Photocatalytic degradation of antibiotic sulfamethizole by visible light activated perovskite LaZnO_(3)

In thiswork,the perovskite LaZnO_(3) was synthesized via sol-gel method and applied for photocatalytic treatment of sulfamethizole(SMZ)antibiotics under visible light activation.SMZ was almost completely degraded(99.2%±0.3%)within 4 hr by photocatalyst LaZnO3 at the optimal dosage of 1.1 g/L,with amineralization proportion of 58.7%±0.4%.The efficient performance of LaZnO_(3) can be attributed to itswide-range light absorption and the appropriate energy band edge levels,which facilitate the formation of active agents such as·O_(2)^(−),h^(+),and·OH.The integration of RP-HPLC/Q-TOF-MS and DFT-based computational techniques revealed three degradation pathways of SMZ,which were initiated by the deamination reaction at the aniline ring,the breakdown of the sulfonamidemoieties,and a process known as Smile-type rearrangement and SO2 intrusion.Corresponding toxicity of SMZ and the intermediateswere analyzed by quantitative structure activity relationship(QSAR),indicating the effectiveness of LaZnO_(3)-based photocatalysis in preventing secondary pollution of the intermediates to the ecosystem during the degradation process.The visible-light-activated photocatalyst LaZnO_(3) exhibited efficient performance in the occurrence of inorganic anions and maintained high durability across multiple recycling tests,making it a promising candidate for practical antibiotic treatment.

Using fluorescence surrogates to track algogenic dissolved organic matter(AOM) during growth and coagulation/flocculation processes of green algae

Tracking the variation of the algogenic organic matter(AOM) released during the proliferation of green algae and subsequent treatment processes is crucial for constructing and optimizing control strategies. In this study, the potential of the spectroscopic tool was fully explored as a surrogate of AOM upon the cultivation of green algae and subsequent coagulation/flocculation(C/F) treatment processes using ZrCl_4 and Al_2(SO_4)_3. Fluorescence excitation emission matrix coupled with parallel factor analysis(EEM-PARAFAC) identified the presence of three independent fluorescent components in AOM, including protein-like(C1), fulvic-like(C2) and humic-like components(C3). Size exclusion chromatography(SEC) revealed that C1 in AOM was composed of large-sized proteins and aromatic amino acids. The individual components exhibited their unique characteristics with respect to the dynamic changes. C1 showed the highest correlation with AOM concentrations(R^2= 0.843) upon the C/F processes. C1 could also be suggested as an optical predictor for the formation of trihalomethanes upon the C/F processes. This study sheds a light for the potential application of the protein-like component(C1) as a practical surrogate to track the evolution of AOM in water treatment or wastewater reclamation systems involving Chlorella vulgaris green algae.

A review on hollow fiber membrane module towards high separation efficiency:Process modeling in fouling perspective

Hollow fiber microfiltration(MF)and ultrafiltration(UF)membrane processes have been extensively used in water purification and biotechnology.However,complicated filtration hydrodynamics wield a negative influence on fouling mitigation and stability of hollow fiber MF/UF membrane processes.Thus,establishing a mathematical model to understand the membrane processes is essential to guide the optimization of module configurations and to alleviate membrane fouling.Here,we present a comprehensive overview of the hollow fiber MF/UF membrane filtration models developed from different theories.The existing models primarily focus on membrane fouling but rarely on the interactions between the membrane fouling and local filtration hydrodynamics.Therefore,more simplified conceptual models and integrated reduced models need to be built to represent the real filtration behaviors of hollow fiber membranes.Future analyses considering practical requirements including complicated local hydrodynamics and nonuniform membrane properties are suggested to meet the accurate prediction of membrane filtration performance in practical application.This review will inspire the development of high-efficiency hollow fiber membrane modules.