A new material of Zr0.1Al1.9Mo2.9V0.1O12 is synthesized by the traditional solid state synthesis method.The phase transition,coefficient of thermal expansion,and luminescence properties of Zr0.1Al1.9Mo2.9V0.1O12 are e...A new material of Zr0.1Al1.9Mo2.9V0.1O12 is synthesized by the traditional solid state synthesis method.The phase transition,coefficient of thermal expansion,and luminescence properties of Zr0.1Al1.9Mo2.9V0.1O12 are explored with Raman spectrometer,dilatometer,and x-ray diffraction(XRD)diffractometer.The results show that the Zr0.1Al1.9Mo2.9V0.1O12 possesses the strong broad-band luminescence characteristics almost in the whole visible region.The sample is crystallized in a monoclinic structure group of P21/a(No.14)crystallized at room temperature(RT).The crystal is changed from monoclinic to orthorhombic structure when the temperature increases to 463 K.The material has very low thermal expansion performance in a wide temperature range.Its excellent low thermal expansion and strong pale green light properties in a wide temperature range suggest its potential applications in light-emitting diode(LED)and other optoelectronic devices.展开更多
The Zr（0.5）Hf（0.5）VPO7 is successfully synthesized by the solid-state method with near-zero thermal expansion. Powder x-ray diffraction（XRD）, Raman spectroscopy, thermal dilatometry, and scanning electron micros...The Zr（0.5）Hf（0.5）VPO7 is successfully synthesized by the solid-state method with near-zero thermal expansion. Powder x-ray diffraction（XRD）, Raman spectroscopy, thermal dilatometry, and scanning electron microscopy（SEM） are used to investigate the structure, the phase transition, and the coefficient of thermal expansion（CTE） of Zr（0.5）Hf（0.5）VPO7. The investigation results show that the samples are of the single cubic type with a space group of Pa3ˉ at room temperature（RT）.It can be inferred that the superstructure is transformed from the 3 × 3 × 3 superstructure to the 1 × 1 × 1 ideal crystal in a temperature range between 310 K and 323 K. The CTE is measured by a dilatometer to be 0.59 × 10^（-6） K^（-1）（310 K–673 K）. The values of intrinsic（XRD） and extrinsic（dilatometric） thermal expansion are both near zero. The results show that Zr（0.5）Hf（0.5）VPO7 has near-zero thermal expansion behavior over a wide temperature range.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11874328,U1731121,and 41401384)the Shandong Province Higher Educational Science and Technology Program,China(Grant No.J17KB127).
文摘A new material of Zr0.1Al1.9Mo2.9V0.1O12 is synthesized by the traditional solid state synthesis method.The phase transition,coefficient of thermal expansion,and luminescence properties of Zr0.1Al1.9Mo2.9V0.1O12 are explored with Raman spectrometer,dilatometer,and x-ray diffraction(XRD)diffractometer.The results show that the Zr0.1Al1.9Mo2.9V0.1O12 possesses the strong broad-band luminescence characteristics almost in the whole visible region.The sample is crystallized in a monoclinic structure group of P21/a(No.14)crystallized at room temperature(RT).The crystal is changed from monoclinic to orthorhombic structure when the temperature increases to 463 K.The material has very low thermal expansion performance in a wide temperature range.Its excellent low thermal expansion and strong pale green light properties in a wide temperature range suggest its potential applications in light-emitting diode(LED)and other optoelectronic devices.
基金supported by the National Natural Science Foundation of China(Grant Nos.11574276,U173112,and 41401384)the Project of Shandong Provincial Higher Educational Science and Technology Program,China(Grant No.J17KB127)+1 种基金the Science and Technology Development Plans of Binzhou City,China(Grant Nos.2014ZC0307 and 2015ZC0210)Binzhou University Research Fund Project,China(Grant Nos.BZXYG1513 and BZXYG1706)
文摘The Zr（0.5）Hf（0.5）VPO7 is successfully synthesized by the solid-state method with near-zero thermal expansion. Powder x-ray diffraction（XRD）, Raman spectroscopy, thermal dilatometry, and scanning electron microscopy（SEM） are used to investigate the structure, the phase transition, and the coefficient of thermal expansion（CTE） of Zr（0.5）Hf（0.5）VPO7. The investigation results show that the samples are of the single cubic type with a space group of Pa3ˉ at room temperature（RT）.It can be inferred that the superstructure is transformed from the 3 × 3 × 3 superstructure to the 1 × 1 × 1 ideal crystal in a temperature range between 310 K and 323 K. The CTE is measured by a dilatometer to be 0.59 × 10^（-6） K^（-1）（310 K–673 K）. The values of intrinsic（XRD） and extrinsic（dilatometric） thermal expansion are both near zero. The results show that Zr（0.5）Hf（0.5）VPO7 has near-zero thermal expansion behavior over a wide temperature range.
