Soil potentially hazardous metal(PHM)is continually attracting public attention worldwide,due to its highly toxic properties and potentially huge damage to human being through food chain.Phytoremediation is an effecti...Soil potentially hazardous metal(PHM)is continually attracting public attention worldwide,due to its highly toxic properties and potentially huge damage to human being through food chain.Phytoremediation is an effective and eco-friendly way in remediation technology.A pot experiment was carried out to investigate the effect of different organic materials(biogas residue(BR),mushroom residue(MR),and bamboo-shoot shell(BS))application on phytoremediation of two PHM-contaminated soils(Fuyang soil as‘heavily-polluted soil’and Wenzhou soil as‘moderately-polluted soil’,respectively)by Sedum alfrecdii Hance.The results indicated:1)for moderately-polluted soil,the 5%BR treatment had the strongest activation to Cu and Zn,for heavily-polluted soil,1%BS treatment had the highest activation effect for Cu,Zn,Pb and Cd.2)the above-ground biomass of Sedum alfredii Hance increased with the addition rate of organic materials.3)for Cd uptake of Sedum alfredii Hance in moderately-polluted soil,only 1%BS treatment had a better accumulation effect,compared to the control,for Zn element,MR treatments were weaker than the control,while other treatments were better than the control,of which 5%BR,1%BS and 5%BS accumulated more Zn element by 39.6%,32.6%and 23.8%,respectively;in heavily-polluted soil,the treatments of 5%BS,1%BR and 5%BR accumulated more Cd than the control by 12.9%,12.8%and 6.2%,respectively,the treatments with organic materials addition promoted Zn accumulation in shoots of Sedum alfredii Hance,and the best treatment was 5%BS.Therefore,an appropriate application rate of BS and BR could improve the remediation efficiency for Zn/Cd contaminated soils by Sedum alfredii Hance.展开更多
A robust three-dimensional(3D)interconnected sulfur host and a polysulfide-proof interlayer are key components in high-performance Li–S batteries.Herein,cellulose-based 3D hierarchical porous carbon(HPC)and two-dimen...A robust three-dimensional(3D)interconnected sulfur host and a polysulfide-proof interlayer are key components in high-performance Li–S batteries.Herein,cellulose-based 3D hierarchical porous carbon(HPC)and two-dimensional(2D)lamellar porous carbon(LPC)are employed as the sulfur host and polysulfide-proof inter-layer,respectively,for a Li–S battery.The 3D HPC displays a cross-linked macroporous structure,which allows high sulfur loading and restriction capability and provides unobstructed electrolyte diffusion channels.With a stackable carbon sheet of 2D LPC that has a large plane view size and is ultrathin and porous,the LPC-coated separator effectively inhibits polysulfides.An optimized combination of the HPC and LPC yields an electrode structure that effectively protects the lithium anode against corrosion by polysulfides,giving the cell a high ca-pacity of 1339.4 mAh g^(-1) and high stability,with a capacity decay rate of 0.021% per cycle at 0.2C.This work provides a new understanding of biomaterials and offers a novel strategy to improve the performance of Li–S batteries for practical applications.展开更多
基金the National College Students’Innovation and Entrepreneurship Training Program(202110341014).
文摘Soil potentially hazardous metal(PHM)is continually attracting public attention worldwide,due to its highly toxic properties and potentially huge damage to human being through food chain.Phytoremediation is an effective and eco-friendly way in remediation technology.A pot experiment was carried out to investigate the effect of different organic materials(biogas residue(BR),mushroom residue(MR),and bamboo-shoot shell(BS))application on phytoremediation of two PHM-contaminated soils(Fuyang soil as‘heavily-polluted soil’and Wenzhou soil as‘moderately-polluted soil’,respectively)by Sedum alfrecdii Hance.The results indicated:1)for moderately-polluted soil,the 5%BR treatment had the strongest activation to Cu and Zn,for heavily-polluted soil,1%BS treatment had the highest activation effect for Cu,Zn,Pb and Cd.2)the above-ground biomass of Sedum alfredii Hance increased with the addition rate of organic materials.3)for Cd uptake of Sedum alfredii Hance in moderately-polluted soil,only 1%BS treatment had a better accumulation effect,compared to the control,for Zn element,MR treatments were weaker than the control,while other treatments were better than the control,of which 5%BR,1%BS and 5%BS accumulated more Zn element by 39.6%,32.6%and 23.8%,respectively;in heavily-polluted soil,the treatments of 5%BS,1%BR and 5%BR accumulated more Cd than the control by 12.9%,12.8%and 6.2%,respectively,the treatments with organic materials addition promoted Zn accumulation in shoots of Sedum alfredii Hance,and the best treatment was 5%BS.Therefore,an appropriate application rate of BS and BR could improve the remediation efficiency for Zn/Cd contaminated soils by Sedum alfredii Hance.
基金The authors gratefully acknowledge the financial support by the Joint Funds of the Natural Science Basic Research Project of Shaanxi Province(2021JLM-23)University Joint Project of Shaanxi Province(2021GXLH-Z-067)+3 种基金Anhui Provincial Natural Science Foundation for Outstanding Young Scholar(2208085Y05)Anhui Provincial Scientific Reuter Foundation for Returned Scholars(2022LCX030)the National Natural Science Foundation of China(51801144)Guangxi Key Labo-ratory of Low Carbon Energy Material(2021GXKLLCEM04)。
文摘A robust three-dimensional(3D)interconnected sulfur host and a polysulfide-proof interlayer are key components in high-performance Li–S batteries.Herein,cellulose-based 3D hierarchical porous carbon(HPC)and two-dimensional(2D)lamellar porous carbon(LPC)are employed as the sulfur host and polysulfide-proof inter-layer,respectively,for a Li–S battery.The 3D HPC displays a cross-linked macroporous structure,which allows high sulfur loading and restriction capability and provides unobstructed electrolyte diffusion channels.With a stackable carbon sheet of 2D LPC that has a large plane view size and is ultrathin and porous,the LPC-coated separator effectively inhibits polysulfides.An optimized combination of the HPC and LPC yields an electrode structure that effectively protects the lithium anode against corrosion by polysulfides,giving the cell a high ca-pacity of 1339.4 mAh g^(-1) and high stability,with a capacity decay rate of 0.021% per cycle at 0.2C.This work provides a new understanding of biomaterials and offers a novel strategy to improve the performance of Li–S batteries for practical applications.