Reaction of homoleptic yttrium tris-alkyl complex YR3 (R=CH2C6H4NMe2-o) with 1 equivalent of amine bis(phenol)s LH2 (L=Me2NCH2CH2N(CH2-(2-O-C6H2-But2-3,5))2) afforded the solvent-free yttrium alkyl complex LYR (1),whi...Reaction of homoleptic yttrium tris-alkyl complex YR3 (R=CH2C6H4NMe2-o) with 1 equivalent of amine bis(phenol)s LH2 (L=Me2NCH2CH2N(CH2-(2-O-C6H2-But2-3,5))2) afforded the solvent-free yttrium alkyl complex LYR (1),which has been characterized with elemental analysis,1H NMR and IR spectra,and structural determination. The coordination geometry around the center metal atom can be best de-scribed as a distorted octahedron. It was found that complex 1 can be used as an efficient catalyst for the Tishchenko reaction.展开更多
基金the National Natural Science Foundation of China (Grant Nos.20771078 and 20632040)Natural Science Foundation of Jiangsu Province (Grant No. BK2007505)Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (Grant No.07KJA15014)
文摘Reaction of homoleptic yttrium tris-alkyl complex YR3 (R=CH2C6H4NMe2-o) with 1 equivalent of amine bis(phenol)s LH2 (L=Me2NCH2CH2N(CH2-(2-O-C6H2-But2-3,5))2) afforded the solvent-free yttrium alkyl complex LYR (1),which has been characterized with elemental analysis,1H NMR and IR spectra,and structural determination. The coordination geometry around the center metal atom can be best de-scribed as a distorted octahedron. It was found that complex 1 can be used as an efficient catalyst for the Tishchenko reaction.
