The first total synthesis of (?-abieta-8, 11, 13-trien-7?ol (7) was accomplished via a strategy of ACABC, in which the reduction of the ketone 6 with LiAlH4 gave exclusively the title compound.
The first total synthesis of (?-Celaphanol A was accomplished starting from cyclocitral and 3,4-dimethoxy benzyl chloride via a six-step process, in which the intramolecular cyclization of ketone 4 with BF3稥t2O affor...The first total synthesis of (?-Celaphanol A was accomplished starting from cyclocitral and 3,4-dimethoxy benzyl chloride via a six-step process, in which the intramolecular cyclization of ketone 4 with BF3稥t2O afforded an all-cis isomer intermediate for synthesis of aromatic tricyclic diterpenes.展开更多
基金the National Natural Science Foundation of China(No.29372050)for financial support.
文摘The first total synthesis of (?-abieta-8, 11, 13-trien-7?ol (7) was accomplished via a strategy of ACABC, in which the reduction of the ketone 6 with LiAlH4 gave exclusively the title compound.
基金We are grateful to the National Natural Science Foundation of China(No.20172023)for financial support
文摘The first total synthesis of (?-Celaphanol A was accomplished starting from cyclocitral and 3,4-dimethoxy benzyl chloride via a six-step process, in which the intramolecular cyclization of ketone 4 with BF3稥t2O afforded an all-cis isomer intermediate for synthesis of aromatic tricyclic diterpenes.
