducting phases can be ascribed to the moderate and negligible coupling between FeSe layers, respectively.展开更多
We report the synthesis,structural and physical properties of a new layered transition metal arsenide Na4Cu3TaAs4.This material adopts the space groupⅠ√2 m,with lattice parameters of a=5.9101(3)?and c=13.8867(12)?.T...We report the synthesis,structural and physical properties of a new layered transition metal arsenide Na4Cu3TaAs4.This material adopts the space groupⅠ√2 m,with lattice parameters of a=5.9101(3)?and c=13.8867(12)?.This structure contains two layers of Na sandwiched by antiPb O-type(Cu/Ta)As layers,similar to the"111"-type ironbased superconductor Na Fe As.The transition metal sites are occupied by 75%Cu and 25%Ta,with Ta forming a well-defined superstructure.Cu and Ta were determined to be+1 and+5 oxidation state respectively.The band structure of the Na4Cu3TaAs4 measured by angle resolved photoemission spectroscopy(ARPES)is in good agreement with the density functional theory(DFT)calculation.Both ARPES and resistivity measurement indicate that this material exhibits metallic behavior with p-type carriers.Magnetic susceptibility measurement shows that the material exhibits nearly T-independent diamagnetism.This new material extends the material system with anti-Pb O-type layers and offers a good playground to investigate this material system further.展开更多
基金supported by National Natural Science Foundation of China(61174053)National Key Basic Research Program of China(2014CB845301/2/3)+3 种基金Fundamental Research Funds for the Central Universities(2014ZP0021)Cultivation Fund of the Key Scientific and Technical Innovation Project,Ministry of Education of China(708069)partially by Key Laboratory of Autonomous Systems and Networked Control,Ministry of EducationKey Laboratory of Surface Functional Structure Manufacturing of Guangdong Higher Education Institutes
基金supported by the National Key R&D Program of China(2017YFA0303001 and 2016YFA0300201)the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(XDB25010100)+2 种基金the National Natural Science Foundation of China(11888101 and 11534010)Science Challenge Project(TZ2016004)Hefei Science Center CAS(2016HSC-IU001)
文摘Superconductivity beyond electron-phonon mechanism is always twisted with magnetism. Based on a new field-effect transistor with solid ion conductor as the gate dielectric(SIC-FET), we successfully achieve an electric-field-controlled phase transition between superconductor and ferromagnetic insulator in(Li,Fe)OHFeSe. A dome-shaped superconducting phase with optimal T_c of 43K is continuously tuned into a ferromagnetic insulating phase, which exhibits an electric-field-controlled quantum critical behavior. The origin of the ferromagnetism is ascribed to the order of the interstitial Fe ions expelled from the(Li,Fe)OH layers by gating-controlled Li injection. These surprising findings offer a unique platform to study the relationship between superconductivity and ferromagnetism in Fe-based superconductors. This work also demonstrates the superior performance of the SIC-FET in regulating physical properties of layered unconventional superconductors.
基金supported by the National Key R&D Program of the Ministry of Science and Technology China(2017YFA0303001,2016YFA0300201 and 2017YFA0204904)the National Natural Science Foundation of China(11534010,11774325 and21603210)+4 种基金the Key Research Program of Frontier Sciences CAS(QYZDY-SSW-SLH021)Hefei Science Center CAS(2016HSCIU001)the Fundamental Research Funds for the Central UniversitiesSupercomputing Center at USTC for providing the computing resourcespartially performed on the Superconducting Magnet and PPMS-16T Facilities,High Magnetic Field Laboratory of CAS
文摘Thermoelectric materials can be used to convert heat to electric power through the Seebeck effect. We study magneto-thermoelectric figure of merit (ZT) in three-dimensional Dirac semimetal Cd3A 5 2 crystal. It is found that enhancement of power factor and reduction of thermal conductivity can be realized at the same time through magnetic field although magnetoresistivity is greatly increased. ZT can be highly enhanced from 0.17 to 1.1 by more than six times around 350 K under a perpendicular magnetic field of 7 T. The huge enhancement of ZT by magnetic field arises from the linear Dirac band with large Fermi velocity and the large electric thermal conductivity in CdsA 5 2. Our work paves a new way to greatly enhance the thermoelectric performance in the quantum topological materials.
基金supported by the National Natural Science Foundation of China (11534010, 11504378 and 11474287)the Key Research Program of Frontier Sciences, CAS, China (QYZDY-SSW-SLH021)+2 种基金the National Key R&D Program of the MOST of China (2016YFA0300201 and 2017YFA0303001)the Hefei Science Center, CAS (2016HSC-IU001)the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology (2017FXCX001)
文摘Different instabilities have been confirmed to exist in the three-dimensional(3D) electron gas when it is confined to the lowest Landau level in the extreme quantum limit. The recently discovered 3D topological semimetals offer a good platform to explore these phenomena due to the small sizes of their Fermi pockets, which means the quantum limit can be achieved at relatively low magnetic fields. In this work, we report the high-magnetic-field transport properties of the Dirac semimetal state in pressurized black phosphorus. Under applied hydrostatic pressure, the band structure of black phosphorus goes through an insulator-semimetal transition. In the high pressure topological semimetal phase, anomalous behaviors are observed on both magnetoresistance and Hall resistivity beyond the relatively low quantum limit field, which is demonstrated to indicate the emergence of an exotic electronic state hosting a density wave ordering. Our findings bring the first insight into the electronic interactions in black phosphorus under intense field.
基金supported by the National Natural Science Foundation of China(Grants Nos.11374252,11604278,11534010,and 91422303)the National Key R&D Program of the MOST of China(Grant No.2017YFA0303001)+1 种基金the Hefei Science Center Chinese Academy Sciences(Grant No.2016HSC-IU001)the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB04040100)
文摘The origin of the ~40 and ~30 K superconducting phases in the metal-intercalated FeSe superconductors is still unclear. We report the synthesis of K_(0.3)(NH_3)_y(FeSe_(1-x)Te_x)_2 and K_(0.6)(NH_3)_y(FeSe_(1-x)Te_x)_2 with x=0-0.6 by using the liquid ammonia method at room temperature. The superconducting transition temperature Tcof the former remains about 43 K for all the nominal Te content less than 0.3, while that of the latter is about 30 K and obviously decreases with Te doping. Superconductivity disappears for x ≥0.4 in both systems. Except for the different chemical pressure induced by substitution of Te for Se in both systems, we also observed distinct external pressure effect on superconductivity for both systems, with much more efficiency of suppressing Tcby external pressure in the former system. These dramatic differences of both chemical and external pressure effects on Tc between the ~30 and ~40 K superconducting phases revealed that the existence of the two superconducting phases can be ascribed to the moderate and negligible coupling between FeSe layers, respectively.
基金supported by the National Natural Science Foundation of China(11888101 and 11534010)Anhui Initiative in Quantum Information Technologies(AHY160000)+2 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(XDB25000000)the National Key Research and Development Program of the Ministry of Science and Technology of China(2016YFA0300201 and 2017YFA0303001)the Key Research Program of Frontier Sciences,CAS,China(QYZDYSSW-SLH021).
文摘We report the synthesis,structural and physical properties of a new layered transition metal arsenide Na4Cu3TaAs4.This material adopts the space groupⅠ√2 m,with lattice parameters of a=5.9101(3)?and c=13.8867(12)?.This structure contains two layers of Na sandwiched by antiPb O-type(Cu/Ta)As layers,similar to the"111"-type ironbased superconductor Na Fe As.The transition metal sites are occupied by 75%Cu and 25%Ta,with Ta forming a well-defined superstructure.Cu and Ta were determined to be+1 and+5 oxidation state respectively.The band structure of the Na4Cu3TaAs4 measured by angle resolved photoemission spectroscopy(ARPES)is in good agreement with the density functional theory(DFT)calculation.Both ARPES and resistivity measurement indicate that this material exhibits metallic behavior with p-type carriers.Magnetic susceptibility measurement shows that the material exhibits nearly T-independent diamagnetism.This new material extends the material system with anti-Pb O-type layers and offers a good playground to investigate this material system further.