Nine limiting binaries of Al 2O 3 SiO 2 Re 2O 3 (Re=Nd,Sm,Gd and La) system are assessed. The binary diagrams or experimental information from Toropov, Mizuno, Aramaki, Bondar, Rolin and Coutures are optimized ...Nine limiting binaries of Al 2O 3 SiO 2 Re 2O 3 (Re=Nd,Sm,Gd and La) system are assessed. The binary diagrams or experimental information from Toropov, Mizuno, Aramaki, Bondar, Rolin and Coutures are optimized with the substitutional model of Kaufman and Nesor and the approximate formula of fusion free energy for rare earth element oxides of Wu and Pelton. The extracted Gibbs free energies of pure solid oxides and stoichiometric phases and the solution parameters are used to estimate the corresponding binaries, liquidus surfaces and a series of isothermal sections of four ternaries Al 2O 3 SiO 2 Nd 2O 3, Al 2O 3 SiO 2 Sm 2O 3, Al 2O 3 SiO 2 Gd 2O 3, and Al 2O 3 SiO 2 La 2O 3. In the Al 2O 3 SiO 2 Gd 2O 3 system samples as fired at exact temperature with different compositions were analyzed by X ray diffractometer and the detected results are fitted with the calculation of isothermal sections.展开更多
文摘Nine limiting binaries of Al 2O 3 SiO 2 Re 2O 3 (Re=Nd,Sm,Gd and La) system are assessed. The binary diagrams or experimental information from Toropov, Mizuno, Aramaki, Bondar, Rolin and Coutures are optimized with the substitutional model of Kaufman and Nesor and the approximate formula of fusion free energy for rare earth element oxides of Wu and Pelton. The extracted Gibbs free energies of pure solid oxides and stoichiometric phases and the solution parameters are used to estimate the corresponding binaries, liquidus surfaces and a series of isothermal sections of four ternaries Al 2O 3 SiO 2 Nd 2O 3, Al 2O 3 SiO 2 Sm 2O 3, Al 2O 3 SiO 2 Gd 2O 3, and Al 2O 3 SiO 2 La 2O 3. In the Al 2O 3 SiO 2 Gd 2O 3 system samples as fired at exact temperature with different compositions were analyzed by X ray diffractometer and the detected results are fitted with the calculation of isothermal sections.
