Mesoporous aluminosilicate with cubic ordered structure was synthesized by two-step crystallization, which showed stronger acid sites and more effective activity for catalytic alkylation of 2, 4-ditert-butylphenol wit...Mesoporous aluminosilicate with cubic ordered structure was synthesized by two-step crystallization, which showed stronger acid sites and more effective activity for catalytic alkylation of 2, 4-ditert-butylphenol with tert-butanol than conventional H-AlMCM-48 materials.展开更多
The AlMCM-41 molecular sieves with two different pore sizes are hydrothermally synthesized in the presence of surfactants with two different chain lengths. H-AlMCM-41 and Ru-Sn-B/H-AlMCM-41 which are prepared by the ...The AlMCM-41 molecular sieves with two different pore sizes are hydrothermally synthesized in the presence of surfactants with two different chain lengths. H-AlMCM-41 and Ru-Sn-B/H-AlMCM-41 which are prepared by the conventional ion-exchange and incipient wetness techniques of the AlMCM-41 show fair catalytic activity for esterification of glycerol by oleic acid and selective hydrogenation of oleic acid methylester, respectively.展开更多
基金We thank financial support by the National Natural Science Foundation of China(grant 29973001).
文摘Mesoporous aluminosilicate with cubic ordered structure was synthesized by two-step crystallization, which showed stronger acid sites and more effective activity for catalytic alkylation of 2, 4-ditert-butylphenol with tert-butanol than conventional H-AlMCM-48 materials.
文摘The AlMCM-41 molecular sieves with two different pore sizes are hydrothermally synthesized in the presence of surfactants with two different chain lengths. H-AlMCM-41 and Ru-Sn-B/H-AlMCM-41 which are prepared by the conventional ion-exchange and incipient wetness techniques of the AlMCM-41 show fair catalytic activity for esterification of glycerol by oleic acid and selective hydrogenation of oleic acid methylester, respectively.