Electrocatalytic carbon dioxide reduction reaction(CO_(2) RR)is a promising method to solve current environment and energy issues.Copper-based catalysts have been widely studied for converting CO_(2) into value-added ...Electrocatalytic carbon dioxide reduction reaction(CO_(2) RR)is a promising method to solve current environment and energy issues.Copper-based catalysts have been widely studied for converting CO_(2) into value-added hy-drocarbon products.Cu monometallic catalyst has been proved to have some shortcomings,including relatively high energy barriers and diverse reaction pathways,leading to low reaction activities and poor product selec-tivity,respectively.Recently copper-based bimetallic tandem catalysts have attracted extensive attentions due to their special catalyst structure,which can be easily regulated to achieve high CO_(2) RR reactivity and product selectivity.With the development of quantum chemistry calculations and spectroscopic characterization methods,deep understandings of CO_(2) RR from the mechanism perspective provide a broad horizon for the design of effi-cient catalysts.This review offers a good summary of reaction mechanisms and product regulation strategies over copper-based bimetallic catalysts,along with a brief discussion on future directions towards their practical applications.展开更多
The wave-induced hydroelastic responses of a thin elastic plate floating on a three-layer fluid, under the assumption of linear potential flow, are investigated for two-dimensional cases. The effect of the lateral str...The wave-induced hydroelastic responses of a thin elastic plate floating on a three-layer fluid, under the assumption of linear potential flow, are investigated for two-dimensional cases. The effect of the lateral stretching or compressive stress is taken into account for plates of either semi-infinite or finite length. An explicit expression for the dispersion relation of the flexural-gravity wave in a three-layer fluid is analytically deduced. The equations for the velocity potential and the wave elevations are solved with the method of matched eigenfunction expansions. To simplify the calculation on the unknown expansion coefficients, a new inner product with orthogonality is proposed for the three-layer fluid, in which the vertical eigenfunctions in the open-water region are involved. The accuracy of the numerical results is checked with an energy conservation equation, representing the energy flux relation among three incident wave modes and the elastic plate. The effects of the lateral stresses on the hydroelastic responses are discussed in detail.展开更多
基金financial support from National Na-ture Science Foundation of China(Nos.22078232 and 21938008)the Science and Technology Major Project of Tianjin(Nos.19ZXNCGX00030 and 20JCYBJC00870)Seed Foundation of Tianjin University(2022XJS-0051).
文摘Electrocatalytic carbon dioxide reduction reaction(CO_(2) RR)is a promising method to solve current environment and energy issues.Copper-based catalysts have been widely studied for converting CO_(2) into value-added hy-drocarbon products.Cu monometallic catalyst has been proved to have some shortcomings,including relatively high energy barriers and diverse reaction pathways,leading to low reaction activities and poor product selec-tivity,respectively.Recently copper-based bimetallic tandem catalysts have attracted extensive attentions due to their special catalyst structure,which can be easily regulated to achieve high CO_(2) RR reactivity and product selectivity.With the development of quantum chemistry calculations and spectroscopic characterization methods,deep understandings of CO_(2) RR from the mechanism perspective provide a broad horizon for the design of effi-cient catalysts.This review offers a good summary of reaction mechanisms and product regulation strategies over copper-based bimetallic catalysts,along with a brief discussion on future directions towards their practical applications.
基金Project supported by the National Basic Research Program of China(973 Programm)(No.2014CB046203)the National Natural Science Foundation of China(No.11472166)the Natural Science Foundation of Shanghai(No.14ZR1416200)
文摘The wave-induced hydroelastic responses of a thin elastic plate floating on a three-layer fluid, under the assumption of linear potential flow, are investigated for two-dimensional cases. The effect of the lateral stretching or compressive stress is taken into account for plates of either semi-infinite or finite length. An explicit expression for the dispersion relation of the flexural-gravity wave in a three-layer fluid is analytically deduced. The equations for the velocity potential and the wave elevations are solved with the method of matched eigenfunction expansions. To simplify the calculation on the unknown expansion coefficients, a new inner product with orthogonality is proposed for the three-layer fluid, in which the vertical eigenfunctions in the open-water region are involved. The accuracy of the numerical results is checked with an energy conservation equation, representing the energy flux relation among three incident wave modes and the elastic plate. The effects of the lateral stresses on the hydroelastic responses are discussed in detail.
