Colloidal synthesis method such as oleylamine(OAm)-stabilized process is of great interest for obtaining uniform and highly dispersed platinum nanoparticle catalysts, yet the ligand may unavoidably inhibit their elect...Colloidal synthesis method such as oleylamine(OAm)-stabilized process is of great interest for obtaining uniform and highly dispersed platinum nanoparticle catalysts, yet the ligand may unavoidably inhibit their electro-catalytic performance. Thus, fully removing these ligands is critical to activate catalyst surface. Previous research of OAm removal process pointed that thermal annealing was the most effective way in comparison with other methods such as chemical washing, UV–Ozone irradiation and cyclic voltammetry sweeping, but generally resulting in undesired growth of platinum nanoparticle. Few studies concerning a more efficient ligand removal process have been published yet. In this work we proposed a platinum in-situ catalytic OAm combustion strategy to elucidate the removal mechanism of OAm ligands in thermal process and the key experimental parameters were also optimized. In addition, heat flow signal based on differential scanning calorimetry(DSC) measurement as a sensitive indicator, is suggested to reveal the ligand removal efficiency, which is much more reliable than the traditional spectroscopy.In comparison with commercial Pt/C sample, such a surface clean Pt/C electrocatalyst has shown an enhanced specific activity for oxygen reduction reaction. Our removal strategy and the evaluation method are highly instructive to efficient removal of different organic ligands.展开更多
Digital geological mapping fundamentally broke through the traditional working pattern,successfully carried out the geological mapping digitalization.By using the RGMAP system to field digital geological mapping,the a...Digital geological mapping fundamentally broke through the traditional working pattern,successfully carried out the geological mapping digitalization.By using the RGMAP system to field digital geological mapping,the authors summarized the method of work and the work flow of the RGMAPGIS during the field geological survey.First,we prepared material,set up the PRB gallery,then put the geographic base map under the background maplayer and organizing the field hand map,forming the field factual datum map.At last,the geological space database is formed.展开更多
Isolation forest and elliptic envelope are used to detect geochemical anomalies,and the bat algorithm was adopted to optimize the parameters of the two models.The two bat-optimized models and their default-parameter c...Isolation forest and elliptic envelope are used to detect geochemical anomalies,and the bat algorithm was adopted to optimize the parameters of the two models.The two bat-optimized models and their default-parameter counterparts were used to detect multivariate geochemical anomalies from the stream sediment survey data of 1:50000 scale collected from the Helong district,Jilin Province,China.Based on the data modeling results,the receiver operating characteristic(ROC)curve analysis was performed to evaluate the performance of the two bat-optimized models and their default-parameter counterparts.The results show that the bat algorithm can improve the performance of the two models by optimizing their parameters in geochemical anomaly detection.The optimal threshold determined by the Youden index was used to identify geochemical anomalies from the geochemical data points.Compared with the anomalies detected by the elliptic envelope models,the anomalies detected by the isolation forest models have higher spatial relationship with the mineral occurrences discovered in the study area.According to the results of this study and previous work,it can be inferred that the background population of the study area is complex,which is not suitable for the establishment of elliptic envelope model.展开更多
基金the financial support by DICP Grant no.ZZBS201705。
文摘Colloidal synthesis method such as oleylamine(OAm)-stabilized process is of great interest for obtaining uniform and highly dispersed platinum nanoparticle catalysts, yet the ligand may unavoidably inhibit their electro-catalytic performance. Thus, fully removing these ligands is critical to activate catalyst surface. Previous research of OAm removal process pointed that thermal annealing was the most effective way in comparison with other methods such as chemical washing, UV–Ozone irradiation and cyclic voltammetry sweeping, but generally resulting in undesired growth of platinum nanoparticle. Few studies concerning a more efficient ligand removal process have been published yet. In this work we proposed a platinum in-situ catalytic OAm combustion strategy to elucidate the removal mechanism of OAm ligands in thermal process and the key experimental parameters were also optimized. In addition, heat flow signal based on differential scanning calorimetry(DSC) measurement as a sensitive indicator, is suggested to reveal the ligand removal efficiency, which is much more reliable than the traditional spectroscopy.In comparison with commercial Pt/C sample, such a surface clean Pt/C electrocatalyst has shown an enhanced specific activity for oxygen reduction reaction. Our removal strategy and the evaluation method are highly instructive to efficient removal of different organic ligands.
基金Supported by National Oil-gas Project:No XQ-2004-07
文摘Digital geological mapping fundamentally broke through the traditional working pattern,successfully carried out the geological mapping digitalization.By using the RGMAP system to field digital geological mapping,the authors summarized the method of work and the work flow of the RGMAPGIS during the field geological survey.First,we prepared material,set up the PRB gallery,then put the geographic base map under the background maplayer and organizing the field hand map,forming the field factual datum map.At last,the geological space database is formed.
基金supported by the National Natural Science Foundation of China(Nos.41672322,41872244)。
文摘Isolation forest and elliptic envelope are used to detect geochemical anomalies,and the bat algorithm was adopted to optimize the parameters of the two models.The two bat-optimized models and their default-parameter counterparts were used to detect multivariate geochemical anomalies from the stream sediment survey data of 1:50000 scale collected from the Helong district,Jilin Province,China.Based on the data modeling results,the receiver operating characteristic(ROC)curve analysis was performed to evaluate the performance of the two bat-optimized models and their default-parameter counterparts.The results show that the bat algorithm can improve the performance of the two models by optimizing their parameters in geochemical anomaly detection.The optimal threshold determined by the Youden index was used to identify geochemical anomalies from the geochemical data points.Compared with the anomalies detected by the elliptic envelope models,the anomalies detected by the isolation forest models have higher spatial relationship with the mineral occurrences discovered in the study area.According to the results of this study and previous work,it can be inferred that the background population of the study area is complex,which is not suitable for the establishment of elliptic envelope model.
