A novel rapid and continuous process has developed for the synthesis of nitrogen-doped TiO2（N-TiO2）with flame spray pyrolysis（FSP） method. The nitrogen incorporation into TiO2 was achieved by a facile modification...A novel rapid and continuous process has developed for the synthesis of nitrogen-doped TiO2（N-TiO2）with flame spray pyrolysis（FSP） method. The nitrogen incorporation into TiO2 was achieved by a facile modification（addition of dilute nitric acid） in the precursor for the synthesis. The catalysts were characterized by X-ray diffraction, Raman spectroscopy, transmission electron microscopy, diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. The doping of nitrogen into the TiO2 was confirmed by X-ray photoelectron spectroscopy（XPS） and energy dispersive X-ray（EDX） spectroscopy. The UV-vis spectra of the modified catalysts（with primary N source） exhibited band-gap narrowing for 4 N-TiO2 with band gap energy of 2.89 eV, which may be due to the presence of nitrogen in TiO2 structure. The introduction of secondary N-source（urea） into TiO2 crystal lattice results in additional reduction of the band gap energy to 2.68 eV and shows a significant improvement of visible light absorption. The N-TiO2 nanoparticles modified by using secondary N-source showed significant photocatalytic activity under visible light much higher than TiO2. The higher activity is attributed to the synergetic interaction of nitrogen with the TiO2 lattice. The lowering of the band-gap energy for the flame made N-doped TiO2 materials implies that the nitrogen doping in TiO2 by aerosol method is highly effective in extending the optical response of TiO2 in the visible region. The nitrogen atomic percentage has increased monotonically（0.09%-0.15%）with the increase in primary nitrogen source（nitric acid）, and significantly boosted to 0.97% when secondary nitrogen source（urea） was introduced. The highest rate of phenol degradation was obtained for catalysts with secondary N source due to increase in N content in the catalyst.展开更多
基金the U.S. EPA/Pegasus contract (contract number EP-C-11-006) for financial support of this work through the scholarship to Siva Nagi Reddy Inturi
文摘A novel rapid and continuous process has developed for the synthesis of nitrogen-doped TiO2（N-TiO2）with flame spray pyrolysis（FSP） method. The nitrogen incorporation into TiO2 was achieved by a facile modification（addition of dilute nitric acid） in the precursor for the synthesis. The catalysts were characterized by X-ray diffraction, Raman spectroscopy, transmission electron microscopy, diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. The doping of nitrogen into the TiO2 was confirmed by X-ray photoelectron spectroscopy（XPS） and energy dispersive X-ray（EDX） spectroscopy. The UV-vis spectra of the modified catalysts（with primary N source） exhibited band-gap narrowing for 4 N-TiO2 with band gap energy of 2.89 eV, which may be due to the presence of nitrogen in TiO2 structure. The introduction of secondary N-source（urea） into TiO2 crystal lattice results in additional reduction of the band gap energy to 2.68 eV and shows a significant improvement of visible light absorption. The N-TiO2 nanoparticles modified by using secondary N-source showed significant photocatalytic activity under visible light much higher than TiO2. The higher activity is attributed to the synergetic interaction of nitrogen with the TiO2 lattice. The lowering of the band-gap energy for the flame made N-doped TiO2 materials implies that the nitrogen doping in TiO2 by aerosol method is highly effective in extending the optical response of TiO2 in the visible region. The nitrogen atomic percentage has increased monotonically（0.09%-0.15%）with the increase in primary nitrogen source（nitric acid）, and significantly boosted to 0.97% when secondary nitrogen source（urea） was introduced. The highest rate of phenol degradation was obtained for catalysts with secondary N source due to increase in N content in the catalyst.
