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聚硅烷类嵌段共聚物的聚合反应动力学及相分离机理 被引量:2
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作者 何磊 黄秋月 +3 位作者 朱秀芳 洪坤 云山 张加栋 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2018年第6期22-26,35,共6页
以聚甲基苯基硅烷为引发剂,在紫外光照下与乙烯基单体聚合形成聚硅烷类嵌段共聚物。基于聚合反应动力学模型,就单体、紫外光强、质量比对反应动力学参数以及嵌段长度的影响进行解析。进一步结合相分离观察的结果,分析了此类共聚物中发... 以聚甲基苯基硅烷为引发剂,在紫外光照下与乙烯基单体聚合形成聚硅烷类嵌段共聚物。基于聚合反应动力学模型,就单体、紫外光强、质量比对反应动力学参数以及嵌段长度的影响进行解析。进一步结合相分离观察的结果,分析了此类共聚物中发生相分离与否的影响因素。结果表明,光聚合后仅1000 s后碳嵌段平均长度就收拢于5~6个碳原子,硅元素嵌段平均长度也降低到2左右,表明此类材料未发生相分离,是适用于光波导领域的理想材料。 展开更多
关键词 聚硅烷嵌段共聚物 聚合反应动力学 相分离 速率常数
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Intrinsically flexible all-carbon-nanotube electronics enabled by a hybrid organic-inorganic gate dielectric
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作者 qiuyue huang Jialiang Wang +9 位作者 Chenglin Li Jiahao Zhu Wanting Wang Youchao huang Yiming Zhang Hailong Jiao Shengdong Zhang Hong Meng Min Zhang Xinwei Wang 《npj Flexible Electronics》 SCIE 2022年第1期569-580,共12页
The advancement of Internet of Things has stimulated huge demands on low-voltage flexible electronics.Carbon-nanotube(CNT)-based electronics are of great promise to this end for their intrinsic flexibility,high carrie... The advancement of Internet of Things has stimulated huge demands on low-voltage flexible electronics.Carbon-nanotube(CNT)-based electronics are of great promise to this end for their intrinsic flexibility,high carrier mobility,and capability to synthesize as semiconducting or metallic to serve as the channels,electrodes,and interconnects of circuits.However,the gate dielectric often has to adopt brittle oxides,which can seriously limit the device flexibility.Herein,we show that a hybrid polyimide-Al2O3 material can serve as a good gate dielectric to realize truly intrinsic flexibility of transistors and circuits based on CNTs.With this hybrid dielectric,high-performance all-CNT transistors and integrated circuits of inverters,ring oscillators,and logic gates are demonstrated.Particularly,the inverters exhibit a remarkably high gain of 342.5 and can be used as an analog amplifier for millivolt small signals.Ultralow voltage(50 mV)operation is also feasible,which highlights the great promise for low-power applications. 展开更多
关键词 AMPLIFIER dielectric INVERTER
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