Cure and decomposition reaction kinetics of typical organic materials in aerospace applications are introduced.From the data of dynamic differential scanning calorimetry(DSC)experiments,and based on changes of the pea...Cure and decomposition reaction kinetics of typical organic materials in aerospace applications are introduced.From the data of dynamic differential scanning calorimetry(DSC)experiments,and based on changes of the peak temperatures(T_(p))with different heating rates(β),a linear equation,T_(p)=T_(1)+△Tlnβ,has been obtained more reasonably.The above equation can be used to explain some laws of higher or lower of apparent activation energies(E_(a)),by which the apparent activation energy(E_(a))is nearly equal to RT^(2)_(1)/△T.A number of kinetic investigations of typical thermosetting resins and energetic materials in aerospace applications were chosen to validate the above equations.展开更多
文摘Cure and decomposition reaction kinetics of typical organic materials in aerospace applications are introduced.From the data of dynamic differential scanning calorimetry(DSC)experiments,and based on changes of the peak temperatures(T_(p))with different heating rates(β),a linear equation,T_(p)=T_(1)+△Tlnβ,has been obtained more reasonably.The above equation can be used to explain some laws of higher or lower of apparent activation energies(E_(a)),by which the apparent activation energy(E_(a))is nearly equal to RT^(2)_(1)/△T.A number of kinetic investigations of typical thermosetting resins and energetic materials in aerospace applications were chosen to validate the above equations.
