The roles of reaction inhomogeneity in phase separation of polymer mixtures were described and summarized via two examples:photocross-link of polymer mixtures in the bulk state and photopolymerization of monomer in th...The roles of reaction inhomogeneity in phase separation of polymer mixtures were described and summarized via two examples:photocross-link of polymer mixtures in the bulk state and photopolymerization of monomer in the liquid state. The reaction kinetics,the reaction-induced elastic strain and the phase separation kinetics were monitored respectively by UV-Vis spectroscopy,Mach-Zehnder interferometry and laser-scanning confocal microscopy.It was found that phase separation in the bulk state was strongly inf...展开更多
The mechanical properties of unidirectional natural fiber-reinforced composites are generally affected by several processing parameters during compression molding.This study investigates the effects of processing temp...The mechanical properties of unidirectional natural fiber-reinforced composites are generally affected by several processing parameters during compression molding.This study investigates the effects of processing temperature,time,and pressure on the tensile and flexural properties of acrylonitrile butadiene styrene reinforced by banana fibers.X-ray CT imaging was employed to find the relationship between the mechanical properties and structure of the processed composite.Besides,the water absorption of composites was observed and the way in which the mechanical properties evolved after water absorption was analyzed.The tensile and flexural properties of the unidirectional banana fiber-reinforced composite were found to be inversely proportional to the porosity.In addition,high-pressure compression molding might result in cracks and floating fibers that would significantly reduce its mechanical properties.The composite with the highest strength,smallest porosity and lowest water absorption was optimally prepared at T=170℃,t=20 min,and P=100 kg cm^-2.展开更多
基金supported by the Ministry of Education (MONKASHO),Japan through the Grant-in-Aid on the Priority-Research-Area"Molecular Nanodynamics"and"Soft Matter Physics".The Grant-in-Aid for Scientific Research (No.20350107) is also gratefully acknowledged.
文摘The roles of reaction inhomogeneity in phase separation of polymer mixtures were described and summarized via two examples:photocross-link of polymer mixtures in the bulk state and photopolymerization of monomer in the liquid state. The reaction kinetics,the reaction-induced elastic strain and the phase separation kinetics were monitored respectively by UV-Vis spectroscopy,Mach-Zehnder interferometry and laser-scanning confocal microscopy.It was found that phase separation in the bulk state was strongly inf...
文摘The mechanical properties of unidirectional natural fiber-reinforced composites are generally affected by several processing parameters during compression molding.This study investigates the effects of processing temperature,time,and pressure on the tensile and flexural properties of acrylonitrile butadiene styrene reinforced by banana fibers.X-ray CT imaging was employed to find the relationship between the mechanical properties and structure of the processed composite.Besides,the water absorption of composites was observed and the way in which the mechanical properties evolved after water absorption was analyzed.The tensile and flexural properties of the unidirectional banana fiber-reinforced composite were found to be inversely proportional to the porosity.In addition,high-pressure compression molding might result in cracks and floating fibers that would significantly reduce its mechanical properties.The composite with the highest strength,smallest porosity and lowest water absorption was optimally prepared at T=170℃,t=20 min,and P=100 kg cm^-2.
