Dwell time plays a vital role in determining the accuracy and convergence of the computer-controlled optical surfacing process.However,optimizing dwell time presents a challenge due to its ill-posed nature,resulting i...Dwell time plays a vital role in determining the accuracy and convergence of the computer-controlled optical surfacing process.However,optimizing dwell time presents a challenge due to its ill-posed nature,resulting in non-unique solutions.To address this issue,several well-known methods have emerged,including the iterative,Bayesian,Fourier transform,and matrix-form methods.Despite their independent development,these methods share common objectives,such as minimizing residual errors,ensuring dwell time's positivity and smoothness,minimizing total processing time,and enabling flexible dwell positions.This paper aims to comprehensively review the existing dwell time optimization methods,explore their interrelationships,provide insights for their effective implementations,evaluate their performances,and ultimately propose a unified dwell time optimization methodology.展开更多
The ever-growing energy demand and environmental issues have stimulated the development of sustainable energy technologies.Herein,an efficient and environmentally friendly electrochemical transformation technology was...The ever-growing energy demand and environmental issues have stimulated the development of sustainable energy technologies.Herein,an efficient and environmentally friendly electrochemical transformation technology was proposed to prepare highly graphitized carbon materials from an abundant natural resource-lignin (LG).The preparation process mainly includes pyrolytic carbonization of raw LG material and electrochemical conversion of amorphous carbon precursor.Interestingly,with the assistance of Co catalyst,the graphitization degree of the products was significantly improved,in which the mechanism was the removal of heteroatoms in LG and the rearrangement of carbon atoms into graphite lattice.Furthermore,tunable microstructures (nanoflakes) under catalytic effects could also be observed by controlling the electrolytic parameters.Compared with the products CN1 (without catalyst) and CN5 (with 10%catalyst),the specific surface area are 158.957 and 202.246 m^(2)g^(-1),respectively.When used as the electrode material for lithium-ion batteries,CN5 delivered a competitive specific capacity of~350 m Ah g^(-1)(0.5 C) compared with commercial graphite.The strategy proposed in this work provides an effective way to extract value-added graphite materials from lignin and can be extended to the graphitization conversion of any other amorphous carbon precursor materials.展开更多
基金supported by the Accelerator and Detector Research Program,part of the Scientific User Facility Division of the Basic Energy Science Office of the U.S.Department of Energy(DOE),under the Field Work Proposal No.FWP-PS032This research was performed at the Optical Metrology Laboratory at the National Synchrotron Light Source II,a U.S.DOE Office of Science User Facility operated by Brookhaven National Laboratory(BNL)under Contract No.DE-SC0012704This work was performed under the BNL LDRD 17-016“Diffraction limited and wavefront preserving reflective optics development.”This work was also supported by the Natural Science Foundation of Fujian Province,China,under grant number 2022J011245.
文摘Dwell time plays a vital role in determining the accuracy and convergence of the computer-controlled optical surfacing process.However,optimizing dwell time presents a challenge due to its ill-posed nature,resulting in non-unique solutions.To address this issue,several well-known methods have emerged,including the iterative,Bayesian,Fourier transform,and matrix-form methods.Despite their independent development,these methods share common objectives,such as minimizing residual errors,ensuring dwell time's positivity and smoothness,minimizing total processing time,and enabling flexible dwell positions.This paper aims to comprehensively review the existing dwell time optimization methods,explore their interrelationships,provide insights for their effective implementations,evaluate their performances,and ultimately propose a unified dwell time optimization methodology.
基金supported by National Key R&D Program of China (No. 2022YFC2906100)National Natural Science Foundation of China (Nos. 52074036, 51725401, 51874019 and 52022013)Fundamental Research Funds for the Central Universities (No. FRF-TP-17-002C2)。
文摘The ever-growing energy demand and environmental issues have stimulated the development of sustainable energy technologies.Herein,an efficient and environmentally friendly electrochemical transformation technology was proposed to prepare highly graphitized carbon materials from an abundant natural resource-lignin (LG).The preparation process mainly includes pyrolytic carbonization of raw LG material and electrochemical conversion of amorphous carbon precursor.Interestingly,with the assistance of Co catalyst,the graphitization degree of the products was significantly improved,in which the mechanism was the removal of heteroatoms in LG and the rearrangement of carbon atoms into graphite lattice.Furthermore,tunable microstructures (nanoflakes) under catalytic effects could also be observed by controlling the electrolytic parameters.Compared with the products CN1 (without catalyst) and CN5 (with 10%catalyst),the specific surface area are 158.957 and 202.246 m^(2)g^(-1),respectively.When used as the electrode material for lithium-ion batteries,CN5 delivered a competitive specific capacity of~350 m Ah g^(-1)(0.5 C) compared with commercial graphite.The strategy proposed in this work provides an effective way to extract value-added graphite materials from lignin and can be extended to the graphitization conversion of any other amorphous carbon precursor materials.
