This study utilizedathermogravimetric analyzer to assess the thermal decomposition behaviors and kinetics properties of vacuum residue(VR)and low-density polyethylene(LDPE)polymers.The kinetic parameters were calculat...This study utilizedathermogravimetric analyzer to assess the thermal decomposition behaviors and kinetics properties of vacuum residue(VR)and low-density polyethylene(LDPE)polymers.The kinetic parameters were calculated using the Friedman technique.To demonstrate the interactive effects between LDPE and VR during the co-pyrolysis process,the disparity in mass loss and mass loss rate between the experimental and calculated values was computed.The co-pyrolysis curves obtained through estimation and experimentation exhibited significantdeviations,whichwerei influencedby temperature and mixing ratio.A negative synergistic interaction was observed between LDPE and VR,although this inhibitory effect could be mitigated or eliminated by reducing the LDPE ratio in the mixture and increasing the co-pyrolysistemperature.Theco-pyrolysisprocess resulted in a reduction in carbon residue,which could be attributed to the interaction between LDPE and the heavy fractions,particularly resin and asphaltene,present in VR.These findings align with the pyrolysis behaviors exhibited by the four VR fractions.Furthermore,it was observed that the co-pyrolysis process exhibited lower activation energy as the VR ratio increased,indicating a continuous enhancement in the reactivity of the mixed samples during co-pyrolysis.展开更多
A coupled numerical method for the direct numerical simulation of particle-fluid systems is formulated and implemented, resolving an order of magnitude smaller than particle size. The particle motion is described by t...A coupled numerical method for the direct numerical simulation of particle-fluid systems is formulated and implemented, resolving an order of magnitude smaller than particle size. The particle motion is described by the time-driven hard-sphere model, while the hydrodynamic equations governing fluid flow are solved by the lattice Boltzmann method (LBM), Particle-fluid coupling is realized by an immersed boundary method (IBM), which considers the effect of boundary on surrounding fluid as a restoring force added to the governing equations of the fluid. The proposed scheme is validated in the classical flow-around-cylinder simulations, and preliminary application of this scheme to fluidization is reported, demonstrating it to be a promising computational strategy for better understanding complex behavior in particle-fluid systems.展开更多
The stress-controlled fatigue tests are carried out at a stress ratio of 0.1 and a frequency of 10 Hz,and span both low-cycle and high-cycle regimes by varying the applied stress amplitudes.The high-cycle fa-tigue reg...The stress-controlled fatigue tests are carried out at a stress ratio of 0.1 and a frequency of 10 Hz,and span both low-cycle and high-cycle regimes by varying the applied stress amplitudes.The high-cycle fa-tigue regime gives a fatigue strength of 497 MPa and a fatigue ratio of 0.44.At equivalent conditions,the alloy’s fatigue strength is greater than all other high-entropy alloys(HEAs)with reported high-cycle fatigue data,dilute body-centered cubic alloys,and many structural alloys such as steels,titanium al-loys,and aluminum alloys.Through in-depth analyses of crack-propagation trajectories,fracture-surface morphologies and deformation plasticity by means of various microstructural analysis techniques and theoretical frameworks,the alloy’s remarkable fatigue resistance is attributed to delayed crack initiation in the high-cycle regime,which is achieved by retarding the formation of localized persistent slip bands,and its good resistance to crack propagation in the low-cycle regime,which is accomplished by intrin-sic toughening backed up by extrinsic toughening.Moreover,the stochastic nature of the fatigue data is neatly captured with a 2-parameter Weibull model.展开更多
The authors regret<to remove Prof.Jien-Wei Yeh from the authorship for some reason.The removal is agreed by Prof.Jien-Wei Yeh>.The authors would like to apologise for any inconvenience caused.
基金The authors acknowledge the support from the National Key Research and Development Program of China(Grant No.2021YFB3801300)the National Natural Science Foundation of China(Grant No.U22B20149,22021004).
文摘This study utilizedathermogravimetric analyzer to assess the thermal decomposition behaviors and kinetics properties of vacuum residue(VR)and low-density polyethylene(LDPE)polymers.The kinetic parameters were calculated using the Friedman technique.To demonstrate the interactive effects between LDPE and VR during the co-pyrolysis process,the disparity in mass loss and mass loss rate between the experimental and calculated values was computed.The co-pyrolysis curves obtained through estimation and experimentation exhibited significantdeviations,whichwerei influencedby temperature and mixing ratio.A negative synergistic interaction was observed between LDPE and VR,although this inhibitory effect could be mitigated or eliminated by reducing the LDPE ratio in the mixture and increasing the co-pyrolysistemperature.Theco-pyrolysisprocess resulted in a reduction in carbon residue,which could be attributed to the interaction between LDPE and the heavy fractions,particularly resin and asphaltene,present in VR.These findings align with the pyrolysis behaviors exhibited by the four VR fractions.Furthermore,it was observed that the co-pyrolysis process exhibited lower activation energy as the VR ratio increased,indicating a continuous enhancement in the reactivity of the mixed samples during co-pyrolysis.
基金sponsored by Ministry of Finance under the grant ZDYZ2008-2National Key Science and Technology Project under the grant 2008ZX05014-003-006HZthe Chinese Academy of Sciences under the grant KGCX2-YW-124
文摘A coupled numerical method for the direct numerical simulation of particle-fluid systems is formulated and implemented, resolving an order of magnitude smaller than particle size. The particle motion is described by the time-driven hard-sphere model, while the hydrodynamic equations governing fluid flow are solved by the lattice Boltzmann method (LBM), Particle-fluid coupling is realized by an immersed boundary method (IBM), which considers the effect of boundary on surrounding fluid as a restoring force added to the governing equations of the fluid. The proposed scheme is validated in the classical flow-around-cylinder simulations, and preliminary application of this scheme to fluidization is reported, demonstrating it to be a promising computational strategy for better understanding complex behavior in particle-fluid systems.
基金the support of the Department of Energy (DOE) Office of Fossil Energy, National Energy Technology Laboratory (NETL) (DE-FE-0011194)the National Science Foundation (DMR1611180 and 1809640)+3 种基金the U.S. Army Office Projects (W911NF-13-1-0438 and W911NF-19-2-0049) with Drs. J. Mullen, V. Cedro, R. Dunst, S. Markovich, J. Yang, G. Shiflet, D. Farkas, M. P. Bakas, D. M. Stepp, and S. Mathaudhu as program managersthe financial support from the National Natural Science Foundation of China (No. 52001271)the Shandong Major Scientific and Technological Innovation Program, China(No. 2019JZZY010325)the financial support of the Center for Materials Processing (CMP), at The University of Tennessee, with the director of Dr. Claudia J. Rawn. J.W.
文摘The stress-controlled fatigue tests are carried out at a stress ratio of 0.1 and a frequency of 10 Hz,and span both low-cycle and high-cycle regimes by varying the applied stress amplitudes.The high-cycle fa-tigue regime gives a fatigue strength of 497 MPa and a fatigue ratio of 0.44.At equivalent conditions,the alloy’s fatigue strength is greater than all other high-entropy alloys(HEAs)with reported high-cycle fatigue data,dilute body-centered cubic alloys,and many structural alloys such as steels,titanium al-loys,and aluminum alloys.Through in-depth analyses of crack-propagation trajectories,fracture-surface morphologies and deformation plasticity by means of various microstructural analysis techniques and theoretical frameworks,the alloy’s remarkable fatigue resistance is attributed to delayed crack initiation in the high-cycle regime,which is achieved by retarding the formation of localized persistent slip bands,and its good resistance to crack propagation in the low-cycle regime,which is accomplished by intrin-sic toughening backed up by extrinsic toughening.Moreover,the stochastic nature of the fatigue data is neatly captured with a 2-parameter Weibull model.
文摘The authors regret<to remove Prof.Jien-Wei Yeh from the authorship for some reason.The removal is agreed by Prof.Jien-Wei Yeh>.The authors would like to apologise for any inconvenience caused.