Platinum-group-metal-based alloy nanocrystals have been considered as the most effi cient catalysts for oxygen reduction reaction(ORR).However,the poor stability issues limit their further deployment in industrializat...Platinum-group-metal-based alloy nanocrystals have been considered as the most effi cient catalysts for oxygen reduction reaction(ORR).However,the poor stability issues limit their further deployment in industrialization.Tungsten oxide(WO_(3))has received attention due to its intrinsic electrochemical stability and proton absorption/desorption capability.In this work,we prepared PtCuNi/WO_(3)/C hybrid catalyst with inter-diff usive alloy/WO_(3)interface on carbon.The catalyst exhibits enhanced activity and stability associated with the WO_(3)content.The characterization results suggest that the increased activity originates from the complementary proton supply of non-stoichiometric H_(x)WO_(3).Moreover,WO_(3)prevents the particle from dissolution and detachment under vigorous electrochemical polarizations.The enhanced stability originates from the electronic interaction established between Pt and W.This work provides new strategies to design high-performance ORR catalysts by taking the merits of WO_(3)。展开更多
A new method of depositing an insulating multifunctional oxide coating on metal particles was developed.Such coatings increase corrosion resistance and insulate metal particles from each other.On base of capsulated by...A new method of depositing an insulating multifunctional oxide coating on metal particles was developed.Such coatings increase corrosion resistance and insulate metal particles from each other.On base of capsulated by oxide coating water-atomized iron powder ASC100.29,new composite soft magnetic materials were synthesized,which are able of replacing electrical steel in devices.Structural,electromagnetic properties and corrosion characte-ristics of the obtained composites were studied.It was found that the synthesized composite materials have low elec-tromagnetic losses,high values of magnetic induction(up to 2.1 T)and good corrosion resistance.The results demon-strate that the use of such materials in power supplies,c hokes,transformers,stators and rotors of electric machines and other products ensures their stable operation under various conditions.展开更多
文摘Platinum-group-metal-based alloy nanocrystals have been considered as the most effi cient catalysts for oxygen reduction reaction(ORR).However,the poor stability issues limit their further deployment in industrialization.Tungsten oxide(WO_(3))has received attention due to its intrinsic electrochemical stability and proton absorption/desorption capability.In this work,we prepared PtCuNi/WO_(3)/C hybrid catalyst with inter-diff usive alloy/WO_(3)interface on carbon.The catalyst exhibits enhanced activity and stability associated with the WO_(3)content.The characterization results suggest that the increased activity originates from the complementary proton supply of non-stoichiometric H_(x)WO_(3).Moreover,WO_(3)prevents the particle from dissolution and detachment under vigorous electrochemical polarizations.The enhanced stability originates from the electronic interaction established between Pt and W.This work provides new strategies to design high-performance ORR catalysts by taking the merits of WO_(3)。
基金Supported by the Joint Projects of the Belarusian Republican Foundation for Basic Research and Romanian Academy(BRFBR-RA)(Nos.T19UZBG-004/2019,T20RA-004/2020).
文摘A new method of depositing an insulating multifunctional oxide coating on metal particles was developed.Such coatings increase corrosion resistance and insulate metal particles from each other.On base of capsulated by oxide coating water-atomized iron powder ASC100.29,new composite soft magnetic materials were synthesized,which are able of replacing electrical steel in devices.Structural,electromagnetic properties and corrosion characte-ristics of the obtained composites were studied.It was found that the synthesized composite materials have low elec-tromagnetic losses,high values of magnetic induction(up to 2.1 T)and good corrosion resistance.The results demon-strate that the use of such materials in power supplies,c hokes,transformers,stators and rotors of electric machines and other products ensures their stable operation under various conditions.
