Low temperature pyrolysis behavior of four low-rank coals from the biggest deposits of Mongolia were studied using a fixed-bed reactor and Gray-King retort.The coal samples and resultant chars were analyzed using Four...Low temperature pyrolysis behavior of four low-rank coals from the biggest deposits of Mongolia were studied using a fixed-bed reactor and Gray-King retort.The coal samples and resultant chars were analyzed using Fourier transform infrared spectroscopy(FTIR),^(13)C nuclear magnetic resonance(^(13)C NMR)to explore the structure changes and thermogravimetric analyzer coupled with mass spectrometry(TG-MS)was used to investigate the pyrolysis reactivity of coal during thermal decomposition process.The results showed that the aliphatic structure in coal was significantly reduced and the carboxyl groups almost completely decomposed during pyrolysis process at 600℃.The tar yield of Gray-king test is higher than that obtained from the fixed-bed reactor.The gaseous evolution measured by TG-MS during pyrolysis showed that the maximum peaks of evolution of CH_(4),H_(2),C_(2)H_(2),C_(2)H_(5),CO,and CO_(2) gases were well corresponded to the maximum rate of weight loss in the range 428-445℃.展开更多
基金financially supported by Bureau of International Cooperation,Chinese Academy of Sciences(Grant No.122214KYSB20170020)the President’s International Fellowship Initiative of Chinese Academy of Sciences(Grant No.2018VSB0003)for financial support of her research stay at State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan PR China.
文摘Low temperature pyrolysis behavior of four low-rank coals from the biggest deposits of Mongolia were studied using a fixed-bed reactor and Gray-King retort.The coal samples and resultant chars were analyzed using Fourier transform infrared spectroscopy(FTIR),^(13)C nuclear magnetic resonance(^(13)C NMR)to explore the structure changes and thermogravimetric analyzer coupled with mass spectrometry(TG-MS)was used to investigate the pyrolysis reactivity of coal during thermal decomposition process.The results showed that the aliphatic structure in coal was significantly reduced and the carboxyl groups almost completely decomposed during pyrolysis process at 600℃.The tar yield of Gray-king test is higher than that obtained from the fixed-bed reactor.The gaseous evolution measured by TG-MS during pyrolysis showed that the maximum peaks of evolution of CH_(4),H_(2),C_(2)H_(2),C_(2)H_(5),CO,and CO_(2) gases were well corresponded to the maximum rate of weight loss in the range 428-445℃.
