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偶氮苯基小分子光控聚N-异丙基丙烯酰胺在离子液体中的自组装
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作者 李佩琪 王彩虹 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第2期32-38,共7页
偶氮苯基材料因其具有可逆的光致顺反异构特性,可调控聚合物的自组装行为而受到广泛关注。采用不同结构且广泛商业化的偶氮苯基小分子(偶氮苯(AZO)、对羟基偶氮苯(AZO-OH)、对氨基偶氮苯(AZO-NH2)、二甲基黄[AZO-N(CH_(3))_(2)])作为光... 偶氮苯基材料因其具有可逆的光致顺反异构特性,可调控聚合物的自组装行为而受到广泛关注。采用不同结构且广泛商业化的偶氮苯基小分子(偶氮苯(AZO)、对羟基偶氮苯(AZO-OH)、对氨基偶氮苯(AZO-NH2)、二甲基黄[AZO-N(CH_(3))_(2)])作为光分子开关,控制聚N-异丙基丙烯酰胺(PNIPAm)在1-乙基-3-甲基咪唑双(三氟甲基磺酰基)亚胺([C2mim][NTf_(2)])离子液体中的自组装行为,探讨不同偶氮苯基末端基元对于PNIPAm自组装相行为的影响。结果表明,偶氮苯基小分子均能有效调控PNIPAm在[C2mim][NTf_(2)]离子液体中的相变响应行为,但不同的末端基元对于PNIPAm的相变温度及相变区间影响甚微。结合原位变温红外谱图分析可知,紫外光照强化了PNIPAm与离子液体之间的相互作用,从而抑制了PNIPAm侧链间的相互聚集,这将促进紫外光照条件下“溶剂化”效应的发生,可获得更低的相变温度。 展开更多
关键词 偶氮苯 聚N-异丙基丙烯酰胺 离子液体 自组装 分子开关 相变 响应行为
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Extracting Soil Moisture from Fengyun-3D Medium Resolution Spectral Imager-Ⅱ Imagery by Using a Deep Belief Network 被引量:2
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作者 Wenwen WANG Chengming ZHANG +3 位作者 Feng li Jiaojie SONG peiqi li Yuhua ZHANG 《Journal of Meteorological Research》 SCIE CSCD 2020年第4期748-759,共12页
Obtaining continuous and high-quality soil moisture(SM) data is important in scientific research and applications,especially for agriculture, meteorology, and environmental monitoring. With the continuously increasing... Obtaining continuous and high-quality soil moisture(SM) data is important in scientific research and applications,especially for agriculture, meteorology, and environmental monitoring. With the continuously increasing number of artificial satellites in China, the acquisition of SM data from remote sensing images has received increasing attention.In this study, we constructed an SM inversion model by using a deep belief network(DBN) to extract SM data from Fengyun-3 D(FY-3 D) Medium Resolution Spectral Imager-Ⅱ(MERSI-Ⅱ) imagery;we named this model SM-DBN.The SM-DBN consists of two subnetworks: one for temperature and the other for SM. In the temperature subnetwork, bands 1, 2, 3, 4, 24, and 25 of the FY-3 D MERSI-Ⅱ imagery, which are relevant to temperature, were used as inputs while land surface temperatures(LST) obtained from ground stations were used as the expected output value when training the model. In the SM subnetwork, the input data included LSTs generated from the temperature subnetwork, normalized difference vegetation index(NDVI), and enhanced vegetation index(EVI);and the SM data obtained from ground stations were used as the expected outputs. We selected the Ningxia Hui Autonomous Region of China as the study area and used selected MERSI-Ⅱ images and in-situ observation station data from 2018 to 2019 to develop our dataset. The results of the SM-DBN were validated by using in-situ SM data as a reference, and its performance was also compared with those of the linear regression(LR) and back propagation(BP) neural network models. The overall accuracy of these models was measured by using the root mean square error(RMSE) of the differences between the model results and in-situ SM observation data. The RMSE of the LR, BP neural network, and SM-DBN models were 0.101, 0.083, and 0.032, respectively. These results suggest that the SM-DBN model significantly outperformed the other two models. 展开更多
关键词 deep learning deep belief network(DBN) Fengyun-3D(FY-3D) Medium Resolution Spectral Imager-Ⅱ(MERSI-Ⅱ)Imagery data fitting soil moisture(SM) Ningxia
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Transmission risk of asymptomatic SARS-CoV-2 infection:a systematic review and meta-analysis
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作者 Ci Zhang Chao Zhou +14 位作者 Wanqing Xu Shimin Zheng Yanxiao Gao peiqi li Luojia Deng Xuezhixing Zhang Qianxue Jiang Frank Qian Xianhong li Honghong Wang Huachun Zou Yinglin Xia Tao Wang Hui Lu Han-Zhu Qian 《Infectious Medicine》 2023年第1期11-18,共8页
Background:Global evidence on the transmission of asymptomatic SARS-CoV-2 infection needs to be synthesized.Methods:A search of 4 electronic databases(PubMed,EMBASE,Cochrane Library,and Web of Science databases)as of ... Background:Global evidence on the transmission of asymptomatic SARS-CoV-2 infection needs to be synthesized.Methods:A search of 4 electronic databases(PubMed,EMBASE,Cochrane Library,and Web of Science databases)as of January 24,2021 was performed.Preferred Reporting Items for Systematic Reviews and Meta-Analyses(PRISMA)guidelines were followed.Studies which reported the transmission rate among close contacts with asymptomatic SARS-CoV-2 cases were included,and transmission activities occurred were considered.The trans-mission rates were pooled by zero-inflated beta distribution.The risk ratios(RRs)were calculated using random-effects models.Results:Of 4923 records retrieved and reviewed,15 studies including 3917 close contacts with asymptomatic indexes were eligible.The pooled transmission rates were 1.79 per 100 person-days(or 1.79%,95%confidence interval[CI]0.41%-3.16%)by asymptomatic index,which is significantly lower than by presymptomatic(5.02%,95%CI 2.37%-7.66%;p<0.001),and by symptomatic(5.27%,95%CI 2.40%-8.15%;p<0.001).Subgroup anal-yses showed that the household transmission rate of asymptomatic index was(4.22%,95%CI 0.91%-7.52%),four times significantly higher than non-household transmission(1.03%,95%CI 0.73%-1.33%;p=0.03),and the asymptomatic transmission rate in China(1.82%,95%CI 0.11%-3.53%)was lower than in other countries(2.22%,95%CI 0.67%-3.77%;p=0.01).Conclusions:People with asymptomatic SARS-CoV-2 infection are at risk of transmitting the virus to their close contacts,particularly in household settings.The transmission potential of asymptomatic infection is lower than symptomatic and presymptomatic infections.This meta-analysis provides evidence for predict-ing the epidemic trend and promulgating vaccination and other control measures.Registered with PROS-PERO International Prospective Register of Systematic Reviews,CRD42021269446;https://www.crd.york.ac.uk/prospero/display_record.php?RecordID=269446. 展开更多
关键词 SARS-CoV-2 ASYMPTOMATIC Transmission rate Systematic review META-ANALYSIS
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