The construction of van der Waals(vdW)heterostructures by stacking different two-dimensional layered materials have been recognised as an effective strategy to obtain the desired properties.The 3N-doped graphdiyne(N-G...The construction of van der Waals(vdW)heterostructures by stacking different two-dimensional layered materials have been recognised as an effective strategy to obtain the desired properties.The 3N-doped graphdiyne(N-GY)has been successfully synthesized in the laboratory.It could be assembled into a supercapacitor and can be used for tensile energy storage.However,the flat band and wide forbidden bands could hinder its application of N-GY layer in optoelectronic and nanoelectronic devices.In order to extend the application of N-GY layer in electronic devices,MoS_(2) was selected to construct an N-GY/MoS_(2) heterostructure due to its good electronic and optical properties.The N-GY/MoS_(2) heterostructure has an optical absorption range from the visible to ultraviolet with a absorption coefficient of 10^(5) cm^(-1).The N-GY/MoS_(2) heterostructure exhibits a type-II band alignment allows the electron–hole to be located on N-GY and MoS_(2) respectively,which can further reduce the electron–hole complexation to increase exciton lifetime.The power conversion efficiency of N-GY/MoS_(2) heterostructure is up to 17.77%,indicating it is a promising candidate material for solar cells.In addition,the external electric field and biaxial strain could effectively tune the electronic structure.Our results provide a theoretical support for the design and application of N-GY/MoS_(2) vdW heterostructures in semiconductor sensors and photovoltaic devices.展开更多
Unraveling the nature of complex condensed matter systems is of paramount importance in a variety of fields such as pharmacology and materials science.Here we report the synthesis,by the dynamic covalent chemistry(DCC...Unraveling the nature of complex condensed matter systems is of paramount importance in a variety of fields such as pharmacology and materials science.Here we report the synthesis,by the dynamic covalent chemistry(DCC),of a robust,continuous,and low-defect glassy covalent organic network(GCON).The direct imaging of the molecular structure clearly shows the amorphous nature of GCONs,which consists with the competing(nano)crystallite model,not Zachariasen continuous random networks(Z-CRN).Remarkably,the microscopic friction properties were measured on GCONs by atomic force microscopy(AFM),and the GCONs showed lower friction force in comparison with crystalline covalent organic frameworks(COFs).展开更多
Two-dimensional(2D)transition metal dichalcogenides(TMDCs)-based heterostructures open the door to fabricate various promising hybrid photodetectors,while it is still a challenge to achieve excellent and stable near-i...Two-dimensional(2D)transition metal dichalcogenides(TMDCs)-based heterostructures open the door to fabricate various promising hybrid photodetectors,while it is still a challenge to achieve excellent and stable near-infrared(NIR)photoresponse.Here,a MoS_(2)–2DPI(2D-polyimide(2DPI))heterojunction-based phototransistor(HPT)was fabricated.Near-infrared photodetection with excellent performance has been realized.This HPT exhibited a photoresponsivity of 390.5 A/W,a specific detectivity of 5.10×10^(12)Jones,a photogain 1.04×10^(5),and a photoresponse rise and decay time of 400 and 430 ms(λ=900 nm,P=16.2μW/cm^(2)),respectively.It also shows a broadband wavelength response from 405 to 1,020 nm.This superior performance could be attributed to the strong near-infrared absorption and the type-II(staggered)band alignment which ensures efficient charge transfer from 2DPI to MoS_(2).The face-to-face spatial configuration of MoS_(2)–2DPI heterostructures ensures efficient transfer of photoinduced carriers through the interface,electron and holes can be separated due to the large band offsets.This work presents a significant step for the manipulation of high-performance NIR photodetector of twodimensional covalent organic polymer-sensitized monolayer TMDCs.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62074053 and 61674053)the Natural Science Foundation of Henan Province,China(Grant No.202300410237)+1 种基金the Program for Science&Technology Innovation Talents in Universities of Henan Province,China(Grant No.18HASTIT030)the Fund from Henan Overseas Expertise Introduction Center for Discipline Innovation(Grant No.CXJD2019005).
文摘The construction of van der Waals(vdW)heterostructures by stacking different two-dimensional layered materials have been recognised as an effective strategy to obtain the desired properties.The 3N-doped graphdiyne(N-GY)has been successfully synthesized in the laboratory.It could be assembled into a supercapacitor and can be used for tensile energy storage.However,the flat band and wide forbidden bands could hinder its application of N-GY layer in optoelectronic and nanoelectronic devices.In order to extend the application of N-GY layer in electronic devices,MoS_(2) was selected to construct an N-GY/MoS_(2) heterostructure due to its good electronic and optical properties.The N-GY/MoS_(2) heterostructure has an optical absorption range from the visible to ultraviolet with a absorption coefficient of 10^(5) cm^(-1).The N-GY/MoS_(2) heterostructure exhibits a type-II band alignment allows the electron–hole to be located on N-GY and MoS_(2) respectively,which can further reduce the electron–hole complexation to increase exciton lifetime.The power conversion efficiency of N-GY/MoS_(2) heterostructure is up to 17.77%,indicating it is a promising candidate material for solar cells.In addition,the external electric field and biaxial strain could effectively tune the electronic structure.Our results provide a theoretical support for the design and application of N-GY/MoS_(2) vdW heterostructures in semiconductor sensors and photovoltaic devices.
基金This work was financially supported by the National Science Foundation of China(Nos.52073208,21872103,and 51633006)the Ministry of Science and Technology of China(No 2016YFB0401100).
文摘Unraveling the nature of complex condensed matter systems is of paramount importance in a variety of fields such as pharmacology and materials science.Here we report the synthesis,by the dynamic covalent chemistry(DCC),of a robust,continuous,and low-defect glassy covalent organic network(GCON).The direct imaging of the molecular structure clearly shows the amorphous nature of GCONs,which consists with the competing(nano)crystallite model,not Zachariasen continuous random networks(Z-CRN).Remarkably,the microscopic friction properties were measured on GCONs by atomic force microscopy(AFM),and the GCONs showed lower friction force in comparison with crystalline covalent organic frameworks(COFs).
基金the National Natural Science Foundation of China(Nos.21872103 and 52073208).
文摘Two-dimensional(2D)transition metal dichalcogenides(TMDCs)-based heterostructures open the door to fabricate various promising hybrid photodetectors,while it is still a challenge to achieve excellent and stable near-infrared(NIR)photoresponse.Here,a MoS_(2)–2DPI(2D-polyimide(2DPI))heterojunction-based phototransistor(HPT)was fabricated.Near-infrared photodetection with excellent performance has been realized.This HPT exhibited a photoresponsivity of 390.5 A/W,a specific detectivity of 5.10×10^(12)Jones,a photogain 1.04×10^(5),and a photoresponse rise and decay time of 400 and 430 ms(λ=900 nm,P=16.2μW/cm^(2)),respectively.It also shows a broadband wavelength response from 405 to 1,020 nm.This superior performance could be attributed to the strong near-infrared absorption and the type-II(staggered)band alignment which ensures efficient charge transfer from 2DPI to MoS_(2).The face-to-face spatial configuration of MoS_(2)–2DPI heterostructures ensures efficient transfer of photoinduced carriers through the interface,electron and holes can be separated due to the large band offsets.This work presents a significant step for the manipulation of high-performance NIR photodetector of twodimensional covalent organic polymer-sensitized monolayer TMDCs.