In this work,a CdS/BivO4 step-scheme(S-scheme)heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI)photoextraction.Characterizations such as transient a...In this work,a CdS/BivO4 step-scheme(S-scheme)heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI)photoextraction.Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions,which allows CdS/BivO_(4) to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BivO_(4).Experimental results such as radical quenching experiments and electron spin resonance show that U(VI)is rapidly oxidized by photoholes/·OH to insoluble UO(OH)2 after being reduced to U(IV)by photoelectrons/·O2,which precisely avoids the depletion of electron sacrificial agents.The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis.This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts.展开更多
Charging piles are used for charging electric vehicles and are directly accessible to users in an energy internet entrance,while playing an important role in energy consumption.Currently,each enterprise constructs the...Charging piles are used for charging electric vehicles and are directly accessible to users in an energy internet entrance,while playing an important role in energy consumption.Currently,each enterprise constructs the center of operation and maintenance of their systems independently,along with their respective APP payment programs.This results in high operating costs,poor user experience,and low utilization rate of the pile,which limits the promotion and popularization of electric vehicles.To overcome this limitation,there is a need for a multi-center,fair,and transparent consortium blockchain,which can conform to the application requirements of a unified payment system and accommodate a range of diverse enterprise charging piles.In this paper,the design for a consensus and incentive program for consortium blockchain is presented.First,the application status of blockchain in an energy internet is described.Then,the logical structure and hierarchical model of the consortium blockchain are analyzed.Next,multicycle accounting and limiting the amount of accounting nodes in each round is presented to ensure the overhead of consensus remain constant.Finally,the accounting incentive mechanism and the bidding encouragement strategy based on“electric beans”are designed.展开更多
基金funded by the National Key Research and Development Program of China(2018YFC1900105)National Natural Science Foundation of China(U21A20290,21876047)the Beijing Outstanding Young Scientist Program,and the Thousand Talents Plan of Qinghai province.
文摘In this work,a CdS/BivO4 step-scheme(S-scheme)heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI)photoextraction.Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions,which allows CdS/BivO_(4) to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BivO_(4).Experimental results such as radical quenching experiments and electron spin resonance show that U(VI)is rapidly oxidized by photoholes/·OH to insoluble UO(OH)2 after being reduced to U(IV)by photoelectrons/·O2,which precisely avoids the depletion of electron sacrificial agents.The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis.This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts.
基金This research is supported by the Science and Technology Project of State Grid Corporation of China(SAP No.52110417000G).
文摘Charging piles are used for charging electric vehicles and are directly accessible to users in an energy internet entrance,while playing an important role in energy consumption.Currently,each enterprise constructs the center of operation and maintenance of their systems independently,along with their respective APP payment programs.This results in high operating costs,poor user experience,and low utilization rate of the pile,which limits the promotion and popularization of electric vehicles.To overcome this limitation,there is a need for a multi-center,fair,and transparent consortium blockchain,which can conform to the application requirements of a unified payment system and accommodate a range of diverse enterprise charging piles.In this paper,the design for a consensus and incentive program for consortium blockchain is presented.First,the application status of blockchain in an energy internet is described.Then,the logical structure and hierarchical model of the consortium blockchain are analyzed.Next,multicycle accounting and limiting the amount of accounting nodes in each round is presented to ensure the overhead of consensus remain constant.Finally,the accounting incentive mechanism and the bidding encouragement strategy based on“electric beans”are designed.
