Nitrogen-containing carbons were prepared by modification of activated carbons.The modified carbons were used as electrode materials with improved electrochemical performance.Precursor anthracite was activated by KOH(...Nitrogen-containing carbons were prepared by modification of activated carbons.The modified carbons were used as electrode materials with improved electrochemical performance.Precursor anthracite was activated by KOH(KOH:anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons.The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively.Electrochemical experiments were performed in an organic electrolytic solution of 1 M(C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement.The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons:this ensured a sufficient utilization of the exposed surface for charge storage.展开更多
This paper focuses on the problem of linear track keeping for marine surface vessels. The influence exerted by sea currents on the kinematic equation of ships is considered first. The input-to-state stability(ISS) the...This paper focuses on the problem of linear track keeping for marine surface vessels. The influence exerted by sea currents on the kinematic equation of ships is considered first. The input-to-state stability(ISS) theory used to verify the system is input-to-state stable. Combining the Nussbaum gain with backstepping techniques,a robust adaptive fuzzy algorithm is presented by employing fuzzy systems as an approximator for unknown nonlinearities in the system. It is proved that the proposed algorithm that guarantees all signals in the closed-loop system are ultimately bounded. Consequently,a ship's linear track-keeping control can be implemented. Simulation results using Dalian Maritime University's ocean-going training ship 'YULONG' are presented to validate the effectiveness of the proposed algorithm.展开更多
基金supported by the National Natural Science Foundation of China (U21A2060, 22178116, 21978097)Shanghai Pujiang Program (21PJD019)+1 种基金Natural Science Foundation of Shanghai (22ZR1417400)the Fundamental Research Funds for the Central Universities (222201817001, 50321041918013, JKA01221601)
基金Projects 50672025 and 50730003 supported by the National Natural Science Foundation of China
文摘Nitrogen-containing carbons were prepared by modification of activated carbons.The modified carbons were used as electrode materials with improved electrochemical performance.Precursor anthracite was activated by KOH(KOH:anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons.The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively.Electrochemical experiments were performed in an organic electrolytic solution of 1 M(C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement.The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons:this ensured a sufficient utilization of the exposed surface for charge storage.
基金Foundation item: National Natural Science Foundation of China (51002051) Fundamental Research Funds for the Cenlxal Universities (WA1014016) Science and Technology Commission of Shanghai Municipality (09520500900)
基金Supported by the National Natural Science Foundation of China under Grant No. 10572094.
文摘This paper focuses on the problem of linear track keeping for marine surface vessels. The influence exerted by sea currents on the kinematic equation of ships is considered first. The input-to-state stability(ISS) theory used to verify the system is input-to-state stable. Combining the Nussbaum gain with backstepping techniques,a robust adaptive fuzzy algorithm is presented by employing fuzzy systems as an approximator for unknown nonlinearities in the system. It is proved that the proposed algorithm that guarantees all signals in the closed-loop system are ultimately bounded. Consequently,a ship's linear track-keeping control can be implemented. Simulation results using Dalian Maritime University's ocean-going training ship 'YULONG' are presented to validate the effectiveness of the proposed algorithm.