The Huangsha-Tieshanlong quartz-vein tungsten polymetallic ore deposit, located in the northern Pangushan-Tieshanlong tungsten ore field in eastern Ganxian-Yudu prospecting areas of the Yushan metallogenic belt, is a ...The Huangsha-Tieshanlong quartz-vein tungsten polymetallic ore deposit, located in the northern Pangushan-Tieshanlong tungsten ore field in eastern Ganxian-Yudu prospecting areas of the Yushan metallogenic belt, is a well-known tungsten deposit in southern Jiangxi province, China. SHRIMP-determined dating of zircons from the Tieshanlong granite yields ages of 168.1±2.1 Ma （n=11, MSWD-1.3）. Rhenium and osmium isotopic dating of molybdenite from the Huangsha quartz-vein tungsten deposit determined by ICP-MS yields a weighted average ages of 153-3 Ma and model ages of 150.22.1 Ma - 155.4-2.3 Ma. The age of the Huangsha tungsten deposit is 10 to 15 Ma later than the Tieshanlong granite, which shows that there might have been another early Late Jurassic magmatic activity between 150 and 160 Ma, a process which is closely related with tungsten mineralization in this area. The Tieshanlong granite, the Hnangsha tungsten deposit and the Pangushan-Tieshanlong ore field were all formed around 150-170 Ma, belonging to products of a Mesozoic second large-scale mineralization. According to the collected molybdenite Re-Os dating results in southern Jiangxi province, the timescale of the associated molybdenum mineralization is 2-6 Ma in the tungsten deposit and the timescale of independent molybdenum mineralization is 1-4 Ma, implying the complexity of tungsten mineralization. Times of molybdenum mineralization are mainly concentrated in the Yanshanian, which includes three stages of 133-135 Ma, 150-162 Ma, and 166-170 Ma, respectively. The 150-162 Ma-stage is in accordance with ages of large-scale WoSn mineralization, which is mainly molybdenum mineralization characterized by associated molybdenum mineralization with development of an even greater-intensity independent molybdenum mineralization. Independent molybdenum mineralization occurred before and after large-scale W-Sn mineralization, which indicates that favorable prospecting period for molybdenum may be in Cretaceous and early late Jurassic.展开更多
The Laojiezi alkaline volcanic rocks, which are located in the intraplate region of the Yangtze craton, coincide with the formation of the Jinshajiang-Ailaoshan-Red River alkaline rock belt. Although this belt has bee...The Laojiezi alkaline volcanic rocks, which are located in the intraplate region of the Yangtze craton, coincide with the formation of the Jinshajiang-Ailaoshan-Red River alkaline rock belt. Although this belt has been widely studied by geologists because of its porphyry-related Pb-Ag-Au polymetallic deposit and geotectonic location, the material sources of this belt are still debate. Whole-rock analyses show that these rocks have high total alkali contents(3.73–11.08 wt%), and their aluminum saturation index(ASI) values widely vary from 0.82 to 3.07, which comprise a metaluminous-peraluminous magma series. These rocks are characterized by high K(K2 O/Na2 O>1) and low Ti and Mg contents; enrichment in large-ion lithophile elements, such as Rb, Ba, K and light rare earth elements; and depletion in high field strength elements, such as Ta, Nb, P, and Ti. These rocks exhibit moderate Eu(Eu/Eu*=0.86–1.04) and Ce(Ce/Ce*=0.63–0.96) anomalies. Their(87 Sr/86 Sr)i, εNd(t), zircon εHf(t) and δ18 O values range from 0.70839 to 0.71013, from-10.16 to-12.45, from-19.6 to-5.8, and from 5.69‰ to 8.54‰, respectively, and their Nd and Hf two-stage model ages(TDM2) are 1.67–1.86 Ga and 1.27–2.02 Ga, respectively. These data reflect the primary partial melting of Paleoproterozoic to Mesoproterozoic lower crust with minor residual continental lithospheric mantle and supracrustal metasediments. The lithosphere was likely thickened along the southeastern margin of the Tibetan Plateau following the Indian-Asian continentcontinent collision(65–41 Ma). During the post-collision phase(36–16 Ma), the transition from a compressional to extensional setting triggered the convective removal of the over-thickened CLM beneath the Yangtze craton, which led to the upwelling of asthenospheric materials. This process created alkali-rich and high-K magma through the partial melting of the thickened lower crust. Magma that carried Cu-Au-Pb-Ag minerals was emplaced by strike-slip motion along the E-to W-or ENE-to WSWtrending tectonically weak zone, finally forming an alkaline porphyry Cu-Au-Pb-Ag polymetallic deposit.展开更多
The black shales of the Lower Cambrian Niutitang Formation in Weng＇an, on the Yangtze platform of south China, contain voluminous polymetallic sulfide deposits. A comprehensive geochemical investigation of trace, rar...The black shales of the Lower Cambrian Niutitang Formation in Weng＇an, on the Yangtze platform of south China, contain voluminous polymetallic sulfide deposits. A comprehensive geochemical investigation of trace, rare earth, and platinum group elements （PGE） has been undertaken in order to discuss its ore genesis and correlation with the tectono-depositional setting. The ore-bearing layers enrich molybdenum （Mo）, nickel （Ni）, vanadium （V）, lead （Pb）, strontium （Sr）, barium （Ba）, uranium （U）, arsenic （As）, and rare earth elements （REE） in abundance. High uranium/ thorium （U/Th） ratios （U/Th〉I） indicated that mineralization was mainly influenced by the hydrothermal process. The 8U value was above 1.9, showing a reducing sedimentary condition. The REE patterns showed high enrichment in light rare earth elements （LREE） （heavy rare earth elements （HREE） （LREE/HREE=5-17）, slightly negative europium （Eu） and cerium （Ce） anomalies （δEu=0.81- 0.93）, and positive Ce anomalies （δCe=0.76-1.12）. PGE abundance was characterized by the PGE-type distribution patterns, enriching platinum （Pt）, palladium （Pd）, ruthenium （Ru） and osmium （Os）. The Pt/Pd ratio was 0.8, which is close to the ratios of seawater and ultramafic rocks. All of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensional setting in the context of break-up of the Rodinian supercontinent.展开更多
The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetailic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples we...The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetailic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples were selected for molybdenite Re-Os dating in order to elucidate the timing of mineralization. Re-Os datings of molybdenite from quartz-woiframite veins and disseminated in granite yield ages of 153±7 Ma and 163.2±4.2 Ma respectively. The results indicate that the Yaogangxian tungsten deposit is the product of large-scale metallogenesis in the middle Yanshanian period in South China, and that the evolution from late magmatic to postmagmatic hypothermal mineralization occurred at about 10 Ma. The rhenium content of molybdenite in the Yaogangxian tungsten deposit suggests that the ore materials originated from the crust.展开更多
The Wenquan molybdenum deposit is associated with a Triassic granite in this area.The Wenquan granite is enriched in LILE and LREE,poor in HFSE,and has significantly higher contents of alkali(K2O+Na2O) and Sr,Ba than ...The Wenquan molybdenum deposit is associated with a Triassic granite in this area.The Wenquan granite is enriched in LILE and LREE,poor in HFSE,and has significantly higher contents of alkali(K2O+Na2O) and Sr,Ba than those of the island arc volcanic rocks.These geochemical characteristics are similar to post-collisional granites in high K calc-alkaline series.Studies of major elements,trace elements,REEs and chronology of the Wenquan pluton show that,in the geodynamic transition stage of continent-continent convergence to extension,the partial melting of the enriched lithospheric mantle generated the basaltic magma and triggered the partial melting of the thickened lower crust which produceded the acidic magma,and the Wenquan pluton was formed by mixing of the two magmas.Molybdenite Re-Os isotopic dating gave Os model ages of 212.7±2.6 Ma to 215.1±2.6 Ma with a weighted mean of 214.1±1.1 Ma,and an Re-Os isochron age of 214.4±7.1 Ma.These ages are close to K-Ar ages(223 to 226 Ma) and a SHRIMP zircon U-Pb age(223±7 Ma) for the Wenquan granite within the error range,but relatively younger.This implies that the Mo mineralization occurred in a late stage of the magmatic intrusion,and the metallogenesis took place in the transition stage from syn-collision to post-collision in the tectonic setting of the Qinling Orogenic Belt(QOB) after continental collision be-tween the North China Block(NCB) and the South China Block(SCB).This process is also corre-sponding to the geological events of metamorphism and deformation in South Qinling,closure of the Mian-Lue oceanic basin,and exhumation of the Dabie-Sulu ultrahigh-pressure metamorphic rocks.The large-scale continent-continent collision between NCB and SCB in the middle Triassic triggered sig-nificant crustal thickening and exhumation of subducted slab.In the late Triassic,the tectonic setting was transformed to the transition stage from collision to extension.Materials from the asthenospheric mantle would ascend into the root of the lower crust,which could induce partial melting of the lower crust and generate Mo-enriched granitic magma.The ore-forming elements enriched in the fluid derived from the condensation and fraction of the magma resulted in the Mo mineralization.The Mo deposits in the QOB are mainly formed in two episodes,namely 220± Ma and 140± Ma.The two episodes of metal-logenesis were developed in the tectonic transition settings from compression to extension,but they were in the different stages of the tectonic evolution.The occurrence of the Wenquan Mo-bearing plu-ton indicates that the Triassic tectonic-magmatic belt of Western Qinling is another favorable region for Mo mineralization in the QOB.Therefore,it is significant to pay more attention to evaluation of the ore-forming potentiality in the Triassic granites in Western Qinling.展开更多
基金supported jointly by grants No K1 022K0901 from the Scientific Research Fund of the China Central Non-Commercial Institutegrant No 40772063 from the National Natural Science Foundation of Chinathe Programme of Excellent Young Scientists of the Ministry of Land and Resources and Geological Survey Program Grant 1212010561603-2 from the China Geological Survey
文摘The Huangsha-Tieshanlong quartz-vein tungsten polymetallic ore deposit, located in the northern Pangushan-Tieshanlong tungsten ore field in eastern Ganxian-Yudu prospecting areas of the Yushan metallogenic belt, is a well-known tungsten deposit in southern Jiangxi province, China. SHRIMP-determined dating of zircons from the Tieshanlong granite yields ages of 168.1±2.1 Ma （n=11, MSWD-1.3）. Rhenium and osmium isotopic dating of molybdenite from the Huangsha quartz-vein tungsten deposit determined by ICP-MS yields a weighted average ages of 153-3 Ma and model ages of 150.22.1 Ma - 155.4-2.3 Ma. The age of the Huangsha tungsten deposit is 10 to 15 Ma later than the Tieshanlong granite, which shows that there might have been another early Late Jurassic magmatic activity between 150 and 160 Ma, a process which is closely related with tungsten mineralization in this area. The Tieshanlong granite, the Hnangsha tungsten deposit and the Pangushan-Tieshanlong ore field were all formed around 150-170 Ma, belonging to products of a Mesozoic second large-scale mineralization. According to the collected molybdenite Re-Os dating results in southern Jiangxi province, the timescale of the associated molybdenum mineralization is 2-6 Ma in the tungsten deposit and the timescale of independent molybdenum mineralization is 1-4 Ma, implying the complexity of tungsten mineralization. Times of molybdenum mineralization are mainly concentrated in the Yanshanian, which includes three stages of 133-135 Ma, 150-162 Ma, and 166-170 Ma, respectively. The 150-162 Ma-stage is in accordance with ages of large-scale WoSn mineralization, which is mainly molybdenum mineralization characterized by associated molybdenum mineralization with development of an even greater-intensity independent molybdenum mineralization. Independent molybdenum mineralization occurred before and after large-scale W-Sn mineralization, which indicates that favorable prospecting period for molybdenum may be in Cretaceous and early late Jurassic.
基金funded by the Open Foundation of the Beijing SHRIMP Center (DDC15-016)the Applied Basic Research Program Youth Project of Yunnan Province (2016DF031)the National Basic Research Program of China (2015CB452605)
文摘The Laojiezi alkaline volcanic rocks, which are located in the intraplate region of the Yangtze craton, coincide with the formation of the Jinshajiang-Ailaoshan-Red River alkaline rock belt. Although this belt has been widely studied by geologists because of its porphyry-related Pb-Ag-Au polymetallic deposit and geotectonic location, the material sources of this belt are still debate. Whole-rock analyses show that these rocks have high total alkali contents(3.73–11.08 wt%), and their aluminum saturation index(ASI) values widely vary from 0.82 to 3.07, which comprise a metaluminous-peraluminous magma series. These rocks are characterized by high K(K2 O/Na2 O>1) and low Ti and Mg contents; enrichment in large-ion lithophile elements, such as Rb, Ba, K and light rare earth elements; and depletion in high field strength elements, such as Ta, Nb, P, and Ti. These rocks exhibit moderate Eu(Eu/Eu*=0.86–1.04) and Ce(Ce/Ce*=0.63–0.96) anomalies. Their(87 Sr/86 Sr)i, εNd(t), zircon εHf(t) and δ18 O values range from 0.70839 to 0.71013, from-10.16 to-12.45, from-19.6 to-5.8, and from 5.69‰ to 8.54‰, respectively, and their Nd and Hf two-stage model ages(TDM2) are 1.67–1.86 Ga and 1.27–2.02 Ga, respectively. These data reflect the primary partial melting of Paleoproterozoic to Mesoproterozoic lower crust with minor residual continental lithospheric mantle and supracrustal metasediments. The lithosphere was likely thickened along the southeastern margin of the Tibetan Plateau following the Indian-Asian continentcontinent collision(65–41 Ma). During the post-collision phase(36–16 Ma), the transition from a compressional to extensional setting triggered the convective removal of the over-thickened CLM beneath the Yangtze craton, which led to the upwelling of asthenospheric materials. This process created alkali-rich and high-K magma through the partial melting of the thickened lower crust. Magma that carried Cu-Au-Pb-Ag minerals was emplaced by strike-slip motion along the E-to W-or ENE-to WSWtrending tectonically weak zone, finally forming an alkaline porphyry Cu-Au-Pb-Ag polymetallic deposit.
基金supported by grants from the Key Projectof Chinese Ministry of Education(no.:104004)the National Natural Science Foundation of China(no.:40839907)
文摘The black shales of the Lower Cambrian Niutitang Formation in Weng＇an, on the Yangtze platform of south China, contain voluminous polymetallic sulfide deposits. A comprehensive geochemical investigation of trace, rare earth, and platinum group elements （PGE） has been undertaken in order to discuss its ore genesis and correlation with the tectono-depositional setting. The ore-bearing layers enrich molybdenum （Mo）, nickel （Ni）, vanadium （V）, lead （Pb）, strontium （Sr）, barium （Ba）, uranium （U）, arsenic （As）, and rare earth elements （REE） in abundance. High uranium/ thorium （U/Th） ratios （U/Th〉I） indicated that mineralization was mainly influenced by the hydrothermal process. The 8U value was above 1.9, showing a reducing sedimentary condition. The REE patterns showed high enrichment in light rare earth elements （LREE） （heavy rare earth elements （HREE） （LREE/HREE=5-17）, slightly negative europium （Eu） and cerium （Ce） anomalies （δEu=0.81- 0.93）, and positive Ce anomalies （δCe=0.76-1.12）. PGE abundance was characterized by the PGE-type distribution patterns, enriching platinum （Pt）, palladium （Pd）, ruthenium （Ru） and osmium （Os）. The Pt/Pd ratio was 0.8, which is close to the ratios of seawater and ultramafic rocks. All of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensional setting in the context of break-up of the Rodinian supercontinent.
基金This work was supported Science Foundation of China by the National Natural （No. 40572061） ； the scientific research funds of state-level scientific research institutes （No. K2007-5-5）.
文摘The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetailic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples were selected for molybdenite Re-Os dating in order to elucidate the timing of mineralization. Re-Os datings of molybdenite from quartz-woiframite veins and disseminated in granite yield ages of 153±7 Ma and 163.2±4.2 Ma respectively. The results indicate that the Yaogangxian tungsten deposit is the product of large-scale metallogenesis in the middle Yanshanian period in South China, and that the evolution from late magmatic to postmagmatic hypothermal mineralization occurred at about 10 Ma. The rhenium content of molybdenite in the Yaogangxian tungsten deposit suggests that the ore materials originated from the crust.
基金Supported by the National Basic Research Program of China(Grant No.2006CB403502)National General Investigation Program of China(Grant No.1212010631007)+3 种基金National Natural Science Foundation of China(Grant No.40872071)Foundation of State Key Laboratory of Ore Deposit Geochemistry,Chinese Academy of Sciences(Grant No.20060)Foundation of Educational Bureau of Shaanxi Province Foundation(Grant No.07JK414)Foundation of State Key Laboratory for Mineral Deposits Research,Nanjing University(Grant No.14-08-1)
文摘The Wenquan molybdenum deposit is associated with a Triassic granite in this area.The Wenquan granite is enriched in LILE and LREE,poor in HFSE,and has significantly higher contents of alkali(K2O+Na2O) and Sr,Ba than those of the island arc volcanic rocks.These geochemical characteristics are similar to post-collisional granites in high K calc-alkaline series.Studies of major elements,trace elements,REEs and chronology of the Wenquan pluton show that,in the geodynamic transition stage of continent-continent convergence to extension,the partial melting of the enriched lithospheric mantle generated the basaltic magma and triggered the partial melting of the thickened lower crust which produceded the acidic magma,and the Wenquan pluton was formed by mixing of the two magmas.Molybdenite Re-Os isotopic dating gave Os model ages of 212.7±2.6 Ma to 215.1±2.6 Ma with a weighted mean of 214.1±1.1 Ma,and an Re-Os isochron age of 214.4±7.1 Ma.These ages are close to K-Ar ages(223 to 226 Ma) and a SHRIMP zircon U-Pb age(223±7 Ma) for the Wenquan granite within the error range,but relatively younger.This implies that the Mo mineralization occurred in a late stage of the magmatic intrusion,and the metallogenesis took place in the transition stage from syn-collision to post-collision in the tectonic setting of the Qinling Orogenic Belt(QOB) after continental collision be-tween the North China Block(NCB) and the South China Block(SCB).This process is also corre-sponding to the geological events of metamorphism and deformation in South Qinling,closure of the Mian-Lue oceanic basin,and exhumation of the Dabie-Sulu ultrahigh-pressure metamorphic rocks.The large-scale continent-continent collision between NCB and SCB in the middle Triassic triggered sig-nificant crustal thickening and exhumation of subducted slab.In the late Triassic,the tectonic setting was transformed to the transition stage from collision to extension.Materials from the asthenospheric mantle would ascend into the root of the lower crust,which could induce partial melting of the lower crust and generate Mo-enriched granitic magma.The ore-forming elements enriched in the fluid derived from the condensation and fraction of the magma resulted in the Mo mineralization.The Mo deposits in the QOB are mainly formed in two episodes,namely 220± Ma and 140± Ma.The two episodes of metal-logenesis were developed in the tectonic transition settings from compression to extension,but they were in the different stages of the tectonic evolution.The occurrence of the Wenquan Mo-bearing plu-ton indicates that the Triassic tectonic-magmatic belt of Western Qinling is another favorable region for Mo mineralization in the QOB.Therefore,it is significant to pay more attention to evaluation of the ore-forming potentiality in the Triassic granites in Western Qinling.
