Extraordinary electronic properties can emerge at the interfaces between metal oxides[1-10].Interfacial behaviors have enabled a wide range of applications from electronic communication,energy conversion and storage,t...Extraordinary electronic properties can emerge at the interfaces between metal oxides[1-10].Interfacial behaviors have enabled a wide range of applications from electronic communication,energy conversion and storage,to data processing and memory.In recent years,unprecedented progress has been made in exploring and exploiting the emergent and/or enhanced properties of these interfaces,and it is becoming clear that interface engineering provides a new opportunity for advanced devices in the near future.The capability of using interfaces to manipulate material properties offers an effective means to achieve intriguing phenomena.展开更多
Epitaxial PrBaCo_(2)O_(5+δ)(PBCO,0≤δ≤1)thin films were deposited by pulsed laser deposition.The structural and electrical properties of the films were characterized at high temperatures in reduced environments.X-r...Epitaxial PrBaCo_(2)O_(5+δ)(PBCO,0≤δ≤1)thin films were deposited by pulsed laser deposition.The structural and electrical properties of the films were characterized at high temperatures in reduced environments.X-ray diffraction scans at high temperature in reduced environment show potential structural transitions of PBCO as evidenced by both a large(Dl=0.335 nm)expansion of the out-plane(caxis)lattice,due to thermal and chemical expansion,and a step in the expansion of the c-axis lattice parameter.These transitions indicate the presence of oxygen vacancy ordering as the oxygen content in the films is reduced.Resistivity measurements under the same environments also show evidence of sharp transitions related with the structural transformations.This study helps the understanding of the structure-property relationship of PBCO at high temperature and provides important technological information to utilize these materials for solid oxide fuel cell at intermediate temperatures.展开更多
基金supported by the National Nature Science Foundation of China(U1530402,17N1041)the CINT User Program+2 种基金the support by the U.S.National Science Foundation(ECCS-1902623)the support by the National Nature Science Foundation of China(51728202)the Center for Nanoscale Materials,an Office of Science user facility,supported by the U.S.Department of Energy(DE-AC02-06CH11357)
文摘Extraordinary electronic properties can emerge at the interfaces between metal oxides[1-10].Interfacial behaviors have enabled a wide range of applications from electronic communication,energy conversion and storage,to data processing and memory.In recent years,unprecedented progress has been made in exploring and exploiting the emergent and/or enhanced properties of these interfaces,and it is becoming clear that interface engineering provides a new opportunity for advanced devices in the near future.The capability of using interfaces to manipulate material properties offers an effective means to achieve intriguing phenomena.
基金This research was partially supported by the National Institute on Minority Health and Health Disparities of the National Institutes of Health under Award Number G12MD007591This work was performed,in part,at the Center for Integrated Nanotechnologies,an Office of Science User Facility operated for the U.S.Department of Energy(DOE)Office of Science.Los Alamos National Laboratory,an affirmative action equal opportunity employer,is operated by Los Alamos National Security,LLC,for the National Nuclear Security Administration of the U.S.Department of Energy under contract DE-AC52-06NA25396.
文摘Epitaxial PrBaCo_(2)O_(5+δ)(PBCO,0≤δ≤1)thin films were deposited by pulsed laser deposition.The structural and electrical properties of the films were characterized at high temperatures in reduced environments.X-ray diffraction scans at high temperature in reduced environment show potential structural transitions of PBCO as evidenced by both a large(Dl=0.335 nm)expansion of the out-plane(caxis)lattice,due to thermal and chemical expansion,and a step in the expansion of the c-axis lattice parameter.These transitions indicate the presence of oxygen vacancy ordering as the oxygen content in the films is reduced.Resistivity measurements under the same environments also show evidence of sharp transitions related with the structural transformations.This study helps the understanding of the structure-property relationship of PBCO at high temperature and provides important technological information to utilize these materials for solid oxide fuel cell at intermediate temperatures.
