CONSPECTUS:Widespread in chemistry and biochemistry,chirality strongly affects the biological,chemical,material,and physical properties.As a downstream derivative,the enantiopure polymers of opposite chirality can coc...CONSPECTUS:Widespread in chemistry and biochemistry,chirality strongly affects the biological,chemical,material,and physical properties.As a downstream derivative,the enantiopure polymers of opposite chirality can cocrystallize in the stereocomplex(SC)in their enantiomeric blends or block copolymers,which endows the materials with improved physical properties and specific functions such as enhanced melting temperature,thermal stability,crystallizability,and hydrolytic resistance.展开更多
基金support of the National Natural Science Foundation of China(22073083 and 21873083).
文摘CONSPECTUS:Widespread in chemistry and biochemistry,chirality strongly affects the biological,chemical,material,and physical properties.As a downstream derivative,the enantiopure polymers of opposite chirality can cocrystallize in the stereocomplex(SC)in their enantiomeric blends or block copolymers,which endows the materials with improved physical properties and specific functions such as enhanced melting temperature,thermal stability,crystallizability,and hydrolytic resistance.