Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene)P(VDF-TrFE-CFE)is a relaxor ferroelectric polymer,which exhibits a temperature-independent electrocaloric effect at room temperature.In this work,the ele...Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene)P(VDF-TrFE-CFE)is a relaxor ferroelectric polymer,which exhibits a temperature-independent electrocaloric effect at room temperature.In this work,the electrocaloric effect in P(VDF-TrFE-CFE)film was directly analysed using infrared imaging.P(VDF-TrFE-CFE)64.8%/27.4%/7.8%(in mole)film of(15±1)mm thickness was deposited on polyethylene naphthalate substrate.Direct ECE of P(VDF-TrFE-CFE)film was measured from 15 to 35C at different electric fields.A maximum adiabatic temperature change(DTad)of 3.58 K was measured during the cooling cycle at a field of 100 V/mm at 30C.Finite element analysis of temperature dissipation through the sample estimated that the actual temperature change within P(VDF-TrFE-CFE)film was 4.3 K.Despite the thermal mass of the substrate,a substantial ECE was observed in P(VDF-TrFE-CFE)films.This electrocaloric terpolymer composition could be of interest for electrocaloric cooling applications.展开更多
基金Fonds National de la Recherche(FNR)of Luxembourg under the grant THERMODIMAT/C20/MS/14718071//Defay,CAMELHEAT/C17/MS/11703691/Defay,MASSENA PRIDE/MASSENA/15/10935404/Defay Siebentritt and CALPOL BRIDGES 2O2O/MS/15410586/Defay.
文摘Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene)P(VDF-TrFE-CFE)is a relaxor ferroelectric polymer,which exhibits a temperature-independent electrocaloric effect at room temperature.In this work,the electrocaloric effect in P(VDF-TrFE-CFE)film was directly analysed using infrared imaging.P(VDF-TrFE-CFE)64.8%/27.4%/7.8%(in mole)film of(15±1)mm thickness was deposited on polyethylene naphthalate substrate.Direct ECE of P(VDF-TrFE-CFE)film was measured from 15 to 35C at different electric fields.A maximum adiabatic temperature change(DTad)of 3.58 K was measured during the cooling cycle at a field of 100 V/mm at 30C.Finite element analysis of temperature dissipation through the sample estimated that the actual temperature change within P(VDF-TrFE-CFE)film was 4.3 K.Despite the thermal mass of the substrate,a substantial ECE was observed in P(VDF-TrFE-CFE)films.This electrocaloric terpolymer composition could be of interest for electrocaloric cooling applications.
