The phase transformation of hydroxyapatite (HAP, Ca10(PO4)6(OH)2) to the beta tricalcium phosphate phase (β-TCP, β-Ca3(PO4)2) at 1100°C is well known. However, in the case of human tooth, the HAP phase transfor...The phase transformation of hydroxyapatite (HAP, Ca10(PO4)6(OH)2) to the beta tricalcium phosphate phase (β-TCP, β-Ca3(PO4)2) at 1100°C is well known. However, in the case of human tooth, the HAP phase transformation is still an open area. For example, the CaO phase has sometimes been reported in the set of phases that make up the teeth. In this study, physical changes of human teeth when subjected to heat treatment in inert atmosphere (argon) were studied. The results were compared with those obtained in air atmosphere, from room temperature (25°C) up to 1200°C. Morphological changes were analyzed by light and scanning electron microscopy (SEM). The HAP to β-TCP phase transformation was followed in powder samples by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). Heating of teeth results in the removal of organic material and structural water before the HAP to β-TCP phase transformation, the increment in hardness and the induced crystal growth. The percentage of the phases, crystal growth and lattice parameter variations as a function of temperature was quantified by Rietveld analysis. The black color was observed in dentin heated under argon atmosphere. Differences in expansivity produce fractures in dentin at 300°C in argon and at 400°C in air. In dentin, the coexistence of the HAP and β-TCP phases was observed after 800°C in argon and after 600°C in air;in enamel it was observed at 600°C in argon compared with 400°C in air. In general, the role played by the argon atmosphere during the thermal treatment of the teeth is to retard the processes observed in air.展开更多
文摘The phase transformation of hydroxyapatite (HAP, Ca10(PO4)6(OH)2) to the beta tricalcium phosphate phase (β-TCP, β-Ca3(PO4)2) at 1100°C is well known. However, in the case of human tooth, the HAP phase transformation is still an open area. For example, the CaO phase has sometimes been reported in the set of phases that make up the teeth. In this study, physical changes of human teeth when subjected to heat treatment in inert atmosphere (argon) were studied. The results were compared with those obtained in air atmosphere, from room temperature (25°C) up to 1200°C. Morphological changes were analyzed by light and scanning electron microscopy (SEM). The HAP to β-TCP phase transformation was followed in powder samples by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). Heating of teeth results in the removal of organic material and structural water before the HAP to β-TCP phase transformation, the increment in hardness and the induced crystal growth. The percentage of the phases, crystal growth and lattice parameter variations as a function of temperature was quantified by Rietveld analysis. The black color was observed in dentin heated under argon atmosphere. Differences in expansivity produce fractures in dentin at 300°C in argon and at 400°C in air. In dentin, the coexistence of the HAP and β-TCP phases was observed after 800°C in argon and after 600°C in air;in enamel it was observed at 600°C in argon compared with 400°C in air. In general, the role played by the argon atmosphere during the thermal treatment of the teeth is to retard the processes observed in air.
