Studied waters belong to warm (T=30-50℃), alkaline (pH=8.9-9.3), low mineralized (TDS〈235 mg/l) Na-HCO3 or Na-SO4-HCO3 thermal waters with high content of SiO2 (up to 81 mg/1) and F (up to 3.9 mg/l), occur...Studied waters belong to warm (T=30-50℃), alkaline (pH=8.9-9.3), low mineralized (TDS〈235 mg/l) Na-HCO3 or Na-SO4-HCO3 thermal waters with high content of SiO2 (up to 81 mg/1) and F (up to 3.9 mg/l), occur on modern volcano-tectonic rejuvenated areas of Eastern Sikhote-Alin orogenic belt. Low 3He concentration as well as N2/O2 and N2/Ar ratios exclude influence of deep mantle fluid. New rare earth element data constrain our understanding of water-rock interaction occurring in the water source region. Meteoric origin of waters is proved by stable isotope values varying from -71%o to -136.1‰ and from -10.8‰ to -18.8%o for δ^2H and δ^18O respectively. REE patterns reflect high pH, resultfing from water-rock interaction and oxidative conditions. Calculations of deep aquifer temperature using Na-K and quartz geothermometers show 116.8-131.1℃ and 82.2-125.8℃ respectively. Presence of deep faults both with abnormal thermal gradient (-45- 50 K/km) define unique geochemical shape of thermal waters of Sikhote-Alin, area, where no present volcanic activity is registered.展开更多
文摘Studied waters belong to warm (T=30-50℃), alkaline (pH=8.9-9.3), low mineralized (TDS〈235 mg/l) Na-HCO3 or Na-SO4-HCO3 thermal waters with high content of SiO2 (up to 81 mg/1) and F (up to 3.9 mg/l), occur on modern volcano-tectonic rejuvenated areas of Eastern Sikhote-Alin orogenic belt. Low 3He concentration as well as N2/O2 and N2/Ar ratios exclude influence of deep mantle fluid. New rare earth element data constrain our understanding of water-rock interaction occurring in the water source region. Meteoric origin of waters is proved by stable isotope values varying from -71%o to -136.1‰ and from -10.8‰ to -18.8%o for δ^2H and δ^18O respectively. REE patterns reflect high pH, resultfing from water-rock interaction and oxidative conditions. Calculations of deep aquifer temperature using Na-K and quartz geothermometers show 116.8-131.1℃ and 82.2-125.8℃ respectively. Presence of deep faults both with abnormal thermal gradient (-45- 50 K/km) define unique geochemical shape of thermal waters of Sikhote-Alin, area, where no present volcanic activity is registered.