Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible devices.However,the power conversion efficiency(PCE) of f...Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible devices.However,the power conversion efficiency(PCE) of flexible Sb_(2)Se_(3) photovoltaic devices is temporarily limited by the complicated intrinsic defects and the undesirable contact interfaces.Herein,a high-quality Sb_(2)Se_(3) absorber layer with large crystal grains and benign [hkl] growth orientation can be first prepared on a Mo foil substrate.Then NaF intermediate layer is introduced between Mo and Sb_(2)Se_(3),which can further optimize the growth of Sb_(2)Se_(3)thin film.Moreover,positive Na ion diffusion enables it to dramatically lower barrier height at the back contact interface and passivate harmful defects at both bulk and heterojunction.As a result,the champion substrate structured Mo-foil/Mo/NaF/Sb_(2)Se_(3)/CdS/ITO/Ag flexible thin-film solar cell delivers an obviously higher efficiency of 8.03% and a record open-circuit voltage(V_(OC)) of 0.492 V.This flexible Sb_(2)Se_(3) device also exhibits excellent stability and flexibility to stand large bending radius and multiple bending times,as well as superior weak light photo-response with derived efficiency of 12.60%.This work presents an effective strategy to enhance the flexible Sb_(2)Se_(3) device performance and expand its potential photovoltaic applications.展开更多
Antimony selenide(Sb_(2)Se_(3))is a potential photovoltaic(PV)material for next-generation solar cells and has achieved great development in the last several years.The properties of Sb_(2)Se_(3)absorber and back conta...Antimony selenide(Sb_(2)Se_(3))is a potential photovoltaic(PV)material for next-generation solar cells and has achieved great development in the last several years.The properties of Sb_(2)Se_(3)absorber and back contact influence the PV performances of Sb_(2)Se_(3)solar cells.Hence,optimization of back contact characteristics and absorber orientation are crucial steps in raising the power conversion efficiency(PCE)of Sb_(2)Se_(3)solar cells.In this work,MoO2was introduced as an intermediate layer(IL)in Sb_(2)Se_(3)solar cells,and comparative investigations were conducted.The growth of(211)-oriented Sb_(2)Se_(3)with large grains was facilitated by introducing the MoO2IL with suitable thickness.The MoO2IL substantially lowered the back contact barrier and prevented the formation of voids at the back contact,which reduced the thickness of the MoSe2interface layer,inhibited carrier recombination,and minimized bulk and interfacial defects in devices.Subsequently,significant optimization enhanced the open-circuit voltage(VOC)of solar cells from 0.481 V to 0.487 V,short-circuit current density(JSC)from 23.81 m A/cm^(2)to 29.29 m A/cm^(2),and fill factor from 50.28%to 57.10%,which boosted the PCE from 5.75%to 8.14%.展开更多
基于河南省111个气象站1971—2010年的逐日降水数据,分析了河南省夏季不同强度降水事件的时空演特征。结果表明:近40 a来,河南省夏季降雨量整体呈上升趋势,各等级降水事件对夏季降雨量贡献率依次是:小雨、中雨、大雨及暴雨,其中小雨和...基于河南省111个气象站1971—2010年的逐日降水数据,分析了河南省夏季不同强度降水事件的时空演特征。结果表明:近40 a来,河南省夏季降雨量整体呈上升趋势,各等级降水事件对夏季降雨量贡献率依次是:小雨、中雨、大雨及暴雨,其中小雨和中雨对夏季降雨量的贡献呈下降趋势,而大雨和暴雨对夏季降雨量的贡献呈上升趋势;大部分区域在降雨量增加同时,降雨日数却在减少,即降雨呈现出极端化发展的趋势。借助小波分析表明,降雨量、降雨日数和降雨强度均表现出2~3 a左右的低频振荡周期,且降雨量和降雨日数的周期具有较好的一致性。为探究降水变化成因,本文对河南省夏季旱涝年大气环流场进行了合成分析,分析表明:偏旱年其500 h Pa高空的100°E)以东大部分区域为位势高度正距平区,不利于东部的冷空气南下,850 h Pa低空盛行偏北风且多下沉运动,水汽较难输送到河南省上空;而偏涝年高空110°E以东为位势高度负距平区,短波槽活动频繁,110°E以西为高压脊区,其低空多偏南风,有利于孟加拉湾的暖湿气流北上,配合较强的垂直上升运动,旺盛的对流和充足的水汽均利于降水过程的发生。展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.62104156,62074102)the Guangdong Basic and Applied Basic Research Foundation(Grant Nos.2023A1515011256,2022A1515010979)China+1 种基金Science and Technology plan project of Shenzhen(Grant Nos.20220808165025003,20200812000347001)Chinasupported by the open foundation of Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials,State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures,Guangxi University(Grant No.2022GXYSOF13)。
文摘Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible devices.However,the power conversion efficiency(PCE) of flexible Sb_(2)Se_(3) photovoltaic devices is temporarily limited by the complicated intrinsic defects and the undesirable contact interfaces.Herein,a high-quality Sb_(2)Se_(3) absorber layer with large crystal grains and benign [hkl] growth orientation can be first prepared on a Mo foil substrate.Then NaF intermediate layer is introduced between Mo and Sb_(2)Se_(3),which can further optimize the growth of Sb_(2)Se_(3)thin film.Moreover,positive Na ion diffusion enables it to dramatically lower barrier height at the back contact interface and passivate harmful defects at both bulk and heterojunction.As a result,the champion substrate structured Mo-foil/Mo/NaF/Sb_(2)Se_(3)/CdS/ITO/Ag flexible thin-film solar cell delivers an obviously higher efficiency of 8.03% and a record open-circuit voltage(V_(OC)) of 0.492 V.This flexible Sb_(2)Se_(3) device also exhibits excellent stability and flexibility to stand large bending radius and multiple bending times,as well as superior weak light photo-response with derived efficiency of 12.60%.This work presents an effective strategy to enhance the flexible Sb_(2)Se_(3) device performance and expand its potential photovoltaic applications.
基金supported by the National Natural Science Foundation of China(62074102)the Guangdong Basic and Applied Basic Research Foundation(2022A1515010979)+1 种基金the Key Project of Department of Education of Guangdong Province(2018KZDXM059)the Science and Technology plan project of Shenzhen(20220808165025003)。
文摘Antimony selenide(Sb_(2)Se_(3))is a potential photovoltaic(PV)material for next-generation solar cells and has achieved great development in the last several years.The properties of Sb_(2)Se_(3)absorber and back contact influence the PV performances of Sb_(2)Se_(3)solar cells.Hence,optimization of back contact characteristics and absorber orientation are crucial steps in raising the power conversion efficiency(PCE)of Sb_(2)Se_(3)solar cells.In this work,MoO2was introduced as an intermediate layer(IL)in Sb_(2)Se_(3)solar cells,and comparative investigations were conducted.The growth of(211)-oriented Sb_(2)Se_(3)with large grains was facilitated by introducing the MoO2IL with suitable thickness.The MoO2IL substantially lowered the back contact barrier and prevented the formation of voids at the back contact,which reduced the thickness of the MoSe2interface layer,inhibited carrier recombination,and minimized bulk and interfacial defects in devices.Subsequently,significant optimization enhanced the open-circuit voltage(VOC)of solar cells from 0.481 V to 0.487 V,short-circuit current density(JSC)from 23.81 m A/cm^(2)to 29.29 m A/cm^(2),and fill factor from 50.28%to 57.10%,which boosted the PCE from 5.75%to 8.14%.
文摘基于河南省111个气象站1971—2010年的逐日降水数据,分析了河南省夏季不同强度降水事件的时空演特征。结果表明:近40 a来,河南省夏季降雨量整体呈上升趋势,各等级降水事件对夏季降雨量贡献率依次是:小雨、中雨、大雨及暴雨,其中小雨和中雨对夏季降雨量的贡献呈下降趋势,而大雨和暴雨对夏季降雨量的贡献呈上升趋势;大部分区域在降雨量增加同时,降雨日数却在减少,即降雨呈现出极端化发展的趋势。借助小波分析表明,降雨量、降雨日数和降雨强度均表现出2~3 a左右的低频振荡周期,且降雨量和降雨日数的周期具有较好的一致性。为探究降水变化成因,本文对河南省夏季旱涝年大气环流场进行了合成分析,分析表明:偏旱年其500 h Pa高空的100°E)以东大部分区域为位势高度正距平区,不利于东部的冷空气南下,850 h Pa低空盛行偏北风且多下沉运动,水汽较难输送到河南省上空;而偏涝年高空110°E以东为位势高度负距平区,短波槽活动频繁,110°E以西为高压脊区,其低空多偏南风,有利于孟加拉湾的暖湿气流北上,配合较强的垂直上升运动,旺盛的对流和充足的水汽均利于降水过程的发生。
