Incorporation ofγ-aminobutyric acid and cesium cations to formamidinium lead halide perovskites for highly efficient solar cells

The stability issue has become one of the main challenges for the commercialization of perovskite solar cells(PSCs).Formamidinium(FA)-based perovskites have shown great promise owing to their improved thermal and moisture stability.However,these perovskites are suffering from phase transition and separation.Here,a method of incorporating of γ-aminobutyric acid(GABA) and cesium cations into FAPbl_(3) is developed to improve the phase stability.It is demonstrated that the crystallinity of α-FAPbl_(3) phase is greatly improved and the phase transition temperature is significantly dropped.The resultant solar cell therefore obtains a champion power conversion efficiency(PCE) of 23.71%,which is one of the highest efficiencies for methylammonium-free PSCs.Furthermore,it shows an impressively enhanced stability under illumination,exhibiting the great potential of FA-based perovskites for efficient and stable solar cells.

Statistical Inference for Partially Linear Regression Models with Measurement Errors

In this paper,the authors investigate three aspects of statistical inference for the partially linear regression models where some covariates are measured with errors.Firstly, a bandwidth selection procedure is proposed,which is a combination of the differencebased technique and GCV method.Secondly,a goodness-of-fit test procedure is proposed, which is an extension of the generalized likelihood technique.Thirdly,a variable selection procedure for the parametric part is provided based on the nonconcave penalization and corrected profile least squares.Same as＂Variable selection via nonconcave penalized likelihood and its oracle properties＂（J.Amer.Statist.Assoc.,96,2001,1348-1360）,it is shown that the resulting estimator has an oracle property with a proper choice of regularization parameters and penalty function.Simulation studies are conducted to illustrate the finite sample performances of the proposed procedures.

Weighted Profile Least Squares Estimation for a Panel Data Varying-Coefficient Partially Linear Model

This paper is concerned with inference of panel data varying-coefficient partially linear models with a one-way error structure. The model is a natural extension of the well-known panel data linear model （due to Baltagi 1995） to the setting of semiparametric regressions. The authors propose a weighted profile least squares estimator （WPLSE） and a weighted local polynomial estimator （WLPE） for the parametric and nonparametric components, respectively. It is shown that the WPLSE is asymptotically more efficient than the usual profile least squares estimator （PLSE）, and that the WLPE is also asymptotically more efficient than the usual local polynomial estimator （LPE）. The latter is an interesting result. According to Ruckstuhl, Welsh and Carroll （2000） and Lin and Carroll （2000）, ignoring the correlation structure entirely and ＂pretending＂ that the data are really independent will result in more efficient estimators when estimating nonparametric regression with longitudinal or panel data. The result in this paper shows that this is not true when the design points of the nonparametric component have a closeness property within groups. The asymptotic properties of the proposed weighted estimators are derived. In addition, a block bootstrap test is proposed for the goodness of fit of models, which can accommodate the correlations within groups illustrate the finite sample performances of the Some simulation studies are conducted to proposed procedures.

Metalens for coaxial double wavelength focusing

We propose a metalens for coaxial double wavelength focusing.One focusing spot is a circular solid spot,and the other focusing spot is a doughnut-shaped spot that is circling the solid spot.The designed metalens was composed of a met a-molecular nanostructured cell array.Each meta-molecular nanostructured cell was divided into four squares.Two slots with exactly the same shape,but usually with the rotation angle measured clockwise from the positive x axis,are etched into the gold film in two diagonally connected squares.Another two slots with the same shape but with the rotation angle measured counter-clockwise from the positive x axis are etched into another two diagonally connected squares in the same cell.The lasers with two different wavelengths are trans?formed into right-handed and left-handed circularly polarized beams,respectively.The two sets of slots with different azimuthal rotations modulated the phases of incident right-handed and left-handed circularly polarized beams independently.The numerical simulation with finite-difference time-domain(FDTD)software was carried out,and the experimental verification was also implemented.Both the experimental result and the numerical simulation agree well with the theoretical design.