In the present investigation an effort has been made to understand the thermal decomposition and burn rate characteristics of AP as oxidizer and PVC and HTPB as fuel binder in composite solid propellant. The burning r...In the present investigation an effort has been made to understand the thermal decomposition and burn rate characteristics of AP as oxidizer and PVC and HTPB as fuel binder in composite solid propellant. The burning rate study has been carried out at ambient and different pressures of 2.068 Mpa, 4.760 Mpa,6.895 Mpa. The mechanism of thermal decomposition of each composition have also been determined by NETZSCH simultaneous thermal analyser, comprising differential scanning calorimeter(DSC) and thermo-gravimetric analyser(TGA). An effort has been made to study the burn rate and decomposition of fuel binder and oxidizer in presence of Fe_2O_3 and also their overall impact on combustion of propellant.展开更多
Thixocasting requires manufacturing of billets with non-dendritic microstructure.Aluminum alloy A356 billets were produced by rheocasting in a mould placed inside a linear electromagnetic stirrer.Subsequent heat treat...Thixocasting requires manufacturing of billets with non-dendritic microstructure.Aluminum alloy A356 billets were produced by rheocasting in a mould placed inside a linear electromagnetic stirrer.Subsequent heat treatment was used to produce a transition from rosette to globular microstructure.The current and the duration of stirring were explored as control parameters.Simultaneous induction heating of the billet during stirring was quantified using experimentally determined thermal profiles.The effect of processing parameters on the dendrite fragmentation was discussed.Corresponding computational modeling of the process was performed using phase-field modeling of alloy solidification in order to gain insight into the process of morphological changes of a solid during this process.A non-isothermal alloy solidification model was used for simulations.The morphological evolution under such imposed thermal cycles was simulated and compared with experimentally determined one.Suitable scaling using the thermosolutal diffusion distances was used to overcome computational difficulties in quantitative comparison at system scale.The results were interpreted in the light of existing theories of microstructure refinement and globularisation.展开更多
The development work for producing an automobile component by thixocasting using A356.2 alloy was introduced.As the first step,the alloy was electromagnetically stirred and solidified to produce a billet with non-dend...The development work for producing an automobile component by thixocasting using A356.2 alloy was introduced.As the first step,the alloy was electromagnetically stirred and solidified to produce a billet with non-dendritic microstructure.The microstructure depended on several process parameters such as stirring intensity,stirring frequency,cooling rate,and melt initial superheat.Through a series of computational studies and controlled experiments,a set of process parameters were identified to produce the best microstructures.Reheating of a billet with non-dendritic microstructure to a semisolid temperature was the next step for thixo-casting of the components.The reheating process was characterized for various reheating cycles using a vertical-type reheating machine.The induction heating cycle was optimized to obtain a near-uniform temperature distribution in radial as well as axial direction of the billet,and the heating was continued until the liquid fraction reached about 50%.These parameters were determined with the help of a computational fluid dynamics(CFD) model of die filling and solidification of the semisolid alloy.The heated billets were subsequently thixo-cast into automobile components using a real-time controlled die casting machine.The results show that the castings are near net shape,free from porosity,good surface finish and have superior mechanical properties compared to those produced by conventional die casting processes using the same alloy.展开更多
Objective Fenvalerate (20% EC) is a synthetic pyrethroid, which is commonly used in India by farmers for the protection of many food and vegetable crops against a wide variety of insects. However, its inhalation toxi...Objective Fenvalerate (20% EC) is a synthetic pyrethroid, which is commonly used in India by farmers for the protection of many food and vegetable crops against a wide variety of insects. However, its inhalation toxicity data is very limited in the literature due to the fact that the exposure levels associated with these effects were usually not reported. Hence, inhalation exposure was carried out to investigate the hepatotoxic effects. Method Adult male rats were exposed to fen for 4 h/day, 5 days a week for 90 days by using Flow Past Nose Only Inhalation Chamber. Sham treated control rats were exposed to compressed air in the inhalation chamber for the same period. Results The results indicated hepatomegaly, increased activities of serum clinical enzymes (indicative of liver damage/dysfunction) along with pronounced histopathological damage of liver. Conclusion The hepatotoxic potential of formulated Fen (20% EC) in rats exposed by nose only inhalation is being reported for the first time and warrant adequate safety measures for human beings exposed to this insecticide, particularly by inhalation route.展开更多
In this paper, generalized dual-phase-lag (DPL) model has been studied for the numerical analysis of spatial variation of temperature within living biological tissues during thermal therapy applications. A new hybrid ...In this paper, generalized dual-phase-lag (DPL) model has been studied for the numerical analysis of spatial variation of temperature within living biological tissues during thermal therapy applications. A new hybrid numerical scheme based on finite difference scheme and Chebyshev wavelet Galerkin method are used to solve the generalized DPL model with constant heat flux boundary condition. Multi-resolution and multi-scale computational property of Chebyshev wavelet in the present case localizes small scale variations of solution and fast switching of functional bases. Our study demonstrates that due to presence of coupling factor (convection–perfusion), generalized DPL model predicts lower temperature than classical DPL and Pennes model at the tumor position. Higher values of phase lag times results in lower temperature at the tumor position. But, in case of variation of phase lag time due to temperature gradient, the nature of temperature profile also depends on the spatial coordinate. The effect of the blood temperature, porosity and interfacial convective heat transfer on temperature distribution has been investigated. It is found that larger values of porosity and interfacial convective heat transfer results in lower temperature at the tumor position. Also, both porosity and interfacial convective heat transfer are pronounced more at higher values. The whole analysis is presented in dimensionless form.展开更多
Lead free(K_(0.5)Na_(0.5))NbO_(3)(KNN)ceramics were prepared by conventional solid state reaction route.For single perovskite phase formation,calcination temperature was optimized at 850℃for 6h,whereas for dense morp...Lead free(K_(0.5)Na_(0.5))NbO_(3)(KNN)ceramics were prepared by conventional solid state reaction route.For single perovskite phase formation,calcination temperature was optimized at 850℃for 6h,whereas for dense morphology the sintering of the ceramic was carried out at 1120℃for 4h.X-ray diffraction XRD analysis confirmed the formation of single phase with orthorhombic structure at room temperature.Impedance analysis and AC conductivity studies of the KNN sample was carried out in the temperature range of 703-773 K.Impedance study showed the increase in conducting behavior at higher temperature.The temperature dependence of AC conductivity indicated that the conduction process is due to doubly ionized oxygen vacancies in the higher temperature region.展开更多
文摘In the present investigation an effort has been made to understand the thermal decomposition and burn rate characteristics of AP as oxidizer and PVC and HTPB as fuel binder in composite solid propellant. The burning rate study has been carried out at ambient and different pressures of 2.068 Mpa, 4.760 Mpa,6.895 Mpa. The mechanism of thermal decomposition of each composition have also been determined by NETZSCH simultaneous thermal analyser, comprising differential scanning calorimeter(DSC) and thermo-gravimetric analyser(TGA). An effort has been made to study the burn rate and decomposition of fuel binder and oxidizer in presence of Fe_2O_3 and also their overall impact on combustion of propellant.
文摘Thixocasting requires manufacturing of billets with non-dendritic microstructure.Aluminum alloy A356 billets were produced by rheocasting in a mould placed inside a linear electromagnetic stirrer.Subsequent heat treatment was used to produce a transition from rosette to globular microstructure.The current and the duration of stirring were explored as control parameters.Simultaneous induction heating of the billet during stirring was quantified using experimentally determined thermal profiles.The effect of processing parameters on the dendrite fragmentation was discussed.Corresponding computational modeling of the process was performed using phase-field modeling of alloy solidification in order to gain insight into the process of morphological changes of a solid during this process.A non-isothermal alloy solidification model was used for simulations.The morphological evolution under such imposed thermal cycles was simulated and compared with experimentally determined one.Suitable scaling using the thermosolutal diffusion distances was used to overcome computational difficulties in quantitative comparison at system scale.The results were interpreted in the light of existing theories of microstructure refinement and globularisation.
基金The financial support from Ministry of Mines,TIFAC,Department of Science and Technology and Defense Research and Development Organization
文摘The development work for producing an automobile component by thixocasting using A356.2 alloy was introduced.As the first step,the alloy was electromagnetically stirred and solidified to produce a billet with non-dendritic microstructure.The microstructure depended on several process parameters such as stirring intensity,stirring frequency,cooling rate,and melt initial superheat.Through a series of computational studies and controlled experiments,a set of process parameters were identified to produce the best microstructures.Reheating of a billet with non-dendritic microstructure to a semisolid temperature was the next step for thixo-casting of the components.The reheating process was characterized for various reheating cycles using a vertical-type reheating machine.The induction heating cycle was optimized to obtain a near-uniform temperature distribution in radial as well as axial direction of the billet,and the heating was continued until the liquid fraction reached about 50%.These parameters were determined with the help of a computational fluid dynamics(CFD) model of die filling and solidification of the semisolid alloy.The heated billets were subsequently thixo-cast into automobile components using a real-time controlled die casting machine.The results show that the castings are near net shape,free from porosity,good surface finish and have superior mechanical properties compared to those produced by conventional die casting processes using the same alloy.
文摘Objective Fenvalerate (20% EC) is a synthetic pyrethroid, which is commonly used in India by farmers for the protection of many food and vegetable crops against a wide variety of insects. However, its inhalation toxicity data is very limited in the literature due to the fact that the exposure levels associated with these effects were usually not reported. Hence, inhalation exposure was carried out to investigate the hepatotoxic effects. Method Adult male rats were exposed to fen for 4 h/day, 5 days a week for 90 days by using Flow Past Nose Only Inhalation Chamber. Sham treated control rats were exposed to compressed air in the inhalation chamber for the same period. Results The results indicated hepatomegaly, increased activities of serum clinical enzymes (indicative of liver damage/dysfunction) along with pronounced histopathological damage of liver. Conclusion The hepatotoxic potential of formulated Fen (20% EC) in rats exposed by nose only inhalation is being reported for the first time and warrant adequate safety measures for human beings exposed to this insecticide, particularly by inhalation route.
文摘In this paper, generalized dual-phase-lag (DPL) model has been studied for the numerical analysis of spatial variation of temperature within living biological tissues during thermal therapy applications. A new hybrid numerical scheme based on finite difference scheme and Chebyshev wavelet Galerkin method are used to solve the generalized DPL model with constant heat flux boundary condition. Multi-resolution and multi-scale computational property of Chebyshev wavelet in the present case localizes small scale variations of solution and fast switching of functional bases. Our study demonstrates that due to presence of coupling factor (convection–perfusion), generalized DPL model predicts lower temperature than classical DPL and Pennes model at the tumor position. Higher values of phase lag times results in lower temperature at the tumor position. But, in case of variation of phase lag time due to temperature gradient, the nature of temperature profile also depends on the spatial coordinate. The effect of the blood temperature, porosity and interfacial convective heat transfer on temperature distribution has been investigated. It is found that larger values of porosity and interfacial convective heat transfer results in lower temperature at the tumor position. Also, both porosity and interfacial convective heat transfer are pronounced more at higher values. The whole analysis is presented in dimensionless form.
文摘Lead free(K_(0.5)Na_(0.5))NbO_(3)(KNN)ceramics were prepared by conventional solid state reaction route.For single perovskite phase formation,calcination temperature was optimized at 850℃for 6h,whereas for dense morphology the sintering of the ceramic was carried out at 1120℃for 4h.X-ray diffraction XRD analysis confirmed the formation of single phase with orthorhombic structure at room temperature.Impedance analysis and AC conductivity studies of the KNN sample was carried out in the temperature range of 703-773 K.Impedance study showed the increase in conducting behavior at higher temperature.The temperature dependence of AC conductivity indicated that the conduction process is due to doubly ionized oxygen vacancies in the higher temperature region.
