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金属/非金属元素掺杂提升原子级分散碳基催化剂的氧还原性能 被引量:1
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作者 孟鹏飞 张笑容 +1 位作者 廖世军 邓怡杰 《化学进展》 SCIE CAS CSCD 北大核心 2022年第10期2190-2201,共12页
原子级别分散的过渡金属和氮共掺杂碳基催化剂(M-N_(x)-C)具有反应活性好、选择性高、制备容易等优点,被认为是最有可能取代价格昂贵的铂催化剂用作燃料电池阴极的一类非贵金属催化剂。然而,该类催化剂在阴极侧氧还原反应过程中存在活... 原子级别分散的过渡金属和氮共掺杂碳基催化剂(M-N_(x)-C)具有反应活性好、选择性高、制备容易等优点,被认为是最有可能取代价格昂贵的铂催化剂用作燃料电池阴极的一类非贵金属催化剂。然而,该类催化剂在阴极侧氧还原反应过程中存在活性位点密度较低、耐久性不足的问题制约了其在燃料电池中的实际应用。研究表明,通过多种金属/非金属元素的掺杂调控活性位点的电子结构与空间构型可显著提升M-N_(x)-C催化剂的氧还原活性和稳定性,已成为掺杂碳基催化剂领域的热门研究课题。本文综述了近年来国内外在多种金属/非金属元素掺杂提升M-N_(x)-C碳基催化剂性能方面的主要研究工作,包括金属元素掺杂、非金属元素掺杂等研究。文章进一步总结和指出了M-N_(x)-C碳基催化剂面临的问题及挑战,并对其发展前景和未来研究方向进行了展望。 展开更多
关键词 非铂催化剂 碳基催化剂 氧还原 共掺杂 单原子催化剂
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金属有机化合物框架材料衍生M-N/C类氧还原电催化剂
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作者 余思妍 郑龙 +2 位作者 孟鹏飞 史修东 廖世军 《化学进展》 SCIE CAS CSCD 北大核心 2021年第10期1693-1705,共13页
过渡金属及氮共掺杂的碳基催化剂(M-N/C)由于具有几乎可以媲美铂的氧还原活性,已成为最为重要的一类非贵金属催化剂,被誉为最有可能在未来应用于燃料电池的一类非贵金属催化剂。金属有机化合物框架材料(MOFs)作为一种新型的结构规整的... 过渡金属及氮共掺杂的碳基催化剂(M-N/C)由于具有几乎可以媲美铂的氧还原活性,已成为最为重要的一类非贵金属催化剂,被誉为最有可能在未来应用于燃料电池的一类非贵金属催化剂。金属有机化合物框架材料(MOFs)作为一种新型的结构规整的多孔材料,具有高孔隙度和形貌尺寸可控等特点,成为制备各种高性能掺杂碳基催化剂的良好前驱体,与过渡金属、氮和碳源的复合前驱体相比,以其为原料制得的衍生M-N/C催化剂往往表现出更优越的结构与性能,具备更好的应用前景,相关研究已成为燃料电池电催化领域的热点研究课题。本文系统地介绍了近年来国内外以MOFs为前驱体制备M-N/C催化剂的相关研究工作,包括:MOFs衍生碳催化剂的制备技术,提升MOFs衍生碳催化剂结构及性能的研究以及这类催化剂表征技术的研究工作。总结和讨论了MOFs衍生M-N/C催化剂尚存的若干重要问题并提出了解决问题的可能举措,对这类催化剂的发展及应用进行了展望。 展开更多
关键词 非Pt催化剂 M-N/C 金属有机化合物框架材料 氧还原 原子级分散
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Morphology evolution and breakdown mechanism of cross-linked polyethylene(XLPE)-silicone rubber(SiR)interface induced by silicone grease diffusion 被引量:2
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作者 Zerui Li Kai Zhou +5 位作者 pengfei meng Hao Yuan Zikang Wang Yidong Chen Yuan Li Guangya Zhu 《High Voltage》 SCIE EI 2022年第4期802-811,共10页
Silicone grease(SG)is used for lubrication during cable accessory installation and can penetrate into the silicone rubber(SiR),leading to properties deterioration of the SiR.In this study,the effects of SG on the brea... Silicone grease(SG)is used for lubrication during cable accessory installation and can penetrate into the silicone rubber(SiR),leading to properties deterioration of the SiR.In this study,the effects of SG on the breakdown characteristics of the cross-linked poly-ethylene(XLPE)-SiR interface are investigated.First,the variation of the XLPE-SiR interface breakdown voltage with SG coating time is experimentally explored.The interface breakdown voltage significantly increases after SG is applied,remains stable for coating times of up to approximately 144 h and then rapidly decreases;the minimum interface breakdown voltage is lower than that without the SG coating.Next,the effects of SG on the chemical composition and surface topography of the SiR are examined by infrared spectroscopy and optical profilometry,respectively.The SG penetration does not change the functional groups of the SiR but significantly increases its surface roughness.Finally,the interface electric-field distribution after coating with SG is analysed by finite-element simulation,revealing that the residual SG at the interface distorts the interface electric field after a long coating time.The increase in the SiR surface roughness caused by SG diffusion and the interface electric-field distortion caused by the residual SG together lead to the decrease of the interface breakdown voltage. 展开更多
关键词 COATING INTERFACE DIFFUSION
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Pulse width modulation voltage source deadtime effect on partial discharge and lifetime of inverter‐fed motor insulation 被引量:2
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作者 Shakeel Akram Peng Wang +2 位作者 pengfei meng Gian Carlo Montanari Farhan Hameed Malik 《High Voltage》 SCIE EI 2022年第6期1185-1193,共9页
This paper analyses the impact of square wave pulse voltage deadtime on the partial discharge(PD)and the lifetime of turn-to-turn insulation.A bipolar repetitive pulse voltage with a deadtime of 0–10μs is produced u... This paper analyses the impact of square wave pulse voltage deadtime on the partial discharge(PD)and the lifetime of turn-to-turn insulation.A bipolar repetitive pulse voltage with a deadtime of 0–10μs is produced using double half-bridge solid-state switches having push–pull technology controlled by a field-programmable gate array.The mechanism of the discharge process at rising and falling edges of the pulse voltage before and after deadtime is analysed in detail.The discharge amplitude and PD probability at the rising/falling edges of the voltage waveform increase as the deadtime increases from 0 to 10μs due to the remanent charges.The number of PD and their intensity is higher at the first rising/falling edges of pulse voltage as compared to the second rising/falling edges for all deadtimes 0–10μs.As the deadtime increases beyond 2μs,the number of PDs increases and concentrates at a specific phase angle of rising/falling edges.These localise discharges degrade the insulation material and reduce its lifetime.This study helps to identify the inverter-fed motor insulation faults due to deadtime.It can provide guidelines to motor insulation designers to determine the limit value of deadtime to compensate PD and ensure the safer operation of such motors. 展开更多
关键词 DEAD INSULATION INVERTER
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