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碳支链分布对乳酸基环保增塑剂性能的影响 被引量:3
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作者 高巍 蒋平平 +4 位作者 张鸿 张琪芳 张萍波 董玉明 冷炎 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第11期41-47,共7页
以生物基L-乳酸为酸源,以含有不同结构1-壬醇、7-甲基-1-辛醇、3,5,5-三甲基-1-己醇为醇源,合成了乙酰化(寡聚)乳酸1-壬酯(ALSH)、乙酰化(寡聚)乳酸7-甲基-1-辛酯(ALMH)、乙酰化(寡聚)乳酸3,5,5-三甲基-1-己酯(ALTH)3种不同链的乳酸基... 以生物基L-乳酸为酸源,以含有不同结构1-壬醇、7-甲基-1-辛醇、3,5,5-三甲基-1-己醇为醇源,合成了乙酰化(寡聚)乳酸1-壬酯(ALSH)、乙酰化(寡聚)乳酸7-甲基-1-辛酯(ALMH)、乙酰化(寡聚)乳酸3,5,5-三甲基-1-己酯(ALTH)3种不同链的乳酸基酯增塑剂。采取傅里叶变换红外光谱、氢核磁共振波谱针对制备的产品进行结构表征;利用溶剂浸泡法、万能试验机、热重分析仪对3种乳酸酯增塑剂增塑的聚氯乙烯(PVC)试片实施应用效果解析。结果表明,不同支链对PVC成品有较大的影响,寻找合适的支链结构有利于提高PVC试片的热稳定性、耐抽出性和耐迁移性,伴随着支链的增多,PVC试片的T_g升高,增塑效率下降;直烷基链的结构具备更优异的延展性。 展开更多
关键词 L-乳酸 支链分布 增塑剂 聚氯乙烯 聚氯乙烯添加剂
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Well-dispersive K2O-KCl alkaline catalyst derived from waste banana peel for biodiesel synthesis
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作者 Mingming Fan Hao Wu +2 位作者 Min Shi pingbo zhang Pingping Jiang 《Green Energy & Environment》 SCIE CSCD 2019年第3期322-327,共6页
In this work, a novel alkaline catalyst was synthesized by an economical and effective method of roasting waste banana peel. From XRD, FTIR, SEM, EDS, TGA and CO2-TPD characterization, it was proved that the calcined ... In this work, a novel alkaline catalyst was synthesized by an economical and effective method of roasting waste banana peel. From XRD, FTIR, SEM, EDS, TGA and CO2-TPD characterization, it was proved that the calcined banana peel catalyst showed the strong alkalinity and well dispersity in microstructure, and K2O-KCl as the main active contents. The calcined banana peel catalyst showed better catalytic performance than the catalysts by physical mixing of K2O and KCl, which was due to good dispersibility of K2O-KCl formed during decomposing of carbon fiber by calcination of banana peel. Furthermore, the calcined banana peel catalyst also performed well in both water-resistant ability and recyclability, indicating their potential for biodiesel production from an efficient, robust, and low-cost catalyst. 展开更多
关键词 BIODIESEL BANANA PEEL Basic CATALYST TRANSESTERIFICATION
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