A facile and convenient one-pot synthesis method of substituted cyclopropanes in water has been developed. A series of 1,1-disubstituted cyclopropanes 3 were synthesized from the reaction of β-dicarbonyl compounds 1 ...A facile and convenient one-pot synthesis method of substituted cyclopropanes in water has been developed. A series of 1,1-disubstituted cyclopropanes 3 were synthesized from the reaction of β-dicarbonyl compounds 1 with 1,2-dibromoethane 2, in very high yields catalyzed by tetrabutylammonium bromide（TBAB） at 50 ℃ in the presence of K2CO3 in water. The catalyst TBAB in the aqueous phase can be reused after the separation of organic products.展开更多
从无人机视角进行目标检测,面临图像目标小、分布密集、类别不均衡等难点,且由于无人机的硬件条件限制了模型的规模,导致模型的准确率偏低。提出一种融合多种注意力机制的YOLOv8s改进模型,在骨干网络中引入感受野注意力卷积和CBAM(conce...从无人机视角进行目标检测,面临图像目标小、分布密集、类别不均衡等难点,且由于无人机的硬件条件限制了模型的规模,导致模型的准确率偏低。提出一种融合多种注意力机制的YOLOv8s改进模型,在骨干网络中引入感受野注意力卷积和CBAM(concentration-based attention module)注意力机制改进卷积模块,解决注意力权重参数在感受野特征中共享问题的同时,在通道和空间维度加上注意力权重,增强特征提取能力;通过引入大型可分离卷积注意力思想,改造空间金字塔池化层,增加不同层级特征间的信息交融;优化颈部结构,增加具有丰富小目标语义信息的特征层;使用inner-IoU损失函数的思想改进MPDIoU(minimum point distance based IoU)函数,以innerMPDIoU代替原损失函数,提升对困难样本的学习能力。实验结果表明,改进后的YOLOv8s模型在VisDrone数据集上mAP、P、R分别提升了16.1%、9.3%、14.9%,性能超过YOLOv8m,可以有效应用于无人机平台上的目标检测任务。展开更多
基金Supported by the National Natural Science Foundation of China(Nos.20572013, 20711130229)the Ministry of Educa-tion of China(No.105061).
文摘A facile and convenient one-pot synthesis method of substituted cyclopropanes in water has been developed. A series of 1,1-disubstituted cyclopropanes 3 were synthesized from the reaction of β-dicarbonyl compounds 1 with 1,2-dibromoethane 2, in very high yields catalyzed by tetrabutylammonium bromide（TBAB） at 50 ℃ in the presence of K2CO3 in water. The catalyst TBAB in the aqueous phase can be reused after the separation of organic products.
文摘从无人机视角进行目标检测,面临图像目标小、分布密集、类别不均衡等难点,且由于无人机的硬件条件限制了模型的规模,导致模型的准确率偏低。提出一种融合多种注意力机制的YOLOv8s改进模型,在骨干网络中引入感受野注意力卷积和CBAM(concentration-based attention module)注意力机制改进卷积模块,解决注意力权重参数在感受野特征中共享问题的同时,在通道和空间维度加上注意力权重,增强特征提取能力;通过引入大型可分离卷积注意力思想,改造空间金字塔池化层,增加不同层级特征间的信息交融;优化颈部结构,增加具有丰富小目标语义信息的特征层;使用inner-IoU损失函数的思想改进MPDIoU(minimum point distance based IoU)函数,以innerMPDIoU代替原损失函数,提升对困难样本的学习能力。实验结果表明,改进后的YOLOv8s模型在VisDrone数据集上mAP、P、R分别提升了16.1%、9.3%、14.9%,性能超过YOLOv8m,可以有效应用于无人机平台上的目标检测任务。
