The binding energy spectrum and electron momentum profiles of the inner orbitals of methyl iodide have been measured using an electron momentum spectrometer at the impact energy of 1200 e V plus binding energy.Two pea...The binding energy spectrum and electron momentum profiles of the inner orbitals of methyl iodide have been measured using an electron momentum spectrometer at the impact energy of 1200 e V plus binding energy.Two peaks in the binding energy spectrum,arising from the spin-orbit splitting,are observed and the corresponding electron momentum profiles are obtained.Relativistic density functional calculations are performed to elucidate the experimental electron momentum profiles of two spin-orbit splitting components,showing agreement with each other except for the intensity in low momentum region.The measured high intensity in the low momentum region can be further explained by the distorted wave calculation.展开更多
基金supported by the National Natural Science Foundation of China (No.11534011 and No.11874339)the Natural Science Research Programme of Education Department of Anhui Province (No.KJ2013A260 and No.KJ2016A749)。
文摘The binding energy spectrum and electron momentum profiles of the inner orbitals of methyl iodide have been measured using an electron momentum spectrometer at the impact energy of 1200 e V plus binding energy.Two peaks in the binding energy spectrum,arising from the spin-orbit splitting,are observed and the corresponding electron momentum profiles are obtained.Relativistic density functional calculations are performed to elucidate the experimental electron momentum profiles of two spin-orbit splitting components,showing agreement with each other except for the intensity in low momentum region.The measured high intensity in the low momentum region can be further explained by the distorted wave calculation.
