A new complex, {[Cd（BIDPT）（NBA）]}n（1）, was synthesized from the selfassembly of BIDPT（BIDPT = 4,4?-bis（imidazol-l-yl）diphenyl thioether） and H2NBA（H2 NBA = 4,4?-azanediyldibenzoic acid） ligands with Cd（Ⅱ...A new complex, {[Cd（BIDPT）（NBA）]}n（1）, was synthesized from the selfassembly of BIDPT（BIDPT = 4,4?-bis（imidazol-l-yl）diphenyl thioether） and H2NBA（H2 NBA = 4,4?-azanediyldibenzoic acid） ligands with Cd（Ⅱ）. 1 was characterized by infrared spectroscopy, powder X-ray diffraction, elemental analysis, and thermogravimetry measurement. 1 crystallizes in monoclinic system, space group P21/c with a = 8.8204（1）, b = 29.835（3）, c = 10.3813（1） ?, β = 96.180（2）°, V = 2730.7（5） ?3, Z = 4, C32H22CdN5O4S, Mr = 685.01, Dc = 1.666 g/cm3, μ = 0.926 mm-1, R = 0.0548 and wR = 0.1528. 1 features a parallel structure with 3-connected hcb network and the adjacent 2 D networks are stacked together via C–H···π interaction to form a 3 D network. Its application in detecting metal cations and inorganic anions was explored. 1 exhibits excellent photoluminescence sensing for Fe3+ and Cr2O72- ions. And the mechanism of quenching is also studied.展开更多
The title complex, [Y（sip）（H2O）4], （sip = 5-sulfoisophthalate）, has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray analysis. The crystal belongs to the orthorhombic...The title complex, [Y（sip）（H2O）4], （sip = 5-sulfoisophthalate）, has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray analysis. The crystal belongs to the orthorhombic system, space group Pna21, a = 7.235（4）, b = 16.456（5）, c = 10.316（3） A, V = 1228.2（9） A^3, Z = 4, Mr = 404.14, Dc = 2.186 g/cm63, F（000） = 808,μ= 4.979 mm^-1, the final R = 0.0474 and wR = 0.1125 for 2122 observed reflections with I 〉 2σ（I）. The structural analysis shows that the intermolecular hydrogen bonds and π-π interactions result in a three-dimensional supramolecular structure. The complex shows intense luminescence in solid state at room temperature.展开更多
A new Cu(Ⅱ)coordination polymer,{[Cu3(oba)2(μ^3-OH)2(H2O)2].6H2O}n(H2 oba=4,4’-oxydibenzoic acid),was synthesized by the solvothermal route and characterized by IR,TGA and XRD.The complex crystallizes in the monocl...A new Cu(Ⅱ)coordination polymer,{[Cu3(oba)2(μ^3-OH)2(H2O)2].6H2O}n(H2 oba=4,4’-oxydibenzoic acid),was synthesized by the solvothermal route and characterized by IR,TGA and XRD.The complex crystallizes in the monoclinic system,space group P21/c with a=5.957(6),b=29.746(3),c=9.351(7)A,β=125.709(4)°,V=1345.4(2)A3,Z=2,C28H36Cu3O20,Mr=883.09,Dc=1.913 g/cm^3,F(000)=782,μ=2.427 mm-1,R=0.0780 and wR=0.1688 for 3120 observed reflections with I>2σ(I).The complex forms a 3D framework based on rare infinite rod-shaped secondary building units(SBUs),and C-H…πinteractions play an important role in stabilizing the 3D supramolecular architecture.It shows excellent catalytic activities for the degradation of safranin O(SO)and methylene blue(MB)dyes in aqueous solution under UV light irradiation.Furthermore,the apparent rate constants have also been investigated.展开更多
基金supported by Key Projects of Natural Science Research in Universities of Anhui Province(No.KJ2018A0409)National Undergraduate Training Programs for Innovation and Entrepreneurship(No.201810375012,201810375039)
文摘A new complex, {[Cd（BIDPT）（NBA）]}n（1）, was synthesized from the selfassembly of BIDPT（BIDPT = 4,4?-bis（imidazol-l-yl）diphenyl thioether） and H2NBA（H2 NBA = 4,4?-azanediyldibenzoic acid） ligands with Cd（Ⅱ）. 1 was characterized by infrared spectroscopy, powder X-ray diffraction, elemental analysis, and thermogravimetry measurement. 1 crystallizes in monoclinic system, space group P21/c with a = 8.8204（1）, b = 29.835（3）, c = 10.3813（1） ?, β = 96.180（2）°, V = 2730.7（5） ?3, Z = 4, C32H22CdN5O4S, Mr = 685.01, Dc = 1.666 g/cm3, μ = 0.926 mm-1, R = 0.0548 and wR = 0.1528. 1 features a parallel structure with 3-connected hcb network and the adjacent 2 D networks are stacked together via C–H···π interaction to form a 3 D network. Its application in detecting metal cations and inorganic anions was explored. 1 exhibits excellent photoluminescence sensing for Fe3+ and Cr2O72- ions. And the mechanism of quenching is also studied.
基金Supported by the National Natural Science Foundation of China (20571039, 20171020) and the Ministry of Education of China (20050284031)
文摘The title complex, [Y（sip）（H2O）4], （sip = 5-sulfoisophthalate）, has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray analysis. The crystal belongs to the orthorhombic system, space group Pna21, a = 7.235（4）, b = 16.456（5）, c = 10.316（3） A, V = 1228.2（9） A^3, Z = 4, Mr = 404.14, Dc = 2.186 g/cm63, F（000） = 808,μ= 4.979 mm^-1, the final R = 0.0474 and wR = 0.1125 for 2122 observed reflections with I 〉 2σ（I）. The structural analysis shows that the intermolecular hydrogen bonds and π-π interactions result in a three-dimensional supramolecular structure. The complex shows intense luminescence in solid state at room temperature.
基金supported by Key Projects of Natural Science Research in Universities of Anhui Province(No.KJ2018A0409)National Undergraduate Training Programs for Innovation and Entrepreneurship(No.201810375012+1 种基金201810375039)Jiangsu Overseas Visiting Scholar Program for University Prominent Young&Middle-aged Teachers and Presidents。
文摘A new Cu(Ⅱ)coordination polymer,{[Cu3(oba)2(μ^3-OH)2(H2O)2].6H2O}n(H2 oba=4,4’-oxydibenzoic acid),was synthesized by the solvothermal route and characterized by IR,TGA and XRD.The complex crystallizes in the monoclinic system,space group P21/c with a=5.957(6),b=29.746(3),c=9.351(7)A,β=125.709(4)°,V=1345.4(2)A3,Z=2,C28H36Cu3O20,Mr=883.09,Dc=1.913 g/cm^3,F(000)=782,μ=2.427 mm-1,R=0.0780 and wR=0.1688 for 3120 observed reflections with I>2σ(I).The complex forms a 3D framework based on rare infinite rod-shaped secondary building units(SBUs),and C-H…πinteractions play an important role in stabilizing the 3D supramolecular architecture.It shows excellent catalytic activities for the degradation of safranin O(SO)and methylene blue(MB)dyes in aqueous solution under UV light irradiation.Furthermore,the apparent rate constants have also been investigated.
