In Fig.4(a)of the article,the range ofλ(w)exhibited by the horizontal coordinate of the middle panel should be from 0 to 2,instead of 0 to 1.Figure 4(a)should be as follows:We note that this mistake does not affect t...In Fig.4(a)of the article,the range ofλ(w)exhibited by the horizontal coordinate of the middle panel should be from 0 to 2,instead of 0 to 1.Figure 4(a)should be as follows:We note that this mistake does not affect the conclusion of our report,and apologize to readers for any inconvenience caused by our oversight.展开更多
Single-layer superconductors are ideal materials for fabricating superconducting nano devices.However,up to date,very few single-layer elemental superconductors have been predicted and especially no one has been succe...Single-layer superconductors are ideal materials for fabricating superconducting nano devices.However,up to date,very few single-layer elemental superconductors have been predicted and especially no one has been successfully synthesized yet.Here,using crystal structure search techniques and ab initio calculations,we predict that a single-layer planar carbon sheet with 4-and 8-membered rings called T-graphene is a new intrinsic elemental superconductor with superconducting critical temperature(Tc)up to around 20.8 K.More importantly,we propose a synthesis route to obtain such a single-layer T-graphene,that is,a T-graphene potassium intercalation compound(C4 K with P4/mmm symmetry)is firstly synthesized at high pressure(>11.5 GPa)and then quenched to ambient condition;and finally,the single-layer T-graphene can be either exfoliated using the electrochemical method from the bulk C4 K,or peeled off from bulk T-graphite C4,where C4 can be obtained from C4 K by evaporating the K atoms.Interestingly,we find that the calculated Tc of C4 K is about 30.4 K at 0 GPa,which sets a new record for layered carbon-based superconductors.The present findings add a new class of carbon-based superconductors.In particular,once the single-layer T-graphene is synthesized,it can pave the way for fabricating superconducting devices together with other 2 D materials using the layer-by-layer growth techniques.展开更多
It has recently been found that nonsymmorphic symmetries can bring many exotic band crossings.Here,based on symmetry analysis,we predict that materials with time-reversal symmetry in the space group of Pbca(No.61)poss...It has recently been found that nonsymmorphic symmetries can bring many exotic band crossings.Here,based on symmetry analysis,we predict that materials with time-reversal symmetry in the space group of Pbca(No.61)possess rich symmetry-enforced band crossings,including nodal surfaces,fourfold degenerate nodal lines and hourglass Dirac loops,which appear in triplets as ensured by the cyclic permutation symmetry.We take Pbca AgF_(2) as an example in real systems and studied its band structures with ab initio calculations.Specifically,in the absence of spin-orbit coupling(SOC),besides the above-mentioned band degeneracies,this system features a nodal chain and a nodal armillary sphere penetrating the Brillouin zone(BZ).While with SOC,we find a new configuration of the hourglass Dirac loop/chain with the feature traversing the BZ,which originates from the splitting of a Dirac loop confined in the BZ.Furthermore,guided by the bulk-surface correspondence,we calculated the surface states to explore these bulk nodal phenomena.The evolution of these interesting nodal phenomena traversing the BZ under two specific uniaxial strains is also discussed.展开更多
文摘In Fig.4(a)of the article,the range ofλ(w)exhibited by the horizontal coordinate of the middle panel should be from 0 to 2,instead of 0 to 1.Figure 4(a)should be as follows:We note that this mistake does not affect the conclusion of our report,and apologize to readers for any inconvenience caused by our oversight.
基金Supported by the National Key Research and Development Program of China under Grant No 2016YFA0300404the National Basic Research Program of China under Grant No 2015CB921202+2 种基金the National Nature Science Foundation of China under Grant Nos 11574133 and 11834006the Nature Science Foundation of Jiangsu Province under Grant No BK20150012the Fundamental Research Funds for the Central Universities,the Science Challenge Project(No TZ2016001)
文摘Single-layer superconductors are ideal materials for fabricating superconducting nano devices.However,up to date,very few single-layer elemental superconductors have been predicted and especially no one has been successfully synthesized yet.Here,using crystal structure search techniques and ab initio calculations,we predict that a single-layer planar carbon sheet with 4-and 8-membered rings called T-graphene is a new intrinsic elemental superconductor with superconducting critical temperature(Tc)up to around 20.8 K.More importantly,we propose a synthesis route to obtain such a single-layer T-graphene,that is,a T-graphene potassium intercalation compound(C4 K with P4/mmm symmetry)is firstly synthesized at high pressure(>11.5 GPa)and then quenched to ambient condition;and finally,the single-layer T-graphene can be either exfoliated using the electrochemical method from the bulk C4 K,or peeled off from bulk T-graphite C4,where C4 can be obtained from C4 K by evaporating the K atoms.Interestingly,we find that the calculated Tc of C4 K is about 30.4 K at 0 GPa,which sets a new record for layered carbon-based superconductors.The present findings add a new class of carbon-based superconductors.In particular,once the single-layer T-graphene is synthesized,it can pave the way for fabricating superconducting devices together with other 2 D materials using the layer-by-layer growth techniques.
基金At last,we thank for the financial support from MOST of China(Grant Nos:2016YFA0300404 and 2015CB921202)the National Natural Science Foundation of China(Grant Nos:11574133,11834006)+1 种基金the NSF Jiangsu province in China(No.BK20150012)the Fundamental Research Funds for the Central Universities and the program B for Outstanding Ph.D candidate of Nanjing University.
文摘It has recently been found that nonsymmorphic symmetries can bring many exotic band crossings.Here,based on symmetry analysis,we predict that materials with time-reversal symmetry in the space group of Pbca(No.61)possess rich symmetry-enforced band crossings,including nodal surfaces,fourfold degenerate nodal lines and hourglass Dirac loops,which appear in triplets as ensured by the cyclic permutation symmetry.We take Pbca AgF_(2) as an example in real systems and studied its band structures with ab initio calculations.Specifically,in the absence of spin-orbit coupling(SOC),besides the above-mentioned band degeneracies,this system features a nodal chain and a nodal armillary sphere penetrating the Brillouin zone(BZ).While with SOC,we find a new configuration of the hourglass Dirac loop/chain with the feature traversing the BZ,which originates from the splitting of a Dirac loop confined in the BZ.Furthermore,guided by the bulk-surface correspondence,we calculated the surface states to explore these bulk nodal phenomena.The evolution of these interesting nodal phenomena traversing the BZ under two specific uniaxial strains is also discussed.