Following the need for the use of environmentally friendly, renewable resource in industrial processes, this work explores the potential of an effective application in pilot scale of Afzelia bella seed as a coag-flocc...Following the need for the use of environmentally friendly, renewable resource in industrial processes, this work explores the potential of an effective application in pilot scale of Afzelia bella seed as a coag-flocculant. The study evaluates the coag-flocculation efficiency and functional kinetic parameter response to varying pH and dosage of coal washery effluent and ABC respectively. The maximum coag-flocculation performance is recorded at rate constant, K of 3.3333 x 10-3m3/kg.s, dosage of (0.3 and 0.2kg/m3);pH of 2 and coagulation period, τ1/2of 28.1216 s while the minimum is recorded at K of 1.6667 x 10-4m3/kg.s, dosage of 0.2kg/m3, pH of 10 and τ1/2 of 562.365 s. The least value of coag-flocculation efficiency, E (%)>89.00. Simulated and unsimulated values of rate constants Ks and K respectively are in close agreement, validating the concept of perikinetics. The potential of ABC as an effective organic coag-flocculant has been established. The results confirm that theory of rapid coagflocculation holds for the aggregation of coal washery effluent using ABC and at the conditions of the experiment.展开更多
This work investigates coag-flocculation optimization treatment of alum-brewery effluent system via response surface methodology (RSM). To minimize suspended and dissolved particles (SDP), experiments were carried out...This work investigates coag-flocculation optimization treatment of alum-brewery effluent system via response surface methodology (RSM). To minimize suspended and dissolved particles (SDP), experiments were carried out using nephelometric jar test and 23-factorial design with three star-points, six-center-points and two replications. A central composite design, which is the standard design of RSM, was used to evaluate the effects and interactions of three major factors (coagulation pH, coagulant dosage, settling time) on the treatment efficiency. Multivariable quadratic model developed for the response studied indicates the optimum conditions to be 9, 500mg/l and 20minutes for coagulation pH, coagulant dosage and settling time, respectively. At optimum, the SDP was reduced from 10831.490mg/l to 801.451mg/l, representing 92.601% removal efficiency. RSM has demonstrated to be appropriate approach for the optimization of the coag-flocculation process by statistical evaluation.展开更多
This work investigates the influence of pH variation on coag-flocculation kinetics and performance of Chitin Derived Coag-flocculant (CDC) in removal of Suspended and Dissolved Particles (SDP) from Coal washery efflue...This work investigates the influence of pH variation on coag-flocculation kinetics and performance of Chitin Derived Coag-flocculant (CDC) in removal of Suspended and Dissolved Particles (SDP) from Coal washery effluent (CWE) medium. Key parameters such as rate constant Km, half life t1/2,, and pH etc. were investigated. The best coag-flocculation performance is recorded at Km, of 0.007 l/mg.min, t1/2, of 0.0362min, pH of 8, dosage of 100mg/l and efficiency E(%) of 99.933. Minimum efficiency (%) > 94.00 was achieved at 30 minutes of coagflocculation, establishing CDC as an effective water treatment agent at the conditions of the experiment.展开更多
文摘Following the need for the use of environmentally friendly, renewable resource in industrial processes, this work explores the potential of an effective application in pilot scale of Afzelia bella seed as a coag-flocculant. The study evaluates the coag-flocculation efficiency and functional kinetic parameter response to varying pH and dosage of coal washery effluent and ABC respectively. The maximum coag-flocculation performance is recorded at rate constant, K of 3.3333 x 10-3m3/kg.s, dosage of (0.3 and 0.2kg/m3);pH of 2 and coagulation period, τ1/2of 28.1216 s while the minimum is recorded at K of 1.6667 x 10-4m3/kg.s, dosage of 0.2kg/m3, pH of 10 and τ1/2 of 562.365 s. The least value of coag-flocculation efficiency, E (%)>89.00. Simulated and unsimulated values of rate constants Ks and K respectively are in close agreement, validating the concept of perikinetics. The potential of ABC as an effective organic coag-flocculant has been established. The results confirm that theory of rapid coagflocculation holds for the aggregation of coal washery effluent using ABC and at the conditions of the experiment.
文摘This work investigates coag-flocculation optimization treatment of alum-brewery effluent system via response surface methodology (RSM). To minimize suspended and dissolved particles (SDP), experiments were carried out using nephelometric jar test and 23-factorial design with three star-points, six-center-points and two replications. A central composite design, which is the standard design of RSM, was used to evaluate the effects and interactions of three major factors (coagulation pH, coagulant dosage, settling time) on the treatment efficiency. Multivariable quadratic model developed for the response studied indicates the optimum conditions to be 9, 500mg/l and 20minutes for coagulation pH, coagulant dosage and settling time, respectively. At optimum, the SDP was reduced from 10831.490mg/l to 801.451mg/l, representing 92.601% removal efficiency. RSM has demonstrated to be appropriate approach for the optimization of the coag-flocculation process by statistical evaluation.
文摘This work investigates the influence of pH variation on coag-flocculation kinetics and performance of Chitin Derived Coag-flocculant (CDC) in removal of Suspended and Dissolved Particles (SDP) from Coal washery effluent (CWE) medium. Key parameters such as rate constant Km, half life t1/2,, and pH etc. were investigated. The best coag-flocculation performance is recorded at Km, of 0.007 l/mg.min, t1/2, of 0.0362min, pH of 8, dosage of 100mg/l and efficiency E(%) of 99.933. Minimum efficiency (%) > 94.00 was achieved at 30 minutes of coagflocculation, establishing CDC as an effective water treatment agent at the conditions of the experiment.