Risk Factor Assessment of Coal Mine Drainage Water on Surrounding Agricultural Soil: A Case Study at Barapukuria in Bangladesh

This study is performed to know the contamination level of heavy metals on the surrounding agricultural soils at the site of Barapukuria Coal Mine Company Limited (BCMCL). Total concentrations of eight heavy metals (Cu, As, Cd, Zn, Pb, Cr, Ni and Mn) were measured in that soil. To calculate the contamination level, the enrichment factor (EF), geoaccumulation index (Igeo) and Hakanson potential ecological risk index were done. Igeo values indicated that the study areas at all stations were suffering from moderate contamination with As. The results of enrichment factor revealed that soils in all stations were in extremely high enrichment condition by As metal. Under Hakanson potential ecological risk index, the contamination coefficient () and potential ecological risk index () were calculated. The degree of contamination at BCMCL area reflects moderate contamination. By considering the ecological risk index of a particular heavy metal, the order is as follows: Cd > As > Cu > Pb > Ni > Cr > Zn and Cd has the highest risk index and poses the greatest damage to the BCMCL area’s soil. EF, Igeo values and potential ecological risk index indicate that there is considerable As and Cd pollution, mainly caused by coal mine drainage water.

Investigation the Risk of Spontaneous Combustion in Barapukuria Coal Mine, Dinajpur, Bangladesh

Spontaneous combustion of coal is one of the major problems in the coal mine. The fire may occur due to exogenous and endogenous causes, by which coal liberated heat to the air or heat absorbed into it. It causes loss of production, as well as economical or financial losses and polluted the environment. If, the heat liberated during this process is allowed to accumulate, the rate of reaction increases exponentially and there is a further rise in temperature that generates the flame and produce CO, CO2, CH4, N2, O2 etc. In addition, the heat generated within coal affected by different factors such moisture, ash, volatile matter etc. of coal. This paper deals with the oxidation and spontaneous combustion risk in Barapukuria underground longwall coal mine, Dinajpur, Bangladesh. In this study, the laboratory analyses (proximate analyses) shows the inherent and the total moisture content value is average 2.73% and 5.82% to 12.75%, respectively. It indicates that these moisture contents are moderately liable to self heating. The less ash content value (av.13.2%) shows, it is less liable to spontaneous combustion. In addition to this, the temperature and concentration of some mine gases (CO, N2, O2) were monitored to calculate the Graham’s ratio. According to Graham’s ratio, the longwall faces have high oxidation risk and medium combustion risk. Therefore, the actual control of spontaneous combustion of coal is important to save coal mine from mine fires and also provides a real opportunity to improve the financial performance of the overall organization.

Geochemical characteristics of Holocene sediments from Chuadanga district, Bangladesh: Implications for weathering, climate, redox conditions, provenance and tectonic setting

The present research deals with the geochemical characteristics of the Holocene sediments from Alamdanga area, Chuadanga district, Bangladesh. Main goals of the study are to delineate source rock characteristics, degree of chemical weathering and sorting processes and behavior of redox conditions during deposition of the sediments. Geochemical characteristics of the sediments show comparatively a wide variation in accordance with stratigraphy in their major element contents(e.g. Si O2 69.46–82.13, Al2O3 2.28–8.88 in wt%), reflecting the distinctive provenance and in part an unstable period in terms of tectonic activity. Geochemical classification of the sediments shows mostly sub-arkose with few sub-litharenites. Some major and trace elements display comprehensible correlation with Al2O3 confirming their possible hydraulic fractionation. The chemical index of alteration(CIA*), W* index, index of compositional variability(ICV), plagioclase index of alteration(PIA*) values and the ratio of Si O2/Al2O3, suggest low degrees of chemical weathering in the source areas as well as immature to moderately mature the sediments. The sediments suggest semi-arid climatic trends within oxic deltaic depositional conditions during the Holocene, at 3–12 ka. Whole rock geochemistry and discrimination diagrams demonstrate the continental signature derivatives, which might have been derived from the felsic to intermediate igneous rocks(granitic plutonic rocks) as well as from quartzose sedimentary/metamorphic provenance. These typical sources are present in a vast region of the Himalayan belt and catchment areas of Ganges. The tectonic setting of the sediments demarcates typically passive margin with slightly continental arc system.

Geochemistry of subsurface Late Quaternary ironstones in Rajshahi and Bogra Districts, Bangladesh: implications for genetic and depositional conditions

The present study deals with the geochemistry of Late Quaternary ironstones in the subsurface in Rajshahi and Bogra districts, Bangladesh with the lithological study of the boreholes sediments. Major lithofacies of the studied boreholes are clay, silty clay, sandy clay, fine to coarse grained sand, gravels and sands with(fragmentary) ironstones. The ironstones contain major oxides, Fe_2 O_3*(*total Fe)(avg. 66.6 wt%), SiO_2(avg. 15.3 wt%), Al_2 O_3(avg. 4.0 wt%), MnO(avg. 7.7 wt%), and CaO(avg. 3.4 wt%). These geochemical data imply that the higher percentage of Fe_2 O_3* along with Al_2 O_3 and MnO indicate the ironstone as goethite and siderite, which is also validated by XRD data. A comparatively higher percentage of SiO_2 indicates the presence of relative amounts of clastic quartz and manganese-rich silicate or clay in these rocks. These ironstones also have significant amounts of MnO(avg. 7.7 wt%) suggesting their depositional environments under oxygenated condition. Chemical data of these ironstones suggest that the source rock suffered deep chemical weathering and iron was mostly carried in association with the clay fraction and organic matter. Iron concretion was mostly formed by bacterial build up in swamps and marshes, and was subsequently embedded in clayey mud.Within the coastal environments, the water table fluctuates and goethite and siderite with mud and quartz became dry and compacted to form ironstone.

Mineralogical and Physical Characterization of Clay of Sitakunda Anticline: Used for Ceramic Industries

This study focuses on mineralogical and chemical characterization of clay of Sitakunda anticline, Bangladesh and potential suitability of this shale as raw materials in ceramic industries. The shale which is clay in texture is composed of chlorite and kaolinite with common illite, smectite, quartz, mica and feldspar. There are two types of samples in color, grey and red. Chemical compositions of clay samples are analyzed by XRF and mineralogical composition of sample analyzed by XRD. Clay samples contain significant amount SiO2, Al2O3 and Fe2O3 with other minor compounds. The plasticity index (12.08 and 16.37) indicates medium ranges of the plasticity of clay. To determine the suitability of ceramic materials, samples were made in a rectangular shape for firing 850°C to 1100°C temperature. The samples were tested for different physical properties such as compressive strength, linear shrinkage, water absorption, porosity and bulk density. Low linear firing shrinkage (0.7% to 2.69%) and water absorption (1.5% to 11%) of the developed ceramic bodies were observed. Scanning Electron Microscope photographs confirm the vitrification of the ceramic bodies. The chemical, physical and ceramic properties of these clays indicate their suitability as raw materials for the production of a wide range of ceramic materials.