A rapid, inexpensive and laboratory friendly method was developed for analysis of off-flavor/odor compounds in fresh and salt water using gas chromatography with chemical ionization-tandem mass spectrometry. Off-flavo...A rapid, inexpensive and laboratory friendly method was developed for analysis of off-flavor/odor compounds in fresh and salt water using gas chromatography with chemical ionization-tandem mass spectrometry. Off-flavor/odor compounds, included geosmin, 2- methylisobomeol （MIB）, 2-isobutyl-3-methyoxypyrazine （IBMP）, and 2-isopropyl-3-methoxypyrazine （IPMP）. Using this method, a single sample can be extracted within minutes using only 1 mL of organic solvent. The ion transitions for IPMP, IBMP, MIB, and geosmin were 153 〉 121, 167 〉 125, 152 〉 95, and 165 〉 109, respectively. The linearity of this method for analyzing MIB ranged from 4 to 200ng·L^-1, and from 0.8 to 200ng·L^-1 for the other analytes. Method recoveries ranged from 97% to 111% and percent relative standard deviations ranged from 3% to 9%, indicating that the method is accurate, precise, and reliable.展开更多
文摘A rapid, inexpensive and laboratory friendly method was developed for analysis of off-flavor/odor compounds in fresh and salt water using gas chromatography with chemical ionization-tandem mass spectrometry. Off-flavor/odor compounds, included geosmin, 2- methylisobomeol （MIB）, 2-isobutyl-3-methyoxypyrazine （IBMP）, and 2-isopropyl-3-methoxypyrazine （IPMP）. Using this method, a single sample can be extracted within minutes using only 1 mL of organic solvent. The ion transitions for IPMP, IBMP, MIB, and geosmin were 153 〉 121, 167 〉 125, 152 〉 95, and 165 〉 109, respectively. The linearity of this method for analyzing MIB ranged from 4 to 200ng·L^-1, and from 0.8 to 200ng·L^-1 for the other analytes. Method recoveries ranged from 97% to 111% and percent relative standard deviations ranged from 3% to 9%, indicating that the method is accurate, precise, and reliable.
