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Synthesis and Magnetic Properties of Fe(Ⅱ) and Nd(Ⅲ) Complexes of Poly(N-2-thiazolylacrylamide)
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作者 ping zheng wei lin sun zhi quan shen 《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第10期1413-1416,共4页
N-2-Thiazolylacrylamide (NTA) was polymerized by a radical route to obtain the polymer in good yield. The polymer with a pendent heterocyclic group is soluble in common organic solvents, which allow to prepare the c... N-2-Thiazolylacrylamide (NTA) was polymerized by a radical route to obtain the polymer in good yield. The polymer with a pendent heterocyclic group is soluble in common organic solvents, which allow to prepare the corresponding metal complexes with higher loads easily. FTIR, ^1H NMR, elemental analysis, and energy-dispersive X-Ray spectroscopy (EDX) were applied to characterize these materials. The magnetic behavior of Fe(Ⅱ) and Nd(Ⅲ) complexes of poly(N-2-thiazolylacrylamide) was examined by a PPMS-9T magnetometer, exhibiting the characteristics of a soft ferromagnet. It is found that the Nd(Ⅲ) complex has an extremely high relative saturation magnetization of 35 emu/g. 展开更多
关键词 N-2-Thiazolylacrylamide POLYMER polymeric complex magnetic property synthesis.
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