Thick electrodes can increase incorporation of active electrode materials by diminishing the proportion of inactive constituents,improving the overall energy density of batteries.However,thick electrodes fabricated us...Thick electrodes can increase incorporation of active electrode materials by diminishing the proportion of inactive constituents,improving the overall energy density of batteries.However,thick electrodes fabricated using the conventional slurry casting approach frequently exhibit an exacerbated accumulation of carbon additives and binders on their surfaces,invariably leading to compromised electrochemical properties.In this study,we introduce a designed conductive agent/binder composite synthesized from carbon nanotube and polytetrafluoroethylene.This agent/binder composite facilitates production of dry-process-prepared ultra-thick electrodes endowed with a three-dimensional and uniformly distributed percolative architecture,ensuring superior electronic conductivity and remarkable mechanical resilience.Using this approach,ultra-thick LiCoO_(2)(LCO) electrodes demonstrated superior cycling performance and rate capabilities,registering an impressive loading capacity of up to 101.4 mg/cm^(2),signifying a 242% increase in battery energy density.In another analytical endeavor,time-of-flight secondary ion mass spectroscopy was used to clarify the distribution of cathode electrolyte interphase(CEI) in cycled LCO electrodes.The results provide unprecedented evidence explaining the intricate correlation between CEI generation and carbon distribution,highlighting the intrinsic advantages of the proposed dry-process approach in fine-tu ning the CEI,with excellent cycling performance in batteries equipped with ultra-thick electrodes.展开更多
Quasi-solid-state lithium metal battery is a promising candidate for next generation high energy density and high safety power supply.Despite intensive efforts on electrolytes,uncontrolled interfacial reactions on lit...Quasi-solid-state lithium metal battery is a promising candidate for next generation high energy density and high safety power supply.Despite intensive efforts on electrolytes,uncontrolled interfacial reactions on lithium with electrolyte and patchy interfacial contacts still hinder its practical process.Herein,we bring in rationally designed F contained groups into polymer skeleton via in-situ gelation for the first time to establish quasi-solid-state battery.This method achieves a capacity retention of 90%after 1000 cycles at 0.5C with LiFePO_(4)cathodes.The interface constructed by polymer skeleton and reaction with–CF_(3)lead to the predicted solid electrolyte interface species with high stability.Furthermore,we optimize molecular reactivity and interface stability with regulating F contained end groups in the polymer.Comparisons on different structures reveal that high performance solid stable lithium metal batteries rely on chemical modification as well as stable polymer skeleton,which is more critical to construct robust and steady SEI with uniform lithium deposition.New approach with functional groups regulation proposes a more stable cycling process with a capacity retention of 94.2%at 0.5C and 87.6%at 1C after 1000 cycles with LiFePO_(4) cathodes,providing new insights for the practical development of quasi-solid-state lithium metal battery.展开更多
With the booming development of lithium-ion batteries,safety has become one of the most primary focuses of current researches.Although there are various approaches to enhance the safety of lithiumion batteries,phospha...With the booming development of lithium-ion batteries,safety has become one of the most primary focuses of current researches.Although there are various approaches to enhance the safety of lithiumion batteries,phosphate-based electrolyte holds the greatest potential for practical application due to their non-flammability.Nonetheless,its compatibility issue with the graphite anode remains a significant obstacle to its widespread use.Herein,an effective method is proposed to improve the compatibility of electrolyte with graphite(Gr)anode by rationally adjusting the proportion of lithium salt and solvent components to optimize the Li^(+)solvation structure.By slightly increasing the Li^(+)/triethyl phosphate(TEP)ratio,TEP alone cannot fully occupy the inner solvation sheath and therefore less polar ethylene carbonate(EC)has to be recruited,and the solvation structure gradually changes from Li^(+)–[TEP]_(4)to Li^(+)–[TEP]_(3)[EC]with the coexistence of EC and TEP.Simultaneously,EC molecules in the Li^(+)–[TEP]_(3)[EC]could be preferentially reduced on graphite compared to the TEP molecules,resulting in the formation of a uniform and durable solid-electrolyte interphase(SEI)layer.Benefiting from the optimized phosphate-based electrolyte,the Gr|Li battery exhibits a capacity retention rate of 96.8%after stable cycling at 0.5 C for 470 cycles which shows a longer cycle life than the battery with carbonate electrolyte(cycling at 0.5 C for 450 cycles).Therefore,this work provides the guidance for designing a non-flammable phosphate-based electrolyte for high-safety and long cycling-life lithium-ion batteries.展开更多
This paper presents designing sequence-to-sequence recurrent neural network(RNN)architectures for a novel study to predict soil NOx emissions,driven by the imperative of understanding and mitigating environmental impa...This paper presents designing sequence-to-sequence recurrent neural network(RNN)architectures for a novel study to predict soil NOx emissions,driven by the imperative of understanding and mitigating environmental impact.The study utilizes data collected by the Environmental Protection Agency(EPA)to develop two distinct RNN predictive models:one built upon the long-short term memory(LSTM)and the other utilizing the gated recurrent unit(GRU).These models are fed with a combination of historical and anticipated air temperature,air moisture,and NOx emissions as inputs to forecast future NOx emissions.Both LSTM and GRU models can capture the intricate pulse patterns inherent in soil NOx emissions.Notably,the GRU model emerges as the superior performer,surpassing the LSTM model in predictive accuracy while demonstrating efficiency by necessitating less training time.Intriguingly,the investigation into varying input features reveals that relying solely on past NOx emissions as input yields satisfactory performance,highlighting the dominant influence of this factor.The study also delves into the impact of altering input series lengths and training data sizes,yielding insights into optimal configurations for enhanced model performance.Importantly,the findings promise to advance our grasp of soil NOx emission dynamics,with implications for environmental management strategies.Looking ahead,the anticipated availability of additional measurements is poised to bolster machine-learning model efficacy.Furthermore,the future study will explore physical-based RNNs,a promising avenue for deeper insights into soil NOx emission prediction.展开更多
The 100 crystal-oriented silicon micropillar array platforms were prepared by microfabrication processes for the purpose of electrolyte additive identification. The silicon micropillar array platform was used for the ...The 100 crystal-oriented silicon micropillar array platforms were prepared by microfabrication processes for the purpose of electrolyte additive identification. The silicon micropillar array platform was used for the study of fluorinated vinyl carbonate(FEC), vinyl ethylene carbonate(VEC), ethylene sulfite(ES), and vinyl carbonate(VC) electrolyte additives in the LiPF_6 dissolved in a mixture of ethylene carbonate and diethyl carbonate electrolyte system using charge/discharge cycles, electrochemical impedance spectroscopy, cyclic voltammetry, scanning electron microscopy, and x-ray photoelectron spectroscopy. The results show that the silicon pillar morphology displays cross-shaped expansion after lithiation/delithiation, the inorganic lithium salt keeps the silicon pillar morphology intact, and the organic lithium salt content promotes a rougher silicon pillar surface. The presence of poly-(VC) components on the surface of FEC and VC electrodes allows the silicon pillar to accommodate greater volume expansion while remaining intact. This work provides a standard, fast, and effective test method for the performance analysis of electrolyte additives and provides guidance for the development of new electrolyte additives.展开更多
The scale factor of a superconducting gravimeter(SG) is usually calibrated by using simultaneous and co-located gravity measurements with the FG5-type absolute gravimeter(AG). In this paper, another new kind of ab...The scale factor of a superconducting gravimeter(SG) is usually calibrated by using simultaneous and co-located gravity measurements with the FG5-type absolute gravimeter(AG). In this paper, another new kind of absolute gravimetercold atom gravimeter(CAG) is first reported to calibrate the SG. Five-day side-by-side gravity measurements have been carried out by using our CAG(NIM-AGRb-1) to calibrate the SG(iGrav-012) located at Changping Campus of the National Institute of Metrology(NIM) of China. A weighted least-squares method is applied to determine the scale factor and the result is given as(-928.01 ± 0.73) nm·s;·V;with a precision of 0.79‰. We have demonstrated that a calibration precision of 1‰ level can be achieved after 3 days of parallel observations at spring tide. The obtained calibration results are then compared with the previous calibration by FG5 X-249, which shows that the calibration precision obtained by using NIM-AGRb-1 was slightly higher than FG5 X-249 with the same time interval. The factors affecting the calibration precision are analyzed in the calibrations by means of different AGs. Finally, several calibration experiments for SG iGrav-012 are discussed. The final scale factor is estimated as(-927.58 ± 0.36) nm·s;·V;with an accuracy of 0.39‰. Our main results demonstrate that the CAGs can be used for high-precision calibrations of SGs.展开更多
The competition between the RKKY interaction and the Kondo effect leads to a magnetic phase transition,which occurs ubiquitously in heavy fermion materials.However,there are more and more experimental evidences indica...The competition between the RKKY interaction and the Kondo effect leads to a magnetic phase transition,which occurs ubiquitously in heavy fermion materials.However,there are more and more experimental evidences indicating that the valence fluctuation plays an essential role in the Ce-and Y-based compounds.We study an extended periodic Anderson model(EPAM)which includes the onsite Coulomb repulsion Ucf between the localized electrons and conduction electrons.By employing the density matrix embedding theory,we investigate the EPAM in the symmetric case at half filling.By fixing the onsite Coulomb repulsion U of the localized electrons to an intermediate value,the interplay between the RKKY interaction,the Kondo effect and the Coulomb repulsion Ucf brings rich physics.We find three different phases,the antiferromagnetic phase,the charge order phase and paramagnetic phase.When the hybridization strength V between the localized orbital and the conduction orbital is small,the Kondo effect is weak so that the AF phase and the CO phase are present.The phase transition between the two long-range ordered phase is of first order.We also find a coexistence region between the two phases.As V increases,the Kondo effect becomes stronger,and the paramagnetic phase appears between the other two phases.展开更多
Modulation of a vector light field has played an important role in the research of nanophotonics.However,it is still a great challenge to accurately measure the three-dimensional vector distribution at nanoscale.Here,...Modulation of a vector light field has played an important role in the research of nanophotonics.However,it is still a great challenge to accurately measure the three-dimensional vector distribution at nanoscale.Here,based on the interaction between the light field and atomic-sized nitrogen-vacancy(NV)color center in diamonds,we demonstrate an efficient method for vectorial mapping of the light-field distribution at nanoscale.Single NV centers with different but well-defined symmetry axes are selected and then interact with the same tightly focused light field.The excitation of a single NV center is related to the angle between the NV center axis and the polarization of the light field.Then the fluorescence patterns of different NV centers provide the information on the vectorial light field distribution.Subsequently analyzing the fluorescence patterns with the help of a deep neural network,the intensity and phase of the light-field vectorial components are fully reconstructed with nanometer resolution.The experimental results are in agreement with theoretical calculations.It demonstrates that our method can help to study light–matter interaction at nanoscale and extend the application of vector light fields in research on nanophotonics.展开更多
The anionic redox reaction(ARR)is a promising charge contributor to improve the reversible capacity of layeredoxide cathodes for Na-ion batteries;however,some practical bottlenecks still need to be eliminated,includin...The anionic redox reaction(ARR)is a promising charge contributor to improve the reversible capacity of layeredoxide cathodes for Na-ion batteries;however,some practical bottlenecks still need to be eliminated,including a low capacity retention,large voltage hysteresis,and low rate capability.Herein,we proposed a high-Na content honeycomb-ordered cathode,P2–Na_(5/6)[Li_(1/6)Cu_(1/6)Mn_(2/3)]O_(2)(P2-NLCMO),with combined cationic/anionic redox.Neutron powder diffraction and X-ray diffraction of P2-NLCMO suggested P2-type stacking with rarely found P6322 symmetry.In addition,advanced spectroscopy techniques and density functional theory calculations confirmed the synergistic stabilizing relationship between the Li/Cu dual honeycomb centers,achieving fully active Cu^(3+)/Cu^(2+) redox and stabilized ARR with interactively suppressed local distortion.With a meticulously regulated charge/discharge protocol,both the cycling and rate capability of P2-NLCMO were significantly.展开更多
The first Asia-Pacific Comparison of Absolute Gravimeters(APMP.M.G-K1) was organized by the National Institute of Metrology(NIM) of China from December 21, 2015 to March 25, 2016 in Changping, Beijing. Our compact col...The first Asia-Pacific Comparison of Absolute Gravimeters(APMP.M.G-K1) was organized by the National Institute of Metrology(NIM) of China from December 21, 2015 to March 25, 2016 in Changping, Beijing. Our compact cold atom gravimeter(CCAG) was transported from Hangzhou to Beijing with a long distance of about1200 km to participate in this comparison. The CCAG is the only one, to the best of our knowledge, that is based on the principle of atom interferometry among all the instruments. Absolute gravity in the indicated three test sites has been measured as requested by the organizer. The sensitivity of our CCAG is estimated to be90 μGal∕Hz p, even when the measurements are carried out without any vibration isolation. Besides, the accuracy of this gravimeter has been evaluated to be about 19 μGal by considering the significant system errors.Our results show a good agreement with the given reference value.展开更多
FF sample(nearly free ofδ-ferrite)and CF sample(containing∼4%δ-ferrite)were prepared from the AISI 316 austenitic stainless steel plate to elucidate the role ofδ-ferrite in the fatigue crack growth under the solut...FF sample(nearly free ofδ-ferrite)and CF sample(containing∼4%δ-ferrite)were prepared from the AISI 316 austenitic stainless steel plate to elucidate the role ofδ-ferrite in the fatigue crack growth under the solution treated and accelerated aged conditions.It is found that the fatigue crack growth resistance of the CF sample is higher than the FF sample under the solution treated condition.However,a significant deterioration of the fatigue crack growth resistance is observed in the CF sample while little variation is found in the FF sample after accelerated aging treatment at 750°C for 10 h.In the solution treated condition,deflected crack growth path is present when the main crack encounters theδ-ferrite in the CF sample due to the differences in the fatigue responses between austenite andδ-ferrite.The measured growth rate of the deflected crack is significantly slower than that of the flat crack of the same length.After the accelerated aging treatment,microcracks are produced at the M_(23)C_(6)/δinterface due to the strain incompatibility between M_(23)C_(6) and retainedδ-ferrite when the decomposedδ-ferrite is subject to plastic deformation in the crack tip plastic zone.The preexisting microcracks in the front of crack tip provide a viable path for crack propagation,resulting in the relatively flat crack path.展开更多
基金supported by the National Key Research and Development Program of China,China(2019YFA0705102)the National Natural Science Foundation of China,China(22179144,22005332)。
文摘Thick electrodes can increase incorporation of active electrode materials by diminishing the proportion of inactive constituents,improving the overall energy density of batteries.However,thick electrodes fabricated using the conventional slurry casting approach frequently exhibit an exacerbated accumulation of carbon additives and binders on their surfaces,invariably leading to compromised electrochemical properties.In this study,we introduce a designed conductive agent/binder composite synthesized from carbon nanotube and polytetrafluoroethylene.This agent/binder composite facilitates production of dry-process-prepared ultra-thick electrodes endowed with a three-dimensional and uniformly distributed percolative architecture,ensuring superior electronic conductivity and remarkable mechanical resilience.Using this approach,ultra-thick LiCoO_(2)(LCO) electrodes demonstrated superior cycling performance and rate capabilities,registering an impressive loading capacity of up to 101.4 mg/cm^(2),signifying a 242% increase in battery energy density.In another analytical endeavor,time-of-flight secondary ion mass spectroscopy was used to clarify the distribution of cathode electrolyte interphase(CEI) in cycled LCO electrodes.The results provide unprecedented evidence explaining the intricate correlation between CEI generation and carbon distribution,highlighting the intrinsic advantages of the proposed dry-process approach in fine-tu ning the CEI,with excellent cycling performance in batteries equipped with ultra-thick electrodes.
基金support from the National Natural Science Foundation of China(52034011)the Fundamental Research Funds for the Science and Technology Program of Hunan Province(2019RS3002)+1 种基金the Central Universities of Central South University(Grant No.2018zzts133)Science and Technology Innovation Program of Hunan Province(2020RC2006).
文摘Quasi-solid-state lithium metal battery is a promising candidate for next generation high energy density and high safety power supply.Despite intensive efforts on electrolytes,uncontrolled interfacial reactions on lithium with electrolyte and patchy interfacial contacts still hinder its practical process.Herein,we bring in rationally designed F contained groups into polymer skeleton via in-situ gelation for the first time to establish quasi-solid-state battery.This method achieves a capacity retention of 90%after 1000 cycles at 0.5C with LiFePO_(4)cathodes.The interface constructed by polymer skeleton and reaction with–CF_(3)lead to the predicted solid electrolyte interface species with high stability.Furthermore,we optimize molecular reactivity and interface stability with regulating F contained end groups in the polymer.Comparisons on different structures reveal that high performance solid stable lithium metal batteries rely on chemical modification as well as stable polymer skeleton,which is more critical to construct robust and steady SEI with uniform lithium deposition.New approach with functional groups regulation proposes a more stable cycling process with a capacity retention of 94.2%at 0.5C and 87.6%at 1C after 1000 cycles with LiFePO_(4) cathodes,providing new insights for the practical development of quasi-solid-state lithium metal battery.
基金the National Natural Science Foundation of China(52034011 and 52101278)the Central South University Research Programme of Advanced Interdisciplinary Studies(2023QYJC005)the Fundamental Research Funds for Central Universities of the Central South University(2022ZZTS0405)。
文摘With the booming development of lithium-ion batteries,safety has become one of the most primary focuses of current researches.Although there are various approaches to enhance the safety of lithiumion batteries,phosphate-based electrolyte holds the greatest potential for practical application due to their non-flammability.Nonetheless,its compatibility issue with the graphite anode remains a significant obstacle to its widespread use.Herein,an effective method is proposed to improve the compatibility of electrolyte with graphite(Gr)anode by rationally adjusting the proportion of lithium salt and solvent components to optimize the Li^(+)solvation structure.By slightly increasing the Li^(+)/triethyl phosphate(TEP)ratio,TEP alone cannot fully occupy the inner solvation sheath and therefore less polar ethylene carbonate(EC)has to be recruited,and the solvation structure gradually changes from Li^(+)–[TEP]_(4)to Li^(+)–[TEP]_(3)[EC]with the coexistence of EC and TEP.Simultaneously,EC molecules in the Li^(+)–[TEP]_(3)[EC]could be preferentially reduced on graphite compared to the TEP molecules,resulting in the formation of a uniform and durable solid-electrolyte interphase(SEI)layer.Benefiting from the optimized phosphate-based electrolyte,the Gr|Li battery exhibits a capacity retention rate of 96.8%after stable cycling at 0.5 C for 470 cycles which shows a longer cycle life than the battery with carbonate electrolyte(cycling at 0.5 C for 450 cycles).Therefore,this work provides the guidance for designing a non-flammable phosphate-based electrolyte for high-safety and long cycling-life lithium-ion batteries.
基金support from the University of Iowa Jumpstarting Tomorrow Community Feasibility Grants and OVPR Interdisciplinary Scholars Program for this study.Z.Wang and S.Xiao received support from the U.S.Department of Education(E.D.#P116S210005)Q.Wang and J.Wang acknowledge the support from NASA Atmospheric Composition Modeling and Analysis Program(ACMAP,Grant#:80NSSC19K0950).
文摘This paper presents designing sequence-to-sequence recurrent neural network(RNN)architectures for a novel study to predict soil NOx emissions,driven by the imperative of understanding and mitigating environmental impact.The study utilizes data collected by the Environmental Protection Agency(EPA)to develop two distinct RNN predictive models:one built upon the long-short term memory(LSTM)and the other utilizing the gated recurrent unit(GRU).These models are fed with a combination of historical and anticipated air temperature,air moisture,and NOx emissions as inputs to forecast future NOx emissions.Both LSTM and GRU models can capture the intricate pulse patterns inherent in soil NOx emissions.Notably,the GRU model emerges as the superior performer,surpassing the LSTM model in predictive accuracy while demonstrating efficiency by necessitating less training time.Intriguingly,the investigation into varying input features reveals that relying solely on past NOx emissions as input yields satisfactory performance,highlighting the dominant influence of this factor.The study also delves into the impact of altering input series lengths and training data sizes,yielding insights into optimal configurations for enhanced model performance.Importantly,the findings promise to advance our grasp of soil NOx emission dynamics,with implications for environmental management strategies.Looking ahead,the anticipated availability of additional measurements is poised to bolster machine-learning model efficacy.Furthermore,the future study will explore physical-based RNNs,a promising avenue for deeper insights into soil NOx emission prediction.
基金supported by the National Key R&D Program of China (Grant Nos. 2016YFB0100500 and 2016YFB0100100)the National Natural Science Foundation of China (Grant Nos. 11674387, 11574385, 22005332, 115674368, and 62065005)。
文摘The 100 crystal-oriented silicon micropillar array platforms were prepared by microfabrication processes for the purpose of electrolyte additive identification. The silicon micropillar array platform was used for the study of fluorinated vinyl carbonate(FEC), vinyl ethylene carbonate(VEC), ethylene sulfite(ES), and vinyl carbonate(VC) electrolyte additives in the LiPF_6 dissolved in a mixture of ethylene carbonate and diethyl carbonate electrolyte system using charge/discharge cycles, electrochemical impedance spectroscopy, cyclic voltammetry, scanning electron microscopy, and x-ray photoelectron spectroscopy. The results show that the silicon pillar morphology displays cross-shaped expansion after lithiation/delithiation, the inorganic lithium salt keeps the silicon pillar morphology intact, and the organic lithium salt content promotes a rougher silicon pillar surface. The presence of poly-(VC) components on the surface of FEC and VC electrodes allows the silicon pillar to accommodate greater volume expansion while remaining intact. This work provides a standard, fast, and effective test method for the performance analysis of electrolyte additives and provides guidance for the development of new electrolyte additives.
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2016YFF0200103 and 2016YFF0200200)the Fundamental Research Funds for National Institute of Metrology,China(Grant No.22-AKY1608)
文摘The scale factor of a superconducting gravimeter(SG) is usually calibrated by using simultaneous and co-located gravity measurements with the FG5-type absolute gravimeter(AG). In this paper, another new kind of absolute gravimetercold atom gravimeter(CAG) is first reported to calibrate the SG. Five-day side-by-side gravity measurements have been carried out by using our CAG(NIM-AGRb-1) to calibrate the SG(iGrav-012) located at Changping Campus of the National Institute of Metrology(NIM) of China. A weighted least-squares method is applied to determine the scale factor and the result is given as(-928.01 ± 0.73) nm·s;·V;with a precision of 0.79‰. We have demonstrated that a calibration precision of 1‰ level can be achieved after 3 days of parallel observations at spring tide. The obtained calibration results are then compared with the previous calibration by FG5 X-249, which shows that the calibration precision obtained by using NIM-AGRb-1 was slightly higher than FG5 X-249 with the same time interval. The factors affecting the calibration precision are analyzed in the calibrations by means of different AGs. Finally, several calibration experiments for SG iGrav-012 are discussed. The final scale factor is estimated as(-927.58 ± 0.36) nm·s;·V;with an accuracy of 0.39‰. Our main results demonstrate that the CAGs can be used for high-precision calibrations of SGs.
基金supported by the National Natural Science Foundation of China (51674297)the Natural Science Foundation of Hunan Province (2016JJ2137)the Fundamental Research Funds for the Central Universities of Central South University (2015cx001)~~
基金the National Natural Science Foundation of China(Grant Nos.11974048 and 11974049)the Beijing Science Foundation(Grant No.1192011)。
文摘The competition between the RKKY interaction and the Kondo effect leads to a magnetic phase transition,which occurs ubiquitously in heavy fermion materials.However,there are more and more experimental evidences indicating that the valence fluctuation plays an essential role in the Ce-and Y-based compounds.We study an extended periodic Anderson model(EPAM)which includes the onsite Coulomb repulsion Ucf between the localized electrons and conduction electrons.By employing the density matrix embedding theory,we investigate the EPAM in the symmetric case at half filling.By fixing the onsite Coulomb repulsion U of the localized electrons to an intermediate value,the interplay between the RKKY interaction,the Kondo effect and the Coulomb repulsion Ucf brings rich physics.We find three different phases,the antiferromagnetic phase,the charge order phase and paramagnetic phase.When the hybridization strength V between the localized orbital and the conduction orbital is small,the Kondo effect is weak so that the AF phase and the CO phase are present.The phase transition between the two long-range ordered phase is of first order.We also find a coexistence region between the two phases.As V increases,the Kondo effect becomes stronger,and the paramagnetic phase appears between the other two phases.
基金was supported by the Innovation Program for Quantum Science and Technology(No.2021ZD0303200)the National Natural Science Foundation of China(No.62225506)+1 种基金the CAS Project for Young Scientists in Basic Research(No.YSBR-049)the Key Research and Development Program of Anhui Province(No.2022b13020006)。
文摘Modulation of a vector light field has played an important role in the research of nanophotonics.However,it is still a great challenge to accurately measure the three-dimensional vector distribution at nanoscale.Here,based on the interaction between the light field and atomic-sized nitrogen-vacancy(NV)color center in diamonds,we demonstrate an efficient method for vectorial mapping of the light-field distribution at nanoscale.Single NV centers with different but well-defined symmetry axes are selected and then interact with the same tightly focused light field.The excitation of a single NV center is related to the angle between the NV center axis and the polarization of the light field.Then the fluorescence patterns of different NV centers provide the information on the vectorial light field distribution.Subsequently analyzing the fluorescence patterns with the help of a deep neural network,the intensity and phase of the light-field vectorial components are fully reconstructed with nanometer resolution.The experimental results are in agreement with theoretical calculations.It demonstrates that our method can help to study light–matter interaction at nanoscale and extend the application of vector light fields in research on nanophotonics.
基金supported by the National Natural Science Foundation(NSFC)of China(52002394)Young Elite Scientists Sponsorship Program by CAST(2022QNRC001)Youth Innovation Promotion Association of the Chinese Academy of Sciences(2020006).
文摘The anionic redox reaction(ARR)is a promising charge contributor to improve the reversible capacity of layeredoxide cathodes for Na-ion batteries;however,some practical bottlenecks still need to be eliminated,including a low capacity retention,large voltage hysteresis,and low rate capability.Herein,we proposed a high-Na content honeycomb-ordered cathode,P2–Na_(5/6)[Li_(1/6)Cu_(1/6)Mn_(2/3)]O_(2)(P2-NLCMO),with combined cationic/anionic redox.Neutron powder diffraction and X-ray diffraction of P2-NLCMO suggested P2-type stacking with rarely found P6322 symmetry.In addition,advanced spectroscopy techniques and density functional theory calculations confirmed the synergistic stabilizing relationship between the Li/Cu dual honeycomb centers,achieving fully active Cu^(3+)/Cu^(2+) redox and stabilized ARR with interactively suppressed local distortion.With a meticulously regulated charge/discharge protocol,both the cycling and rate capability of P2-NLCMO were significantly.
基金supported by the National Key Research and Development Program of China(Nos.2017YFC0601602 and 2016YFF0200206)the National Natural Science Foundation of China(Nos.61727821,61475139,11604296,and 11174249)
文摘The first Asia-Pacific Comparison of Absolute Gravimeters(APMP.M.G-K1) was organized by the National Institute of Metrology(NIM) of China from December 21, 2015 to March 25, 2016 in Changping, Beijing. Our compact cold atom gravimeter(CCAG) was transported from Hangzhou to Beijing with a long distance of about1200 km to participate in this comparison. The CCAG is the only one, to the best of our knowledge, that is based on the principle of atom interferometry among all the instruments. Absolute gravity in the indicated three test sites has been measured as requested by the organizer. The sensitivity of our CCAG is estimated to be90 μGal∕Hz p, even when the measurements are carried out without any vibration isolation. Besides, the accuracy of this gravimeter has been evaluated to be about 19 μGal by considering the significant system errors.Our results show a good agreement with the given reference value.
基金financially supported by the National Natural Science Foundation of China (No. 51871218)the Youth Innovation Promotion Association, CAS (No. 2018227)+1 种基金the Ling Chuang Research Project of China National Nuclear CorporationCNNC Science Fund for Talented Young Scholars
文摘FF sample(nearly free ofδ-ferrite)and CF sample(containing∼4%δ-ferrite)were prepared from the AISI 316 austenitic stainless steel plate to elucidate the role ofδ-ferrite in the fatigue crack growth under the solution treated and accelerated aged conditions.It is found that the fatigue crack growth resistance of the CF sample is higher than the FF sample under the solution treated condition.However,a significant deterioration of the fatigue crack growth resistance is observed in the CF sample while little variation is found in the FF sample after accelerated aging treatment at 750°C for 10 h.In the solution treated condition,deflected crack growth path is present when the main crack encounters theδ-ferrite in the CF sample due to the differences in the fatigue responses between austenite andδ-ferrite.The measured growth rate of the deflected crack is significantly slower than that of the flat crack of the same length.After the accelerated aging treatment,microcracks are produced at the M_(23)C_(6)/δinterface due to the strain incompatibility between M_(23)C_(6) and retainedδ-ferrite when the decomposedδ-ferrite is subject to plastic deformation in the crack tip plastic zone.The preexisting microcracks in the front of crack tip provide a viable path for crack propagation,resulting in the relatively flat crack path.