Polycyclic aromatic hydrocarbons(PAHs)are major organic pollutants in soil.It is known that they are released to the atmosphere by wind via dust aerosol generation.However,it remains unclear how these pollutants are t...Polycyclic aromatic hydrocarbons(PAHs)are major organic pollutants in soil.It is known that they are released to the atmosphere by wind via dust aerosol generation.However,it remains unclear how these pollutants are transferred through the air/soil interface.In this study,dust aerosols were generated in the laboratory using soils(sandy loam and loam)with various physicochemical properties.The PAH concentrations of these soils and their generated dust aerosol were measured,showing that the enrichment factors(EFs)of PAHs were affected by soil texture,PAH contamination level,molecular weight of PAH species and aerosol sizes.The PAHs with higher EFs(6.24–123.35 in dust PM_(2.5);7.02–47.65 in dust PM_(10))usually had high molecular weights with more than four aromatic rings.In addition,the positive correlation between EFs of PAHs and the total OCaerosol content of dust aerosol in different particle sizes was also statistically significant(r=0.440,P<0.05).This work provides insights into the relationship between atmospheric PAHs and the contaminated soils and the transfer process of PAHs through the soil-air interface.展开更多
基金supported by the National Natural Science Foundation of China(Nos.42077193,21906024,and 92044301)the Shanghai Natural Science Foundation(China)(No.19ZR1404000)。
文摘Polycyclic aromatic hydrocarbons(PAHs)are major organic pollutants in soil.It is known that they are released to the atmosphere by wind via dust aerosol generation.However,it remains unclear how these pollutants are transferred through the air/soil interface.In this study,dust aerosols were generated in the laboratory using soils(sandy loam and loam)with various physicochemical properties.The PAH concentrations of these soils and their generated dust aerosol were measured,showing that the enrichment factors(EFs)of PAHs were affected by soil texture,PAH contamination level,molecular weight of PAH species and aerosol sizes.The PAHs with higher EFs(6.24–123.35 in dust PM_(2.5);7.02–47.65 in dust PM_(10))usually had high molecular weights with more than four aromatic rings.In addition,the positive correlation between EFs of PAHs and the total OCaerosol content of dust aerosol in different particle sizes was also statistically significant(r=0.440,P<0.05).This work provides insights into the relationship between atmospheric PAHs and the contaminated soils and the transfer process of PAHs through the soil-air interface.
