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LED光诱导下咪唑并吡啶氰甲基化反应用于本科实验教学的探索 被引量:2
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作者 汪蕾 宋楚文 +3 位作者 谷青雨 张英华 刘平 孙培培 《大学化学》 CAS 2020年第4期90-95,共6页
可见光催化的有机反应具有高效、条件温和、操作简单、催化剂用量少等优点,近年来受到广泛关注。以咪唑[1,2-a]吡啶杂环为骨架的化合物表现出丰富多样的生物活性,如抗炎、抗病毒活性、抗原生虫药、细胞周期蛋白依赖性激酶抑制剂等。3-... 可见光催化的有机反应具有高效、条件温和、操作简单、催化剂用量少等优点,近年来受到广泛关注。以咪唑[1,2-a]吡啶杂环为骨架的化合物表现出丰富多样的生物活性,如抗炎、抗病毒活性、抗原生虫药、细胞周期蛋白依赖性激酶抑制剂等。3-氰甲基-2-苯基咪唑并[1,2-a]吡啶是合成具有抗抑郁作用的药物唑吡坦的关键中间体。我们在前期的研究工作中,以2-苯基咪唑并[1,2-a]吡啶和溴乙腈为原料,通过可见光诱导,在光催化剂fac-Ir(ppy)3的作用下,合成了3-氰甲基-2-苯基咪唑并[1,2-a]吡啶。本文以此反应为基础,通过将可见光催化这一新型的方法运用于本科实验教学,拓宽本科生的视野,增加其对有机化学实验的兴趣,并掌握微量化学实验的基本操作和相关仪器的使用方法。本设计实验使用LED灯作为光源,避免了剧毒试剂的使用,符合绿色化学理念,具备制备方法简单、生产成本低、产物收率高、重复性良好等优点。 展开更多
关键词 绿色化学 LED光催化 3-氰甲基化咪唑并吡啶类化合物 本科实验教学
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Development of UAV-based shot seeding device for rice planting 被引量:4
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作者 Wei Liu Shuaishuai Zou +9 位作者 Xuelang Xu qingyu gu Weizhuo He Jun Huang Junhao Huang Zichen Lyu Jianqin Lin Zhiyan Zhou Rui Jiang Xiwen Luo 《International Journal of Agricultural and Biological Engineering》 SCIE CAS 2022年第6期1-7,共7页
In order to realize the high-quality row seeding operation with unmanned aerial vehicle(UAV)in paddy field,a shot seeding device that can sow five rows of pelleted rice seeds at the same time was designed.The shot see... In order to realize the high-quality row seeding operation with unmanned aerial vehicle(UAV)in paddy field,a shot seeding device that can sow five rows of pelleted rice seeds at the same time was designed.The shot seeding device mainly consists of an external grooved wheel seed metering device and five shot seeding modules.The designed external grooved wheel seed metering device can take the seeds out of the seed box and divide the seeds into five parts.The shot seeding module can accelerate the pelleted rice seeds to reduce the impact of the UAV wind on the direction of seed movement.Furthermore,an angle adjustment mechanism for the shot seeding module was used to change the row spacing.The seed metering device test verified that when the speed of the seed metering wheel was 15 r/min,the coefficient of variation of the discharge rate of each row(C.V1)and total seed discharge rate stability(C.V2)were 1.70%and 1.04%,respectively.Image processing technique was used to test the UAV seeding performance.The distribution characteristics of seeds on the ground showed that the number of seeds in each row gradually increased from both sides to the middle in the width direction.According to the statistics,there were 60%-70%of the seeds in each row in the 100 mm width range.The field test showed that when the working height was 1.5 m and the seeding quantity was 38.56 kg/hm^(2),the performance of sowing in rows was obvious,the deviation rate of seeding quantity was 1.89%.After 16 d of sowing,the seeds’emergence rate was stable,and the average emergence rate was 82.63%and the yield was 6775.50 kg/hm^(2). 展开更多
关键词 unmanned aerial vehicle rice direct seeding row seeding pelleted rice seeds
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