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Initiation of a Greenhouse Gas Monitoring System in New York City
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作者 Dickens St. Hilaire philippe mercier Neal Phillip 《Atmospheric and Climate Sciences》 2019年第1期26-34,共9页
Highly urbanized and industrialized cities across the globe have been known for a long time to be major anthropogenic sources of greenhouse gases (GHGs), yet there is still no consensus on an adequate methodology to m... Highly urbanized and industrialized cities across the globe have been known for a long time to be major anthropogenic sources of greenhouse gases (GHGs), yet there is still no consensus on an adequate methodology to monitor their ambient concentration. This work describes the initiation of a GHG monitoring program at Bronx Community College (BCC) of the City University of New York (CUNY) in Bronx, New York using a Picarro GHG monitor (Model g2301). Results show average atmospheric levels of carbon dioxide (CO2) and methane (CH4) that are above 400 and 2.0 ppmv, respectively. Similar daily fluctuations, with peaks levels resulting from emissions likely occurring during morning rush hour, indicate that there are common sources for both gases. This monitoring system is replicable, sustainable and scalable and will make it possible to more quantifiably link emissions produced in New York City to their material sources. As more data is collected, reduction projections for GHG-producing materials will more accurately be associated to reduction projections for atmospheric CO2 and CH4 levels originating in New York City. In the process, empirical models on air exchange rates and convective boundary layer homogenization through turbulence could also be improved. 展开更多
关键词 GREENHOUSE Gases Methane Carbon Dioxide ANTHROPOGENIC Sources New YORK CITY NYC
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微过氧化物酶-11在碳纳米管/壳聚糖修饰电极上的直接电化学及电催化(英文) 被引量:3
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作者 姜慧君 philippe mercier +4 位作者 Shiunchin C. Wang 杜翀 李晓伟 杨辉 Daniel L.Akins 《功能材料与器件学报》 CAS CSCD 北大核心 2009年第2期132-142,共11页
采用一步法于室温下有选择性地将小管径的单壁碳纳米管(SWCNTs)分散于生物相容性的聚合物——壳聚糖的水溶液中,并将其滴涂于玻碳电极表面,制备出微过氧化物酶-11(MP-11)修饰电极。循环伏安结果表明SWCNT促进了MP-11在电极表面的直接电... 采用一步法于室温下有选择性地将小管径的单壁碳纳米管(SWCNTs)分散于生物相容性的聚合物——壳聚糖的水溶液中,并将其滴涂于玻碳电极表面,制备出微过氧化物酶-11(MP-11)修饰电极。循环伏安结果表明SWCNT促进了MP-11在电极表面的直接电子传递,在pH=7.2的磷酸缓冲溶液中,MP-11的式电位为-0.36V(vs.SCE),MP-11在电极表面的直接电子转移表观速率常数和覆盖度分别为78s-1和8.76×10-10mol.cm-2。进一步的研究结果显示,固定在SWCNT表面的MP-11能保持其对氧气和过氧化氢还原的生物电催化活性,适合用作生物燃料电池的阴极和过氧化氢传感器。氧气在该修饰电极上的还原经历一个四电子过程;该过氧化氢生物传感器对过氧化氢还原的检测具有响应灵敏度高(响应时间小于4s),检测线性范围为2.5×10-6~7.0×10-5μM,检测限为0.8μM,相应的米氏常数和检测灵敏度分别为1.0mMand22.4μA/mM。 展开更多
关键词 微过氧化物酶-11 单壁碳纳米管 壳聚糖 直接电化学 电催化
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