In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electro...In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, and tensile tests. The results showed that Ti can decrease the secondary dendrite arm spacing(SDAS). The tensile strength of the Mg-8Sn-1Zn-Ti alloys is initially increased by increasing the Ti content up to 0.09 wt.%, but subsequently decreased for further increase of Ti content. The improved tensile properties are attributed to the decreased SDAS and refi ned Mg_2Sn phases, as well as the increased fraction of tin(Sn) segregated regions. The tensile fracture surface of the studied alloys shows mixed characteristics of cleavage and quasi-cleavage fracture. Adding Ti does not significantly change the fracture mode of the studied alloys.展开更多
Biodegradable Mg-xB i(x = 3, 6 and 9wt.%) alloys were fabricated by ingot casting, and the change of corrosion behavior of the alloys in the Hank's solution was analyzed with respect to the microstructure using op...Biodegradable Mg-xB i(x = 3, 6 and 9wt.%) alloys were fabricated by ingot casting, and the change of corrosion behavior of the alloys in the Hank's solution was analyzed with respect to the microstructure using optical micrograph(OM), X-ray diffraction(XRD), scanning electron microscope(SEM) equipped with an energy dispersive X-ray spectrometer(EDS), electrochemical and immersion tests. The results show that the microstructures of the as-cast Mg-Bi alloys mainly consisted of dendritic α-Mg grains and Mg3Bi2 phase in common, with the secondary dendrite arm spacing(SDAS) decreasing significantly from 41.2 μm to 25.4 μm and the fraction of Mg3Bi2 increasing from 3.1% to 10.7%. Furthermore, the corrosion rate increasing from 1.32 mm·a-1 to 8.07 mm·a-1 as the Bi content was increased from 3wt.% to 9wt.%. The reduced corrosion resistance was mainly ascribed to the increasing fraction of the second phase particles, which bring positive effects on the development of pitting.展开更多
基金supported by the National Natural Science Foundation of China(Grant no.51404166)Shanxi Province Science Foundation for Youths(2013021013-4)+2 种基金Research Project Supported by Shanxi Scholarship Council of China(2014-023)Technological Innovation Programs of Higher Education Institutions Shanxi(Grant no.2014120)the Advanced Programs of Department of Human Resources and Social Security of Shanxi Province for Returned Scholars(2013101)
文摘In this study, the influence of minor titanium(Ti) addition on the microstructure and tensile properties of Mg-8Sn-1Zn based alloys were investigated by means of optical microscopy, X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, and tensile tests. The results showed that Ti can decrease the secondary dendrite arm spacing(SDAS). The tensile strength of the Mg-8Sn-1Zn-Ti alloys is initially increased by increasing the Ti content up to 0.09 wt.%, but subsequently decreased for further increase of Ti content. The improved tensile properties are attributed to the decreased SDAS and refi ned Mg_2Sn phases, as well as the increased fraction of tin(Sn) segregated regions. The tensile fracture surface of the studied alloys shows mixed characteristics of cleavage and quasi-cleavage fracture. Adding Ti does not significantly change the fracture mode of the studied alloys.
基金supported by the National Natural Science Foundation of China(Grant no.51404166)Shanxi Province Science Foundation for Youths(2013021013-4)+2 种基金the Research Project Supported by Shanxi Scholarship Council of China(2014-023)the Technological Innovation Programs of Higher Education Institutions in Shanxi(Grant no.2014120)the Advanced Programs of Department of Human Resources and Social Security of Shanxi Province for Returned Scholars(2013101)
文摘Biodegradable Mg-xB i(x = 3, 6 and 9wt.%) alloys were fabricated by ingot casting, and the change of corrosion behavior of the alloys in the Hank's solution was analyzed with respect to the microstructure using optical micrograph(OM), X-ray diffraction(XRD), scanning electron microscope(SEM) equipped with an energy dispersive X-ray spectrometer(EDS), electrochemical and immersion tests. The results show that the microstructures of the as-cast Mg-Bi alloys mainly consisted of dendritic α-Mg grains and Mg3Bi2 phase in common, with the secondary dendrite arm spacing(SDAS) decreasing significantly from 41.2 μm to 25.4 μm and the fraction of Mg3Bi2 increasing from 3.1% to 10.7%. Furthermore, the corrosion rate increasing from 1.32 mm·a-1 to 8.07 mm·a-1 as the Bi content was increased from 3wt.% to 9wt.%. The reduced corrosion resistance was mainly ascribed to the increasing fraction of the second phase particles, which bring positive effects on the development of pitting.