In this work we synthesize a novel and highly efficient photocatalyst for degradation of methyl orange and rhodamine B. In addition, a new method for synthesis of FeO@SiO@TiO@Ho magnetic core-shell nanoparticles with ...In this work we synthesize a novel and highly efficient photocatalyst for degradation of methyl orange and rhodamine B. In addition, a new method for synthesis of FeO@SiO@TiO@Ho magnetic core-shell nanoparticles with spherical morphology is proposed. The crystal structures, morphology and chemical properties of the as-synthesized nanoparticles were characterized using Fourier transform infrared spectroscopy（FT-IR）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, energy dispersive X-ray（EDS）, X-ray diffraction（XRD）, UV–vis diffuse reflectance spectroscopy（DRS） and vibrating sample magnetometer（VSM） techniques. The photocatalytic activity of FeO@SiO@TiO@Ho was investigated by degradation of methyl orange（MO） as cationic dye and rhodamine B（Rh B） as anionic dye in aqueous solution under UV/vis irradiation. The results indicate that about 92.1% of Rh B and78.4% of MO were degraded after 120 and 150 min, respectively. These degradation results show that FeO@SiO@TiO@Ho nanoparticles are better photocatalyst than Fe3O4@Si O2@TiO 2@Ho for degradation of MO and Rh B. As well as, the catalyst shows high recovery and stability even after several separation cycles.展开更多
基金the council of Iran National Science Foundation and University of Kashan for supporting this work by Grant No (159271/999)
文摘In this work we synthesize a novel and highly efficient photocatalyst for degradation of methyl orange and rhodamine B. In addition, a new method for synthesis of FeO@SiO@TiO@Ho magnetic core-shell nanoparticles with spherical morphology is proposed. The crystal structures, morphology and chemical properties of the as-synthesized nanoparticles were characterized using Fourier transform infrared spectroscopy（FT-IR）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, energy dispersive X-ray（EDS）, X-ray diffraction（XRD）, UV–vis diffuse reflectance spectroscopy（DRS） and vibrating sample magnetometer（VSM） techniques. The photocatalytic activity of FeO@SiO@TiO@Ho was investigated by degradation of methyl orange（MO） as cationic dye and rhodamine B（Rh B） as anionic dye in aqueous solution under UV/vis irradiation. The results indicate that about 92.1% of Rh B and78.4% of MO were degraded after 120 and 150 min, respectively. These degradation results show that FeO@SiO@TiO@Ho nanoparticles are better photocatalyst than Fe3O4@Si O2@TiO 2@Ho for degradation of MO and Rh B. As well as, the catalyst shows high recovery and stability even after several separation cycles.
